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(tert-butyl)((S,3Z,5E)-4-ethyl-6-((2R,6R)-6-isopropoxy-3,6-dihydro-2H-pyran-2-yl)-2-methylhexa-3,5-dienyloxy)(diphenyl)silane

(tert-butyl)((S,3Z,5E)-4-ethyl-6-((2R,6R)-6-isopropoxy-3,6-dihydro-2H-pyran-2-yl)-2-methylhexa-3,5-dienyloxy)(diphenyl)silane

CAS号：486444-32-0

英文名：(tert-butyl)((S,3Z,5E)-4-ethyl-6-((2R,6R)-6-isopropoxy-3,6-dihydro-2H-pyran-2-yl)-2-methylhexa-3,5-dienyloxy)(diphenyl)silane

分子式：C33H46O3Si

分子量：518.802

合成路线

(R,Z)-ethyl 4-(2,2-dimethyl-1,3-dioxolan-4-yl)but-2-enoate

(R,Z)-ethyl 4-(2,2-dimethyl-1,3-dioxolan-4-yl)but-2-enoate

(tert-butyl)((S,3Z,5E)-4-ethyl-6-((2R,6R)-6-isopropoxy-3,6-dihydro-2H-pyran-2-yl)-2-methylhexa-3,5-dienyloxy)(diphenyl)silane

(tert-butyl)((S,3Z,5E)-4-ethyl-6-((2R,6R)-6-isopropoxy-3,6-dihydro-2H-pyran-2-yl)-2-methylhexa-3,5-dienyloxy)(diphenyl)silane

(S,Z)-ethyl 5-(tert-butyl(diphenyl)silyloxy)-2-ethyl-4-methylpent-2-enoate

(S,Z)-ethyl 5-(tert-butyl(diphenyl)silyloxy)-2-ethyl-4-methylpent-2-enoate

(tert-butyl)((S,3Z,5E)-4-ethyl-6-((2R,6R)-6-isopropoxy-3,6-dihydro-2H-pyran-2-yl)-2-methylhexa-3,5-dienyloxy)(diphenyl)silane

(tert-butyl)((S,3Z,5E)-4-ethyl-6-((2R,6R)-6-isopropoxy-3,6-dihydro-2H-pyran-2-yl)-2-methylhexa-3,5-dienyloxy)(diphenyl)silane

2H-Pyran-2-one, 5,6-dihydro-6-(hydroxymethyl)-, (6R)-

2H-Pyran-2-one, 5,6-dihydro-6-(hydroxymethyl)-, (6R)-

(tert-butyl)((S,3Z,5E)-4-ethyl-6-((2R,6R)-6-isopropoxy-3,6-dihydro-2H-pyran-2-yl)-2-methylhexa-3,5-dienyloxy)(diphenyl)silane

(tert-butyl)((S,3Z,5E)-4-ethyl-6-((2R,6R)-6-isopropoxy-3,6-dihydro-2H-pyran-2-yl)-2-methylhexa-3,5-dienyloxy)(diphenyl)silane

(2R,6R)-(+)-(6-isopropoxy-3,6-dihydro-2H-6-pyran-2-yl)methanol

(2R,6R)-(+)-(6-isopropoxy-3,6-dihydro-2H-6-pyran-2-yl)methanol

(tert-butyl)((S,3Z,5E)-4-ethyl-6-((2R,6R)-6-isopropoxy-3,6-dihydro-2H-pyran-2-yl)-2-methylhexa-3,5-dienyloxy)(diphenyl)silane

(tert-butyl)((S,3Z,5E)-4-ethyl-6-((2R,6R)-6-isopropoxy-3,6-dihydro-2H-pyran-2-yl)-2-methylhexa-3,5-dienyloxy)(diphenyl)silane

(R)-6-((tert-butyl(dimethyl)silyloxy)methyl)-5,6-dihydropyran-2-one

(R)-6-((tert-butyl(dimethyl)silyloxy)methyl)-5,6-dihydropyran-2-one

(tert-butyl)((S,3Z,5E)-4-ethyl-6-((2R,6R)-6-isopropoxy-3,6-dihydro-2H-pyran-2-yl)-2-methylhexa-3,5-dienyloxy)(diphenyl)silane

(tert-butyl)((S,3Z,5E)-4-ethyl-6-((2R,6R)-6-isopropoxy-3,6-dihydro-2H-pyran-2-yl)-2-methylhexa-3,5-dienyloxy)(diphenyl)silane

(tert-butyl)[((2R,6R)-6-isopropoxy-3,6-dihydro-2H-pyran-2-yl)methoxy](dimethyl)silane

(tert-butyl)[((2R,6R)-6-isopropoxy-3,6-dihydro-2H-pyran-2-yl)methoxy](dimethyl)silane

(tert-butyl)((S,3Z,5E)-4-ethyl-6-((2R,6R)-6-isopropoxy-3,6-dihydro-2H-pyran-2-yl)-2-methylhexa-3,5-dienyloxy)(diphenyl)silane

(tert-butyl)((S,3Z,5E)-4-ethyl-6-((2R,6R)-6-isopropoxy-3,6-dihydro-2H-pyran-2-yl)-2-methylhexa-3,5-dienyloxy)(diphenyl)silane

(S,Z)-(4-(bromomethyl)-2-methylhex-3-en-1-yloxy)(tert-butyl)(diphenyl)silane

(S,Z)-(4-(bromomethyl)-2-methylhex-3-en-1-yloxy)(tert-butyl)(diphenyl)silane

(tert-butyl)((S,3Z,5E)-4-ethyl-6-((2R,6R)-6-isopropoxy-3,6-dihydro-2H-pyran-2-yl)-2-methylhexa-3,5-dienyloxy)(diphenyl)silane

(tert-butyl)((S,3Z,5E)-4-ethyl-6-((2R,6R)-6-isopropoxy-3,6-dihydro-2H-pyran-2-yl)-2-methylhexa-3,5-dienyloxy)(diphenyl)silane

(S,Z)-5-(tert-butyl(diphenyl)silyloxy)-2-ethyl-4-methylpent-2-en-1-ol

(S,Z)-5-(tert-butyl(diphenyl)silyloxy)-2-ethyl-4-methylpent-2-en-1-ol

(tert-butyl)((S,3Z,5E)-4-ethyl-6-((2R,6R)-6-isopropoxy-3,6-dihydro-2H-pyran-2-yl)-2-methylhexa-3,5-dienyloxy)(diphenyl)silane

(tert-butyl)((S,3Z,5E)-4-ethyl-6-((2R,6R)-6-isopropoxy-3,6-dihydro-2H-pyran-2-yl)-2-methylhexa-3,5-dienyloxy)(diphenyl)silane

上游原料

(tert-butyl)[((2R,6R)-6-isopropoxy-3,6-dihydro-2H-pyran-2-yl)methoxy](dimethyl)silane (2R,6R)-(+)-(6-isopropoxy-3,6-dihydro-2H-6-pyran-2-yl)methanol (S,Z)-ethyl 5-(tert-butyl(diphenyl)silyloxy)-2-ethyl-4-methylpent-2-enoate (S,Z)-5-(tert-butyl(diphenyl)silyloxy)-2-ethyl-4-methylpent-2-en-1-ol (R,Z)-ethyl 4-(2,2-dimethyl-1,3-dioxolan-4-yl)but-2-enoate (S,Z)-(4-(bromomethyl)-2-methylhex-3-en-1-yloxy)(tert-butyl)(diphenyl)silane (R)-6-((tert-butyl(dimethyl)silyloxy)methyl)-5,6-dihydropyran-2-one

下游产品

(2R,6R)-2-((S,1E,3Z)-3-ethyl-6-iodo-5-methylhexa-1,3-dienyl)-6-isopropoxy-3,6-dihydro-2H-pyran (3Z,5E)-(S)-4-Ethyl-6-((2R,6R)-6-isopropoxy-3,6-dihydro-2H-pyran-2-yl)-2-methyl-hexa-3,5-dien-1-ol