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(1R,3S,5S,7S,9R,13R,15S,18S)-7-hydroxy-3-methoxy-18-methyl-13-((E)-4-methylpent-1-enyl)-12,19,20-trioxatricyclo[13.3.1.15,9]icosan-11-one

(1R,3S,5S,7S,9R,13R,15S,18S)-7-hydroxy-3-methoxy-18-methyl-13-((E)-4-methylpent-1-enyl)-12,19,20-trioxatricyclo[13.3.1.15,9]icosan-11-one

CAS号:477974-86-0
英文名:(1R,3S,5S,7S,9R,13R,15S,18S)-7-hydroxy-3-methoxy-18-methyl-13-((E)-4-methylpent-1-enyl)-12,19,20-trioxatricyclo[13.3.1.15,9]icosan-11-one
分子式:C25H42O6
分子量:438.597
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上游原料
{(2S,4S,6R)-6-[(R)-4-benzyloxy-2-methoxybutyl]-4-(tert-butyldiphenylsilanyloxy)tetrahydro-2H-pyran-2-yl}acetonitrile {(2S,4S,6R)-4-(tert-butyldiphenylsilanyloxy)-6-[(R)-4-hydroxy-2-methoxybutyl]-tetrahydro-2H-pyran-2-yl}acetonitrile (2S,5S,6R)-6-{(2S)-3-[(2R,4S,6S)-4-(tert-butyldiphenylsilanyloxy)-6-cyanomethyltetrahydro-2H-pyran-2-yl]-2-methoxypropyl}-5-methyl-5,6-dihydro-2H-pyran-2-carboxylic acid isopropyl ester (4S,5R,7R)-8-{(2R,4S,6S)-6-[2-(4-Methoxy-benzyloxy)-ethyl]-4-triisopropylsilanyloxy-tetrahydro-pyran-2-yl}-4-methyl-octane-1,5,7-triol (1R,3R,5R,9R,13R,15S,18S)-3-methoxy-18-methyl-13-<(E)-4-methylpent-1-enyl>-12,19,20-trioxatricyclo<13.3.1.15,9>icosane-7,11-dione (3R)-1-[(4-methoxybenzyl)oxy]hex-5-en-3-ol (2S,5S,6R)-6-{(2S)-3-[(2R,4S,6S)-4-(tert-butyldiphenylsilanyloxy)-6-cyanomethyltetrahydro-2H-pyran-2-yl]-2-methoxypropyl}-5-methyltetrahydro-2H-pyran-2-carboxylic acid isopropyl ester 2,4,6-trimethylbenzenesulfonic acid (2R,6S)-6-((R)-4-benzyloxy-2-methoxybutyl)-5,6-dihydro-2H-pyran-2-ylmethyl ester {(2S,6S)-6-[(R)-4-benzyloxy-2-methoxybutyl]-5,6-dihydro-2H-pyran-2-yl}acetonitrile {(2S,4S,6S)-6-[(R)-4-benzyloxy-2-methoxybutyl]-4-hydroxytetrahydro-2H-pyran-2-yl}acetonitrile (1R,3S,5R,7R,9R,13R,15S,18S)-7-(tert-butyldiphenylsilanyloxy)-3-methoxy-18-methyl-13-((E)-4-methylpent-1-enyl)-12,19,20-trioxatricyclo[13.3.1.15,9]icosan-11-one ((2R,4R,6R)-6-{(S)-3-[(2R,3S,6S)-6-((E)-(S)-2-Acetoxy-6-methyl-hept-3-enyl)-3-methyl-tetrahydro-pyran-2-yl]-2-methoxy-propyl}-4-triisopropylsilanyloxy-tetrahydro-pyran-2-yl)-acetic acid {(2S,4S,6R)-4-(tert-butyldiphenylsilanyloxy)-6-[(2S)-3-((2R,3S,6S)-6-formyl-3-methyltetrahydro-2H-pyran-2-yl)-2-methoxypropyl]tetrahydro-2H-pyran-2-yl}acetonitrile (5S,6R)-6-((S)-2-Hydroxy-3-{(2R,4S,6S)-6-[2-(4-methoxy-benzyloxy)-ethyl]-4-triisopropylsilanyloxy-tetrahydro-pyran-2-yl}-propyl)-5-methyl-tetrahydro-pyran-2-one {(2S,4S,6R)-4-(tert-butyldiphenylsilanyloxy)-6-[(2S)-3-((2R,3S,6S)-6-((2R,3E)-2-hydroxy-6-methylhept-3-enyl)-3-methyltetrahydro-2H-pyran-2-yl)-2-methoxypropyl]tetrahydro-2H-pyran-2-yl}acetonitrile (5S,6R)-6-((S)-2-Methoxy-3-{(2R,4S,6S)-6-[2-(4-methoxy-benzyloxy)-ethyl]-4-triisopropylsilanyloxy-tetrahydro-pyran-2-yl}-propyl)-5-methyl-tetrahydro-pyran-2-one (E)-1-[(2S,5S,6R)-6-((S)-2-Methoxy-3-{(2R,4S,6S)-6-[2-(4-methoxy-benzyloxy)-ethyl]-4-triisopropylsilanyloxy-tetrahydro-pyran-2-yl}-propyl)-5-methyl-tetrahydro-pyran-2-yl]-6-methyl-hept-3-en-2-one (2S,4S,6S)-2-(tert-Butyl-dimethyl-silanyloxymethyl)-6-[2-(4-methoxy-benzyloxy)-ethyl]-tetrahydro-pyran-4-ol 2-((S)-4-Bromomethyl-3-methyl-pent-4-enyl)-[1,3]dithiane (2S,6R)-2-[2-(4-Methoxy-benzyloxy)-ethyl]-6-((2S,5S)-2,8,8-trimethoxy-5-methyl-4-oxo-octyl)-tetrahydro-pyran-4-one (4R,5S)-8-(tert-Butyl-dimethyl-silanyloxy)-4-hydroxy-1-{(2S,4R,6S)-6-[2-(4-methoxy-benzyloxy)-ethyl]-4-triisopropylsilanyloxy-tetrahydro-pyran-2-yl}-5-methyl-octan-2-one {(2S,4S,6R)-4-(tert-butyldiphenylsilanyloxy)-6-[(2S)-2-methoxy-3-((2R,3S,6S)-3-methyl-6-(oxoethyl)tetrahydro-2H-pyran-2-yl)propyl]tetrahydro-2H-pyran-2-yl}acetonitrile (2R,3S,4E)-3-(dimethylphenylsilanyl)-2-hydroxyhex-4-enoic acid isopropyl ester [4-(tert-butyldiphenylsilanyloxy)-6-(2-methoxy-4-oxobutyl)-tetrahydro-2H-pyran-2-yl]acetonitrile (2R,4R,5S)-8-(tert-Butyl-dimethyl-silanyloxy)-1-{(2R,4S,6S)-6-[2-(4-methoxy-benzyloxy)-ethyl]-4-triisopropylsilanyloxy-tetrahydro-pyran-2-yl}-5-methyl-octane-2,4-diol 2,4,6-Trimethyl-benzenesulfonic acid (2S,3S)-3-(dimethyl-phenyl-silanyl)-2-hydroxy-pent-4-enyl ester (2R,6S)-2-[2-(4-Methoxy-benzyloxy)-ethyl]-4-methylene-6-((2R,5S)-2,8,8-trimethoxy-5-methyl-4-methylene-octyl)-tetrahydro-pyran 1-{(2S,4S,6S)-6-[2-(4-Methoxy-benzyloxy)-ethyl]-4-triisopropylsilanyloxy-tetrahydro-pyran-2-yl}-propan-2-one (1R,3S,5R,7R,9R,13R,15S,18S)-7-(tert-Butyl-diphenyl-silanyloxy)-3-methoxy-18-methyl-13-((E)-4-methyl-pent-1-enyl)-12,19,20-trioxa-tricyclo[13.3.1.15,9]icosan-11-ol (2S,3S)-3-(Dimethyl-phenyl-silanyl)-pent-4-ene-1,2-diol (2R,5S)-8,8-Dimethoxy-1-{(2S,6R)-6-[2-(4-methoxy-benzyloxy)-ethyl]-4-methylene-tetrahydro-pyran-2-yl}-5-methyl-4-methylene-octan-2-ol (2R,5S)-7-([1,3]dithian-2-yl)-1-{(2S,6R)-6-[2-(4-methoxy-benzyloxy)-ethyl]-4-methylene-tetrahydropyran-2-yl}-5-methyl-4-methylene-heptan-2-ol {(2S,4S,6S)-6-[2-(4-Methoxy-benzyloxy)-ethyl]-4-triisopropylsilanyloxy-tetrahydro-pyran-2-yl}-methanol (2S,3S)-2,4,6-trimethylbenzenesulfonic acid 3-(dimethylphenylsilanyl)-2-(trimethylsilanyloxy)pent-4-enyl ester (R)-tert-butyl(1-(4-methoxybenzyloxy)hex-5-en-3-yloxy)dimethylsilane Triisopropyl-{(2S,4R,6R)-2-[2-(4-methoxy-benzyloxy)-ethyl]-6-prop-2-ynyl-tetrahydro-pyran-4-yloxy}-silane