百科

(E)-4-[(4aR,5aS,8R,9S,10aR,11aS)-8-(tert-Butyl-dimethyl-silanyloxy)-8-methyl-2-phenyl-decahydro-1,3,5,10-tetraoxa-cyclohepta[b]naphthalen-9-yl]-2-methyl-but-2-en-1-ol

CAS号：476687-77-1

英文名：(E)-4-[(4aR,5aS,8R,9S,10aR,11aS)-8-(tert-Butyl-dimethyl-silanyloxy)-8-methyl-2-phenyl-decahydro-1,3,5,10-tetraoxa-cyclohepta[b]naphthalen-9-yl]-2-methyl-but-2-en-1-ol

分子式：C29H46O6Si

分子量：518.757

合成路线

476687-71-5

((4aR,6S,7R,8aS)-7-Hydroxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-6-yl)-acetic acid ethyl ester

476687-77-1

(E)-4-[(4aR,5aS,8R,9S,10aR,11aS)-8-(tert-Butyl-dimethyl-silanyloxy)-8-methyl-2-phenyl-decahydro-1,3,5,10-tetraoxa-cyclohepta[b]naphthalen-9-yl]-2-methyl-but-2-en-1-ol

50907-65-8

2-deoxy-D-erythro-pentose cyclic 1,3-propanediyl mercaptal

476687-77-1

(E)-4-[(4aR,5aS,8R,9S,10aR,11aS)-8-(tert-Butyl-dimethyl-silanyloxy)-8-methyl-2-phenyl-decahydro-1,3,5,10-tetraoxa-cyclohepta[b]naphthalen-9-yl]-2-methyl-but-2-en-1-ol

476688-07-0

(E)-4-[(4aR,5aS,8R,9S,10aR,11aS)-8-(tert-Butyl-dimethyl-silanyloxy)-8-methyl-2-phenyl-decahydro-1,3,5,10-tetraoxa-cyclohepta[b]naphthalen-9-yl]-2-methyl-but-2-enoic acid ethyl ester

476687-77-1

(E)-4-[(4aR,5aS,8R,9S,10aR,11aS)-8-(tert-Butyl-dimethyl-silanyloxy)-8-methyl-2-phenyl-decahydro-1,3,5,10-tetraoxa-cyclohepta[b]naphthalen-9-yl]-2-methyl-but-2-en-1-ol

476688-04-7

((4aR,5aS,8R,9S,10aR,11aS)-8-Hydroxy-8-methyl-2-phenyl-decahydro-1,3,5,10-tetraoxa-cyclohepta[b]naphthalen-9-yl)-acetaldehyde

476687-77-1

(E)-4-[(4aR,5aS,8R,9S,10aR,11aS)-8-(tert-Butyl-dimethyl-silanyloxy)-8-methyl-2-phenyl-decahydro-1,3,5,10-tetraoxa-cyclohepta[b]naphthalen-9-yl]-2-methyl-but-2-en-1-ol

476687-73-7

tert-Butyl-[(4aR,6S,7R,8aS)-6-(2-iodo-ethyl)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yloxy]-dimethyl-silane

476687-77-1

(E)-4-[(4aR,5aS,8R,9S,10aR,11aS)-8-(tert-Butyl-dimethyl-silanyloxy)-8-methyl-2-phenyl-decahydro-1,3,5,10-tetraoxa-cyclohepta[b]naphthalen-9-yl]-2-methyl-but-2-en-1-ol

476688-03-6

2-[(4aR,6S,7R,8aS)-7-(tert-Butyl-dimethyl-silanyloxy)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-6-yl]-ethanol

476687-77-1

(E)-4-[(4aR,5aS,8R,9S,10aR,11aS)-8-(tert-Butyl-dimethyl-silanyloxy)-8-methyl-2-phenyl-decahydro-1,3,5,10-tetraoxa-cyclohepta[b]naphthalen-9-yl]-2-methyl-but-2-en-1-ol

476687-76-0

(3aS,4aR,5aS,9aR,10aS,12aR)-12a-Methyl-7-phenyl-decahydro-1,4,6,8,10-pentaoxa-naphtho[2,3-f]azulen-2-one

476687-77-1

(E)-4-[(4aR,5aS,8R,9S,10aR,11aS)-8-(tert-Butyl-dimethyl-silanyloxy)-8-methyl-2-phenyl-decahydro-1,3,5,10-tetraoxa-cyclohepta[b]naphthalen-9-yl]-2-methyl-but-2-en-1-ol

476687-75-9

(E)-3-[(4aR,6S,7R,8aS)-6-(3-Oxo-butyl)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yloxy]-acrylic acid ethyl ester

476687-77-1

(E)-4-[(4aR,5aS,8R,9S,10aR,11aS)-8-(tert-Butyl-dimethyl-silanyloxy)-8-methyl-2-phenyl-decahydro-1,3,5,10-tetraoxa-cyclohepta[b]naphthalen-9-yl]-2-methyl-but-2-en-1-ol

807617-30-7

(4S,5R)-4-[1,3]Dithian-2-ylmethyl-2-phenyl-[1,3]dioxan-5-ol

476687-77-1

(E)-4-[(4aR,5aS,8R,9S,10aR,11aS)-8-(tert-Butyl-dimethyl-silanyloxy)-8-methyl-2-phenyl-decahydro-1,3,5,10-tetraoxa-cyclohepta[b]naphthalen-9-yl]-2-methyl-but-2-en-1-ol

807616-94-0

(E)-3-[(4S,5R)-4-(2-Oxo-ethyl)-2-phenyl-[1,3]dioxan-5-yloxy]-acrylic acid ethyl ester

476687-77-1

(E)-4-[(4aR,5aS,8R,9S,10aR,11aS)-8-(tert-Butyl-dimethyl-silanyloxy)-8-methyl-2-phenyl-decahydro-1,3,5,10-tetraoxa-cyclohepta[b]naphthalen-9-yl]-2-methyl-but-2-en-1-ol

上游原料

(E)-3-[(4aR,6S,7R,8aS)-6-(3-Oxo-butyl)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yloxy]-acrylic acid ethyl ester 2-[(4aR,6S,7R,8aS)-7-(tert-Butyl-dimethyl-silanyloxy)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-6-yl]-ethanol (E)-4-[(4aR,5aS,8R,9S,10aR,11aS)-8-(tert-Butyl-dimethyl-silanyloxy)-8-methyl-2-phenyl-decahydro-1,3,5,10-tetraoxa-cyclohepta[b]naphthalen-9-yl]-2-methyl-but-2-enoic acid ethyl ester tert-Butyl-[(4aR,6S,7R,8aS)-6-(2-iodo-ethyl)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yloxy]-dimethyl-silane (E)-3-[(4S,5R)-4-(2-Oxo-ethyl)-2-phenyl-[1,3]dioxan-5-yloxy]-acrylic acid ethyl ester 2-deoxy-D-erythro-pentose cyclic 1,3-propanediyl mercaptal ((4aR,6S,7R,8aS)-7-Hydroxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-6-yl)-acetic acid ethyl ester (3aS,4aR,5aS,9aR,10aS,12aR)-12a-Methyl-7-phenyl-decahydro-1,4,6,8,10-pentaoxa-naphtho[2,3-f]azulen-2-one (4S,5R)-4-[1,3]Dithian-2-ylmethyl-2-phenyl-[1,3]dioxan-5-ol ((4aR,5aS,8R,9S,10aR,11aS)-8-Hydroxy-8-methyl-2-phenyl-decahydro-1,3,5,10-tetraoxa-cyclohepta[b]naphthalen-9-yl)-acetaldehyde

下游产品

(2S,3R,4aS,5aR,6aS,10aR,11aS,13aR)-2-(2-Hydroxy-ethyl)-2,13a-dimethyl-8-phenyl-dodecahydro-1,5,7,9,11-pentaoxa-benzo[4,5]cyclohepta[1,2-b]naphthalen-3-ol tert-Butyl-dimethyl-[(4aR,5aS,8R,9S,10aR,11aS)-8-methyl-9-((2R,3R)-3-methyl-3-vinyl-oxiranylmethyl)-2-phenyl-decahydro-1,3,5,10-tetraoxa-cyclohepta[b]naphthalen-8-yloxy]-silane (2S,3R,4aS,5aR,6aS,10aR,11aS,13aR)-3-Benzyloxy-2-(2-benzyloxy-ethyl)-2,13a-dimethyl-8-phenyl-dodecahydro-1,5,7,9,11-pentaoxa-benzo[4,5]cyclohepta[1,2-b]naphthalene (2S,3R,4aS,5aR,6aS,10aR,11aS,13aR)-2,13a-Dimethyl-8-phenyl-2-vinyl-dodecahydro-1,5,7,9,11-pentaoxa-benzo[4,5]cyclohepta[1,2-b]naphthalen-3-ol (4aR,5aS,8R,9S,10aR,11aS)-8-Methyl-9-((2R,3R)-3-methyl-3-vinyl-oxiranylmethyl)-2-phenyl-decahydro-1,3,5,10-tetraoxa-cyclohepta[b]naphthalen-8-ol {(2R,3R)-3-[(4aR,5aS,8R,9S,10aR,11aS)-8-(tert-Butyl-dimethyl-silanyloxy)-8-methyl-2-phenyl-decahydro-1,3,5,10-tetraoxa-cyclohepta[b]naphthalen-9-ylmethyl]-2-methyl-oxiranyl}-methanol