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ethyl (1R,4R)-5-hydroxy-8,8-dimethyl-7,9-dioxatricyclo[4.3.0.0^[2,4]]nonane-4-carboxylate

ethyl (1R,4R)-5-hydroxy-8,8-dimethyl-7,9-dioxatricyclo[4.3.0.0^[2,4]]nonane-4-carboxylate

CAS号：495397-74-5

英文名：ethyl (1R,4R)-5-hydroxy-8,8-dimethyl-7,9-dioxatricyclo[4.3.0.0^[2,4]]nonane-4-carboxylate

分子式：C12H18O5

分子量：242.268

合成路线

ethyl 3-((4R,5R)-2,2-dimethyl-5-vinyl-1,3-dioxolan-4-yl)-3-oxo-2-(phenyl-l3-iodaneylidene)propanoate

ethyl 3-((4R,5R)-2,2-dimethyl-5-vinyl-1,3-dioxolan-4-yl)-3-oxo-2-(phenyl-l3-iodaneylidene)propanoate

ethyl (1R,4R)-5-hydroxy-8,8-dimethyl-7,9-dioxatricyclo[4.3.0.0^[2,4]]nonane-4-carboxylate

ethyl (1R,4R)-5-hydroxy-8,8-dimethyl-7,9-dioxatricyclo[4.3.0.0^[2,4]]nonane-4-carboxylate

131064-98-7

ethyl (1R,4R)-5-hydroxy-8,8-dimethyl-7,9-dioxatricyclo[4.3.0.0^[2,4]]nonane-4-carboxylate

ethyl (1R,4R)-5-hydroxy-8,8-dimethyl-7,9-dioxatricyclo[4.3.0.0^[2,4]]nonane-4-carboxylate

methyl 2,3-O-isopropylidene-D-lyxofuranoside

methyl 2,3-O-isopropylidene-D-lyxofuranoside

ethyl (1R,4R)-5-hydroxy-8,8-dimethyl-7,9-dioxatricyclo[4.3.0.0^[2,4]]nonane-4-carboxylate

ethyl (1R,4R)-5-hydroxy-8,8-dimethyl-7,9-dioxatricyclo[4.3.0.0^[2,4]]nonane-4-carboxylate

(3aS,4S,6aR)-4-(iodomethyl)-6-methoxy-2,2-dimethyltetrahydrofuro[3,4-d][1,3]dioxole

(3aS,4S,6aR)-4-(iodomethyl)-6-methoxy-2,2-dimethyltetrahydrofuro[3,4-d][1,3]dioxole

ethyl (1R,4R)-5-hydroxy-8,8-dimethyl-7,9-dioxatricyclo[4.3.0.0^[2,4]]nonane-4-carboxylate

ethyl (1R,4R)-5-hydroxy-8,8-dimethyl-7,9-dioxatricyclo[4.3.0.0^[2,4]]nonane-4-carboxylate

上游原料

ethyl 3-((4R,5R)-2,2-dimethyl-5-vinyl-1,3-dioxolan-4-yl)-3-oxo-2-(phenyl-l3-iodaneylidene)propanoate methyl 2,3-O-isopropylidene-D-lyxofuranoside (3aS,4S,6aR)-4-(iodomethyl)-6-methoxy-2,2-dimethyltetrahydrofuro[3,4-d][1,3]dioxole

下游产品

(1R,2S,5S,3R,4R)-1-ethoxycarbonyl-2,3-O-isopropylidene-2,3-dihydroxy-4-(hydroxymethyl)bicyclo[3.1.0]hexane ethyl (2R,5R)-5-[[(tert-butyldiphenylsilyl)oxy]methyl]-8,8-dimethyl-7,9-dioxatricyclo[4.3.0.02,4]nonane-2-carboxylate (1R,2S,5S,3R,4R)-1-azidocarbonyl-4-[(tert-butyldiphenylsilyloxy)methyl]-2,3-O-isopropylidene-2,3-dihydroxybicyclo[3.1.0]hexane (1S,2S,3R,4R,5R)-1-[(trityloxy)methyl]bicyclo[3.1.0]hexane-2,3,4-triol (1R,2S,4S,5S,3R)-1-ethoxycarbonyl-4-formyl-2,3-O-isopropylidene-2,3-dihydroxybicyclo[3.1.0]hexane (1R,2S,5S,3R,4R)-1-ethoxycarbonyl-4-cyano-2,3-O-isopropylidene-2,3-dihydroxybicyclo[3.1.0]hexane ethyl (2R,5R)-5-hydroxy-8,8-dimethyl-7,9-dioxatricyclo[4.3.0.0^[2,4]]nonane-2-carboxylate (1R,2S,5S,3R,4R)-4-[(tert-butyldiphenylsilyloxy)methyl]-2,3-O-isopropylidene-2,3-dihydroxybicyclo[3.1.0]hexane-1-carboxylic acid (1R,2S,5S,3R,4R)-1-amino-4-[(tert-butyldiphenylsilyloxy)methyl]-2,3-O-isopropylidene-2,3-dihydroxybicyclo[3.1.0]hexane