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Methanesulfonic acid (2S,3S)-3-(tert-butyl-dimethyl-silanyloxy)-2-((R)-(R)-1-oxiranyl-but-3-enyloxy)-hex-5-enyl ester

Methanesulfonic acid (2S,3S)-3-(tert-butyl-dimethyl-silanyloxy)-2-((R)-(R)-1-oxiranyl-but-3-enyloxy)-hex-5-enyl ester

CAS号：475276-09-6

英文名：Methanesulfonic acid (2S,3S)-3-(tert-butyl-dimethyl-silanyloxy)-2-((R)-(R)-1-oxiranyl-but-3-enyloxy)-hex-5-enyl ester

分子式：C19H36O6SSi

分子量：420.636

合成路线

(S)-1-((3aS,4R,6R,7S,7aR)-6-Allyl-7-benzyloxy-2,2-dimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-4-yl)-but-3-en-1-ol

(S)-1-((3aS,4R,6R,7S,7aR)-6-Allyl-7-benzyloxy-2,2-dimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-4-yl)-but-3-en-1-ol

Methanesulfonic acid (2S,3S)-3-(tert-butyl-dimethyl-silanyloxy)-2-((R)-(R)-1-oxiranyl-but-3-enyloxy)-hex-5-enyl ester

Methanesulfonic acid (2S,3S)-3-(tert-butyl-dimethyl-silanyloxy)-2-((R)-(R)-1-oxiranyl-but-3-enyloxy)-hex-5-enyl ester

2,6-anhydro-7,8,9-trideoxy-D-glycero-L-galacto-non-8-enitol

2,6-anhydro-7,8,9-trideoxy-D-glycero-L-galacto-non-8-enitol

Methanesulfonic acid (2S,3S)-3-(tert-butyl-dimethyl-silanyloxy)-2-((R)-(R)-1-oxiranyl-but-3-enyloxy)-hex-5-enyl ester

Methanesulfonic acid (2S,3S)-3-(tert-butyl-dimethyl-silanyloxy)-2-((R)-(R)-1-oxiranyl-but-3-enyloxy)-hex-5-enyl ester

((3aS,4R,6R,7S,7aR)-6-Allyl-7-benzyloxy-2,2-dimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-4-yl)-methanol

((3aS,4R,6R,7S,7aR)-6-Allyl-7-benzyloxy-2,2-dimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-4-yl)-methanol

Methanesulfonic acid (2S,3S)-3-(tert-butyl-dimethyl-silanyloxy)-2-((R)-(R)-1-oxiranyl-but-3-enyloxy)-hex-5-enyl ester

Methanesulfonic acid (2S,3S)-3-(tert-butyl-dimethyl-silanyloxy)-2-((R)-(R)-1-oxiranyl-but-3-enyloxy)-hex-5-enyl ester

上游原料

(S)-1-((3aS,4R,6R,7S,7aR)-6-Allyl-7-benzyloxy-2,2-dimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-4-yl)-but-3-en-1-ol 2,6-anhydro-7,8,9-trideoxy-D-glycero-L-galacto-non-8-enitol ((3aS,4R,6R,7S,7aR)-6-Allyl-7-benzyloxy-2,2-dimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-4-yl)-methanol

下游产品

{(1S,2S)-1-Allyl-5,5-dibromo-2-[(R)-1-((S)-1-bromo-propyl)-but-3-enyloxy]-pent-4-enyloxy}-tert-butyl-dimethyl-silane (3S,4S)-3-[(R)-1-((S)-1-Bromo-propyl)-but-3-enyloxy]-4-(tert-butyl-dimethyl-silanyloxy)-hept-6-enenitrile