百科

(2E,4E)-7-((2R,3R)-3-{1-[(2R,3R)-3-allyl-1,4-dioxaspiro[4.4]non-2-yl]vinyl}-1,4-dioxaspiro[4.4]non-2-yl)-3-methylocta-2,4,7-trienoic acid

(2E,4E)-7-((2R,3R)-3-{1-[(2R,3R)-3-allyl-1,4-dioxaspiro[4.4]non-2-yl]vinyl}-1,4-dioxaspiro[4.4]non-2-yl)-3-methylocta-2,4,7-trienoic acid

CAS号：476452-84-3

英文名：(2E,4E)-7-((2R,3R)-3-{1-[(2R,3R)-3-allyl-1,4-dioxaspiro[4.4]non-2-yl]vinyl}-1,4-dioxaspiro[4.4]non-2-yl)-3-methylocta-2,4,7-trienoic acid

分子式：C28H38O6

分子量：470.598

合成路线

1,7-bis[(4-methoxybenzyl)oxy]hepta-2,5-diyn-4-ol

1,7-bis[(4-methoxybenzyl)oxy]hepta-2,5-diyn-4-ol

(2E,4E)-7-((2R,3R)-3-{1-[(2R,3R)-3-allyl-1,4-dioxaspiro[4.4]non-2-yl]vinyl}-1,4-dioxaspiro[4.4]non-2-yl)-3-methylocta-2,4,7-trienoic acid

(2E,4E)-7-((2R,3R)-3-{1-[(2R,3R)-3-allyl-1,4-dioxaspiro[4.4]non-2-yl]vinyl}-1,4-dioxaspiro[4.4]non-2-yl)-3-methylocta-2,4,7-trienoic acid

((2R,3R)-3-{1-[(2R,3R)-3-(tert-Butyl-dimethyl-silanyloxymethyl)-1,4-dioxa-spiro[4.4]non-2-yl]-vinyl}-1,4-dioxa-spiro[4.4]non-2-yl)-methanol

((2R,3R)-3-{1-[(2R,3R)-3-(tert-Butyl-dimethyl-silanyloxymethyl)-1,4-dioxa-spiro[4.4]non-2-yl]-vinyl}-1,4-dioxa-spiro[4.4]non-2-yl)-methanol

(2E,4E)-7-((2R,3R)-3-{1-[(2R,3R)-3-allyl-1,4-dioxaspiro[4.4]non-2-yl]vinyl}-1,4-dioxaspiro[4.4]non-2-yl)-3-methylocta-2,4,7-trienoic acid

(2E,4E)-7-((2R,3R)-3-{1-[(2R,3R)-3-allyl-1,4-dioxaspiro[4.4]non-2-yl]vinyl}-1,4-dioxaspiro[4.4]non-2-yl)-3-methylocta-2,4,7-trienoic acid

上游原料

((2R,3R)-3-{1-[(2R,3R)-3-(tert-Butyl-dimethyl-silanyloxymethyl)-1,4-dioxa-spiro[4.4]non-2-yl]-vinyl}-1,4-dioxa-spiro[4.4]non-2-yl)-methanol 1,7-bis[(4-methoxybenzyl)oxy]hepta-2,5-diyn-4-ol

下游产品

(2E,4E)-(8R,9R,11R,12R)-8,9,11,12-Tetrahydroxy-3-methyl-7,10-dimethylene-pentadeca-2,4,14-trienoic acid (2E,4E)-(8R,9R,11R,12R)-3-Methyl-7,10-dimethylene-8,9,11,12-tetrakis-triethylsilanyloxy-pentadeca-2,4,14-trienoic acid (1R,2S)-2-methyl-1-[(2S,3R)-3-((R)-1-methyl-butyl)-oxiranyl]-pent-4-ynyl ester