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(Diethoxy-phosphoryl)-acetic acid (4E,6E)-(1S,3S,8R)-1-((E)-(1S,2R)-4-iodo-2-methoxy-1,3-dimethyl-but-3-enyl)-4-methyl-8-[(2R,4S)-6-oxo-4-(2-oxo-ethyl)-tetrahydro-pyran-2-yl]-3-triisopropylsilanyloxy-nona-4,6-dienyl ester

(Diethoxy-phosphoryl)-acetic acid (4E,6E)-(1S,3S,8R)-1-((E)-(1S,2R)-4-iodo-2-methoxy-1,3-dimethyl-but-3-enyl)-4-methyl-8-[(2R,4S)-6-oxo-4-(2-oxo-ethyl)-tetrahydro-pyran-2-yl]-3-triisopropylsilanyloxy-nona-4,6-dienyl ester

CAS号：477201-02-8
英文名：(Diethoxy-phosphoryl)-acetic acid (4E,6E)-(1S,3S,8R)-1-((E)-(1S,2R)-4-iodo-2-methoxy-1,3-dimethyl-but-3-enyl)-4-methyl-8-[(2R,4S)-6-oxo-4-(2-oxo-ethyl)-tetrahydro-pyran-2-yl]-3-triisopropylsilanyloxy-nona-4,6-dienyl ester
分子式：C39H68IO10PSi
分子量：882.915
合成路线
(2R,3R)-N-methoxy-N-methyl (E)-2,4-dimethyl-5-iodo-3-hydroxypent-4-enamide
477200-93-4
(2R,3R)-N-methoxy-N-methyl (E)-2,4-dimethyl-5-iodo-3-hydroxypent-4-enamide
(Diethoxy-phosphoryl)-acetic acid (4E,6E)-(1S,3S,8R)-1-((E)-(1S,2R)-4-iodo-2-methoxy-1,3-dimethyl-but-3-enyl)-4-methyl-8-[(2R,4S)-6-oxo-4-(2-oxo-ethyl)-tetrahydro-pyran-2-yl]-3-triisopropylsilanyloxy-nona-4,6-dienyl ester
477201-02-8
(Diethoxy-phosphoryl)-acetic acid (4E,6E)-(1S,3S,8R)-1-((E)-(1S,2R)-4-iodo-2-methoxy-1,3-dimethyl-but-3-enyl)-4-methyl-8-[(2R,4S)-6-oxo-4-(2-oxo-ethyl)-tetrahydro-pyran-2-yl]-3-triisopropylsilanyloxy-nona-4,6-dienyl ester
(Z)-(5R,6R)-7-(tert-Butyl-dimethyl-silanyloxy)-5-(1-ethoxy-2-iodo-ethoxy)-6-methyl-hept-2-enoic acid methyl ester
477200-76-3
(Z)-(5R,6R)-7-(tert-Butyl-dimethyl-silanyloxy)-5-(1-ethoxy-2-iodo-ethoxy)-6-methyl-hept-2-enoic acid methyl ester
(Diethoxy-phosphoryl)-acetic acid (4E,6E)-(1S,3S,8R)-1-((E)-(1S,2R)-4-iodo-2-methoxy-1,3-dimethyl-but-3-enyl)-4-methyl-8-[(2R,4S)-6-oxo-4-(2-oxo-ethyl)-tetrahydro-pyran-2-yl]-3-triisopropylsilanyloxy-nona-4,6-dienyl ester
477201-02-8
(Diethoxy-phosphoryl)-acetic acid (4E,6E)-(1S,3S,8R)-1-((E)-(1S,2R)-4-iodo-2-methoxy-1,3-dimethyl-but-3-enyl)-4-methyl-8-[(2R,4S)-6-oxo-4-(2-oxo-ethyl)-tetrahydro-pyran-2-yl]-3-triisopropylsilanyloxy-nona-4,6-dienyl ester
(E)-(5R,6R)-7-(tert-Butyl-dimethyl-silanyloxy)-5-(1-ethoxy-2-iodo-ethoxy)-6-methyl-hept-2-enoic acid methyl ester
477200-75-2
(E)-(5R,6R)-7-(tert-Butyl-dimethyl-silanyloxy)-5-(1-ethoxy-2-iodo-ethoxy)-6-methyl-hept-2-enoic acid methyl ester
(Diethoxy-phosphoryl)-acetic acid (4E,6E)-(1S,3S,8R)-1-((E)-(1S,2R)-4-iodo-2-methoxy-1,3-dimethyl-but-3-enyl)-4-methyl-8-[(2R,4S)-6-oxo-4-(2-oxo-ethyl)-tetrahydro-pyran-2-yl]-3-triisopropylsilanyloxy-nona-4,6-dienyl ester
477201-02-8
(Diethoxy-phosphoryl)-acetic acid (4E,6E)-(1S,3S,8R)-1-((E)-(1S,2R)-4-iodo-2-methoxy-1,3-dimethyl-but-3-enyl)-4-methyl-8-[(2R,4S)-6-oxo-4-(2-oxo-ethyl)-tetrahydro-pyran-2-yl]-3-triisopropylsilanyloxy-nona-4,6-dienyl ester
2-{(2R,4R,6S)-2-[(R)-2-(tert-Butyl-dimethyl-silanyloxy)-1-methyl-ethyl]-6-phenylsulfanyl-tetrahydro-pyran-4-yl}-ethanol
477200-79-6
2-{(2R,4R,6S)-2-[(R)-2-(tert-Butyl-dimethyl-silanyloxy)-1-methyl-ethyl]-6-phenylsulfanyl-tetrahydro-pyran-4-yl}-ethanol
(Diethoxy-phosphoryl)-acetic acid (4E,6E)-(1S,3S,8R)-1-((E)-(1S,2R)-4-iodo-2-methoxy-1,3-dimethyl-but-3-enyl)-4-methyl-8-[(2R,4S)-6-oxo-4-(2-oxo-ethyl)-tetrahydro-pyran-2-yl]-3-triisopropylsilanyloxy-nona-4,6-dienyl ester
477201-02-8
(Diethoxy-phosphoryl)-acetic acid (4E,6E)-(1S,3S,8R)-1-((E)-(1S,2R)-4-iodo-2-methoxy-1,3-dimethyl-but-3-enyl)-4-methyl-8-[(2R,4S)-6-oxo-4-(2-oxo-ethyl)-tetrahydro-pyran-2-yl]-3-triisopropylsilanyloxy-nona-4,6-dienyl ester
(2E,4E)-(R)-6-{(2R,4R,6S)-4-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-6-phenylsulfanyl-tetrahydro-pyran-2-yl}-2-methyl-hepta-2,4-dienoic acid methyl ester
477200-83-2
(2E,4E)-(R)-6-{(2R,4R,6S)-4-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-6-phenylsulfanyl-tetrahydro-pyran-2-yl}-2-methyl-hepta-2,4-dienoic acid methyl ester
(Diethoxy-phosphoryl)-acetic acid (4E,6E)-(1S,3S,8R)-1-((E)-(1S,2R)-4-iodo-2-methoxy-1,3-dimethyl-but-3-enyl)-4-methyl-8-[(2R,4S)-6-oxo-4-(2-oxo-ethyl)-tetrahydro-pyran-2-yl]-3-triisopropylsilanyloxy-nona-4,6-dienyl ester
477201-02-8
(Diethoxy-phosphoryl)-acetic acid (4E,6E)-(1S,3S,8R)-1-((E)-(1S,2R)-4-iodo-2-methoxy-1,3-dimethyl-but-3-enyl)-4-methyl-8-[(2R,4S)-6-oxo-4-(2-oxo-ethyl)-tetrahydro-pyran-2-yl]-3-triisopropylsilanyloxy-nona-4,6-dienyl ester
(1E,8E,10E)-(3R,4R,7S,12R)-12-{(2R,4R,6S)-4-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-6-phenylsulfanyl-tetrahydro-pyran-2-yl}-7-hydroxy-1-iodo-3-methoxy-2,4,8-trimethyl-trideca-1,8,10-trien-5-one
477200-96-7
(1E,8E,10E)-(3R,4R,7S,12R)-12-{(2R,4R,6S)-4-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-6-phenylsulfanyl-tetrahydro-pyran-2-yl}-7-hydroxy-1-iodo-3-methoxy-2,4,8-trimethyl-trideca-1,8,10-trien-5-one
(Diethoxy-phosphoryl)-acetic acid (4E,6E)-(1S,3S,8R)-1-((E)-(1S,2R)-4-iodo-2-methoxy-1,3-dimethyl-but-3-enyl)-4-methyl-8-[(2R,4S)-6-oxo-4-(2-oxo-ethyl)-tetrahydro-pyran-2-yl]-3-triisopropylsilanyloxy-nona-4,6-dienyl ester
477201-02-8
(Diethoxy-phosphoryl)-acetic acid (4E,6E)-(1S,3S,8R)-1-((E)-(1S,2R)-4-iodo-2-methoxy-1,3-dimethyl-but-3-enyl)-4-methyl-8-[(2R,4S)-6-oxo-4-(2-oxo-ethyl)-tetrahydro-pyran-2-yl]-3-triisopropylsilanyloxy-nona-4,6-dienyl ester
(1E,8E,10E)-(3R,4S,5S,7S,12R)-12-{(2R,4R,6S)-4-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-6-phenylsulfanyl-tetrahydro-pyran-2-yl}-1-iodo-3-methoxy-2,4,8-trimethyl-trideca-1,8,10-triene-5,7-diol
477200-97-8
(1E,8E,10E)-(3R,4S,5S,7S,12R)-12-{(2R,4R,6S)-4-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-6-phenylsulfanyl-tetrahydro-pyran-2-yl}-1-iodo-3-methoxy-2,4,8-trimethyl-trideca-1,8,10-triene-5,7-diol
(Diethoxy-phosphoryl)-acetic acid (4E,6E)-(1S,3S,8R)-1-((E)-(1S,2R)-4-iodo-2-methoxy-1,3-dimethyl-but-3-enyl)-4-methyl-8-[(2R,4S)-6-oxo-4-(2-oxo-ethyl)-tetrahydro-pyran-2-yl]-3-triisopropylsilanyloxy-nona-4,6-dienyl ester
477201-02-8
(Diethoxy-phosphoryl)-acetic acid (4E,6E)-(1S,3S,8R)-1-((E)-(1S,2R)-4-iodo-2-methoxy-1,3-dimethyl-but-3-enyl)-4-methyl-8-[(2R,4S)-6-oxo-4-(2-oxo-ethyl)-tetrahydro-pyran-2-yl]-3-triisopropylsilanyloxy-nona-4,6-dienyl ester
(1E,8E,10E)-(3R,4S,5S,7S,12R)-12-{(2R,4R,6S)-4-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-6-phenylsulfanyl-tetrahydro-pyran-2-yl}-1-iodo-3-methoxy-2,4,8-trimethyl-7-triisopropylsilanyloxy-trideca-1,8,10-trien-5-ol
477200-98-9
(1E,8E,10E)-(3R,4S,5S,7S,12R)-12-{(2R,4R,6S)-4-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-6-phenylsulfanyl-tetrahydro-pyran-2-yl}-1-iodo-3-methoxy-2,4,8-trimethyl-7-triisopropylsilanyloxy-trideca-1,8,10-trien-5-ol
(Diethoxy-phosphoryl)-acetic acid (4E,6E)-(1S,3S,8R)-1-((E)-(1S,2R)-4-iodo-2-methoxy-1,3-dimethyl-but-3-enyl)-4-methyl-8-[(2R,4S)-6-oxo-4-(2-oxo-ethyl)-tetrahydro-pyran-2-yl]-3-triisopropylsilanyloxy-nona-4,6-dienyl ester
477201-02-8
(Diethoxy-phosphoryl)-acetic acid (4E,6E)-(1S,3S,8R)-1-((E)-(1S,2R)-4-iodo-2-methoxy-1,3-dimethyl-but-3-enyl)-4-methyl-8-[(2R,4S)-6-oxo-4-(2-oxo-ethyl)-tetrahydro-pyran-2-yl]-3-triisopropylsilanyloxy-nona-4,6-dienyl ester
(diethoxy-phosphoryl)-acetic acid 8-{4-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-6-phenylsulfanyl-tetrahydro-pyran-2-yl}-1-(4-iodo-2-methoxy-1,3-dimethyl-but-3-enyl)-4-methyl-3-triisopropylsilanyloxy-nona-4,6-dienyl ester
477200-99-0
(diethoxy-phosphoryl)-acetic acid 8-{4-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-6-phenylsulfanyl-tetrahydro-pyran-2-yl}-1-(4-iodo-2-methoxy-1,3-dimethyl-but-3-enyl)-4-methyl-3-triisopropylsilanyloxy-nona-4,6-dienyl ester
(Diethoxy-phosphoryl)-acetic acid (4E,6E)-(1S,3S,8R)-1-((E)-(1S,2R)-4-iodo-2-methoxy-1,3-dimethyl-but-3-enyl)-4-methyl-8-[(2R,4S)-6-oxo-4-(2-oxo-ethyl)-tetrahydro-pyran-2-yl]-3-triisopropylsilanyloxy-nona-4,6-dienyl ester
477201-02-8
(Diethoxy-phosphoryl)-acetic acid (4E,6E)-(1S,3S,8R)-1-((E)-(1S,2R)-4-iodo-2-methoxy-1,3-dimethyl-but-3-enyl)-4-methyl-8-[(2R,4S)-6-oxo-4-(2-oxo-ethyl)-tetrahydro-pyran-2-yl]-3-triisopropylsilanyloxy-nona-4,6-dienyl ester
(Diethoxy-phosphoryl)-acetic acid (4E,6E)-(1S,3S,8R)-8-[(2R,4R)-4-(2-hydroxy-ethyl)-6-oxo-tetrahydro-pyran-2-yl]-1-((E)-(1S,2R)-4-iodo-2-methoxy-1,3-dimethyl-but-3-enyl)-4-methyl-3-triisopropylsilanyloxy-nona-4,6-dienyl ester
477201-01-7
(Diethoxy-phosphoryl)-acetic acid (4E,6E)-(1S,3S,8R)-8-[(2R,4R)-4-(2-hydroxy-ethyl)-6-oxo-tetrahydro-pyran-2-yl]-1-((E)-(1S,2R)-4-iodo-2-methoxy-1,3-dimethyl-but-3-enyl)-4-methyl-3-triisopropylsilanyloxy-nona-4,6-dienyl ester
(Diethoxy-phosphoryl)-acetic acid (4E,6E)-(1S,3S,8R)-1-((E)-(1S,2R)-4-iodo-2-methoxy-1,3-dimethyl-but-3-enyl)-4-methyl-8-[(2R,4S)-6-oxo-4-(2-oxo-ethyl)-tetrahydro-pyran-2-yl]-3-triisopropylsilanyloxy-nona-4,6-dienyl ester
477201-02-8
(Diethoxy-phosphoryl)-acetic acid (4E,6E)-(1S,3S,8R)-1-((E)-(1S,2R)-4-iodo-2-methoxy-1,3-dimethyl-but-3-enyl)-4-methyl-8-[(2R,4S)-6-oxo-4-(2-oxo-ethyl)-tetrahydro-pyran-2-yl]-3-triisopropylsilanyloxy-nona-4,6-dienyl ester
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上游原料
(diethoxy-phosphoryl)-acetic acid 8-{4-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-6-phenylsulfanyl-tetrahydro-pyran-2-yl}-1-(4-iodo-2-methoxy-1,3-dimethyl-but-3-enyl)-4-methyl-3-triisopropylsilanyloxy-nona-4,6-dienyl ester (2E,4E)-(R)-6-{(2R,4R,6S)-4-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-6-phenylsulfanyl-tetrahydro-pyran-2-yl}-2-methyl-hepta-2,4-dienal (2R,3R)-N-methoxy-N-methyl (E)-2,4-dimethyl-5-iodo-3-hydroxypent-4-enamide (E)-(5R,6R)-7-(tert-Butyl-dimethyl-silanyloxy)-5-(1-ethoxy-2-iodo-ethoxy)-6-methyl-hept-2-enoic acid methyl ester (1E,8E,10E)-(3R,4R,7S,12R)-12-{(2R,4R,6S)-4-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-6-phenylsulfanyl-tetrahydro-pyran-2-yl}-7-hydroxy-1-iodo-3-methoxy-2,4,8-trimethyl-trideca-1,8,10-trien-5-one (Z)-(5R,6R)-7-(tert-Butyl-dimethyl-silanyloxy)-5-(1-ethoxy-2-iodo-ethoxy)-6-methyl-hept-2-enoic acid methyl ester (1E,8E,10E)-(3R,4S,5S,7S,12R)-12-{(2R,4R,6S)-4-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-6-phenylsulfanyl-tetrahydro-pyran-2-yl}-1-iodo-3-methoxy-2,4,8-trimethyl-7-triisopropylsilanyloxy-trideca-1,8,10-trien-5-ol {(2R,4S,6S)-2-[(R)-2-(tert-Butyl-dimethyl-silanyloxy)-1-methyl-ethyl]-6-phenylsulfanyl-tetrahydro-pyran-4-yl}-acetic acid methyl ester (1E,8E,10E)-(3R,4S,5S,7S,12R)-12-{(2R,4R,6S)-4-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-6-phenylsulfanyl-tetrahydro-pyran-2-yl}-1-iodo-3-methoxy-2,4,8-trimethyl-trideca-1,8,10-triene-5,7-diol 2-{(2R,4R,6S)-2-[(R)-2-(tert-Butyl-dimethyl-silanyloxy)-1-methyl-ethyl]-6-phenylsulfanyl-tetrahydro-pyran-4-yl}-ethanol (R)-2-{(2R,4R,6S)-4-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-6-phenylsulfanyl-tetrahydro-pyran-2-yl}-propan-1-ol (Diethoxy-phosphoryl)-acetic acid (4E,6E)-(1S,3S,8R)-8-[(2R,4R)-4-(2-hydroxy-ethyl)-6-oxo-tetrahydro-pyran-2-yl]-1-((E)-(1S,2R)-4-iodo-2-methoxy-1,3-dimethyl-but-3-enyl)-4-methyl-3-triisopropylsilanyloxy-nona-4,6-dienyl ester (2E,4E)-(R)-6-{(2R,4R,6S)-4-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-6-phenylsulfanyl-tetrahydro-pyran-2-yl}-2-methyl-hepta-2,4-dienoic acid methyl ester (S)-2-{(2R,4R,6S)-4-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-6-phenylsulfanyl-tetrahydro-pyran-2-yl}-propionaldehyde
下游产品
O-triisopropylsilylrhizoxin D
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