百科

tert-Butyl-[(4aR,6S,7R,8aS)-6-(2-iodo-ethyl)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yloxy]-dimethyl-silane

tert-Butyl-[(4aR,6S,7R,8aS)-6-(2-iodo-ethyl)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yloxy]-dimethyl-silane

CAS号：476687-73-7

英文名：tert-Butyl-[(4aR,6S,7R,8aS)-6-(2-iodo-ethyl)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yloxy]-dimethyl-silane

分子式：C21H33IO4Si

分子量：504.474

合成路线

((4aR,6S,7R,8aS)-7-Hydroxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-6-yl)-acetic acid ethyl ester

((4aR,6S,7R,8aS)-7-Hydroxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-6-yl)-acetic acid ethyl ester

tert-Butyl-[(4aR,6S,7R,8aS)-6-(2-iodo-ethyl)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yloxy]-dimethyl-silane

tert-Butyl-[(4aR,6S,7R,8aS)-6-(2-iodo-ethyl)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yloxy]-dimethyl-silane

2-deoxy-D-erythro-pentose cyclic 1,3-propanediyl mercaptal

2-deoxy-D-erythro-pentose cyclic 1,3-propanediyl mercaptal

tert-Butyl-[(4aR,6S,7R,8aS)-6-(2-iodo-ethyl)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yloxy]-dimethyl-silane

tert-Butyl-[(4aR,6S,7R,8aS)-6-(2-iodo-ethyl)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yloxy]-dimethyl-silane

(E)-3-[(4S,5R)-4-(2-Oxo-ethyl)-2-phenyl-[1,3]dioxan-5-yloxy]-acrylic acid ethyl ester

(E)-3-[(4S,5R)-4-(2-Oxo-ethyl)-2-phenyl-[1,3]dioxan-5-yloxy]-acrylic acid ethyl ester

tert-Butyl-[(4aR,6S,7R,8aS)-6-(2-iodo-ethyl)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yloxy]-dimethyl-silane

tert-Butyl-[(4aR,6S,7R,8aS)-6-(2-iodo-ethyl)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yloxy]-dimethyl-silane

上游原料

(E)-3-[(4S,5R)-4-(2-Oxo-ethyl)-2-phenyl-[1,3]dioxan-5-yloxy]-acrylic acid ethyl ester 2-deoxy-D-erythro-pentose cyclic 1,3-propanediyl mercaptal ((4aR,6S,7R,8aS)-7-Hydroxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-6-yl)-acetic acid ethyl ester

下游产品

(E)-4-[(4aR,5aS,8R,9S,10aR,11aS)-8-(tert-Butyl-dimethyl-silanyloxy)-8-methyl-2-phenyl-decahydro-1,3,5,10-tetraoxa-cyclohepta[b]naphthalen-9-yl]-2-methyl-but-2-en-1-ol (2S,3R,4aS,5aR,6aS,10aR,11aS,13aR)-2,13a-Dimethyl-8-phenyl-2-vinyl-dodecahydro-1,5,7,9,11-pentaoxa-benzo[4,5]cyclohepta[1,2-b]naphthalen-3-ol {(2R,3R)-3-[(4aR,5aS,8R,9S,10aR,11aS)-8-(tert-Butyl-dimethyl-silanyloxy)-8-methyl-2-phenyl-decahydro-1,3,5,10-tetraoxa-cyclohepta[b]naphthalen-9-ylmethyl]-2-methyl-oxiranyl}-methanol