百科

(3S,4S,5S,6R)-6-[(3,4-dimethoxybenzyl)oxy]-4-hydroxy-5-methyl-3-[(tert-butyldimethylsilyl)oxy]oct-1-ene

(3S,4S,5S,6R)-6-[(3,4-dimethoxybenzyl)oxy]-4-hydroxy-5-methyl-3-[(tert-butyldimethylsilyl)oxy]oct-1-ene

CAS号：488099-62-3

英文名：(3S,4S,5S,6R)-6-[(3,4-dimethoxybenzyl)oxy]-4-hydroxy-5-methyl-3-[(tert-butyldimethylsilyl)oxy]oct-1-ene

分子式：C24H42O5Si

分子量：438.673

合成路线

2(R),3(R) methyl 3-hydroxy-2-methylpentanoate

2(R),3(R) methyl 3-hydroxy-2-methylpentanoate

(3S,4S,5S,6R)-6-[(3,4-dimethoxybenzyl)oxy]-4-hydroxy-5-methyl-3-[(tert-butyldimethylsilyl)oxy]oct-1-ene

(3S,4S,5S,6R)-6-[(3,4-dimethoxybenzyl)oxy]-4-hydroxy-5-methyl-3-[(tert-butyldimethylsilyl)oxy]oct-1-ene

133098-13-2

(3S,4S,5S,6R)-6-[(3,4-dimethoxybenzyl)oxy]-4-hydroxy-5-methyl-3-[(tert-butyldimethylsilyl)oxy]oct-1-ene

(3S,4S,5S,6R)-6-[(3,4-dimethoxybenzyl)oxy]-4-hydroxy-5-methyl-3-[(tert-butyldimethylsilyl)oxy]oct-1-ene

(2S,3R)-3-(3,4-Dimethoxy-benzyloxy)-2-methyl-pentan-1-ol

(2S,3R)-3-(3,4-Dimethoxy-benzyloxy)-2-methyl-pentan-1-ol

(3S,4S,5S,6R)-6-[(3,4-dimethoxybenzyl)oxy]-4-hydroxy-5-methyl-3-[(tert-butyldimethylsilyl)oxy]oct-1-ene

(3S,4S,5S,6R)-6-[(3,4-dimethoxybenzyl)oxy]-4-hydroxy-5-methyl-3-[(tert-butyldimethylsilyl)oxy]oct-1-ene

(2S,3R,1'S)-1,3-O-[1'-(3,4-dimethoxyphenyl)methylidene]-2-methylpentane

(2S,3R,1'S)-1,3-O-[1'-(3,4-dimethoxyphenyl)methylidene]-2-methylpentane

(3S,4S,5S,6R)-6-[(3,4-dimethoxybenzyl)oxy]-4-hydroxy-5-methyl-3-[(tert-butyldimethylsilyl)oxy]oct-1-ene

(3S,4S,5S,6R)-6-[(3,4-dimethoxybenzyl)oxy]-4-hydroxy-5-methyl-3-[(tert-butyldimethylsilyl)oxy]oct-1-ene

上游原料

(2S,3R)-3-(3,4-Dimethoxy-benzyloxy)-2-methyl-pentan-1-ol 2(R),3(R) methyl 3-hydroxy-2-methylpentanoate (2S,3R,1'S)-1,3-O-[1'-(3,4-dimethoxyphenyl)methylidene]-2-methylpentane

下游产品

2'-chloroethyl (2R,3S,4S,6R,7R,8E,10S)-5,11-bisoxo-2,7-bis[(tert-butyldimethylsilyl)oxy]-3-methoxy-4,6,8,10-tetramethyldodec-8-enoate (2R,3S,4S,5R)-5-[(3,4-dimethoxybenzyl)oxy]-3-methoxy-4-methyl-2-[(tert-butyldimethylsilyl)oxy]heptanal methyl (2R,3S,4S,6R,7R,8E,10S,11R)-11-[(3,4-dimethoxybenzyl)oxy]-7-hydroxy-3-methoxy-5-oxo-2-[(tert-butyldimethylsilyl)oxy]-4,6,8,10-tetramethyldodec-8-enoate methyl (2R,3S,4S,6R,7R,8E,10S)-5,11-bisoxo-2,7-bis[(tert-butyldimethylsilyl)oxy]-3-methoxy-4,6,8,10-tetramethyldodec-8-enoate methyl (2R,3S,4S)-3-methoxy-4-methyl-2-[(tert-butyldimethylsilyl)oxy]-5-oxoheptanoate 2'-chloroethyl (2R,3S,4S,5R)-5-[(3,4-dimethoxybenzyl)oxy]-3-methoxy-4-methyl-2-[(tert-butyldimethylsilyl)oxy]heptanoate