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(3S,4S,6S,8R,10S,11R)-12-(benzyloxy)-3,11-bis(methoxymethoxy)-4,6,8,10-tetramethyldodecanal

(3S,4S,6S,8R,10S,11R)-12-(benzyloxy)-3,11-bis(methoxymethoxy)-4,6,8,10-tetramethyldodecanal

CAS号：501419-35-8

英文名：(3S,4S,6S,8R,10S,11R)-12-(benzyloxy)-3,11-bis(methoxymethoxy)-4,6,8,10-tetramethyldodecanal

分子式：C27H46O6

分子量：466.651

合成路线

3S,5,7S,9S-tetramethyl-11-benzyloxy-1-paramethoxybenzyloxy-2R,10R-dihydroxy-4E-undecene

3S,5,7S,9S-tetramethyl-11-benzyloxy-1-paramethoxybenzyloxy-2R,10R-dihydroxy-4E-undecene

(3S,4S,6S,8R,10S,11R)-12-(benzyloxy)-3,11-bis(methoxymethoxy)-4,6,8,10-tetramethyldodecanal

(3S,4S,6S,8R,10S,11R)-12-(benzyloxy)-3,11-bis(methoxymethoxy)-4,6,8,10-tetramethyldodecanal

(+)-(2S,3R)-4-benzyloxy-3-(tert-butyldimethylsiloxy)-2-methylbutan-1-ol

(+)-(2S,3R)-4-benzyloxy-3-(tert-butyldimethylsiloxy)-2-methylbutan-1-ol

(3S,4S,6S,8R,10S,11R)-12-(benzyloxy)-3,11-bis(methoxymethoxy)-4,6,8,10-tetramethyldodecanal

(3S,4S,6S,8R,10S,11R)-12-(benzyloxy)-3,11-bis(methoxymethoxy)-4,6,8,10-tetramethyldodecanal

(2S,3R)-3-{[tert-butyl(dimethyl)silyl]oxy}-4-[(4-methoxybenzyl)oxy]-2-methylbutan-1-ol

(2S,3R)-3-{[tert-butyl(dimethyl)silyl]oxy}-4-[(4-methoxybenzyl)oxy]-2-methylbutan-1-ol

(3S,4S,6S,8R,10S,11R)-12-(benzyloxy)-3,11-bis(methoxymethoxy)-4,6,8,10-tetramethyldodecanal

(3S,4S,6S,8R,10S,11R)-12-(benzyloxy)-3,11-bis(methoxymethoxy)-4,6,8,10-tetramethyldodecanal

1-para-methoxybenzyloxy-2R-tert-butyldimethylsiloxy-3S-methyl-4-hexyne

1-para-methoxybenzyloxy-2R-tert-butyldimethylsiloxy-3S-methyl-4-hexyne

(3S,4S,6S,8R,10S,11R)-12-(benzyloxy)-3,11-bis(methoxymethoxy)-4,6,8,10-tetramethyldodecanal

(3S,4S,6S,8R,10S,11R)-12-(benzyloxy)-3,11-bis(methoxymethoxy)-4,6,8,10-tetramethyldodecanal

3R-(tert-butyl-dimethylsilanyloxy)-4-(4-methoxy-benzyloxy)-2R-methyl-butyric acid methyl ester

3R-(tert-butyl-dimethylsilanyloxy)-4-(4-methoxy-benzyloxy)-2R-methyl-butyric acid methyl ester

(3S,4S,6S,8R,10S,11R)-12-(benzyloxy)-3,11-bis(methoxymethoxy)-4,6,8,10-tetramethyldodecanal

(3S,4S,6S,8R,10S,11R)-12-(benzyloxy)-3,11-bis(methoxymethoxy)-4,6,8,10-tetramethyldodecanal

5R-tert-butyldimethylsiloxy-2S,4S-dimethyl-6-benzyloxy-1-iodohexane

5R-tert-butyldimethylsiloxy-2S,4S-dimethyl-6-benzyloxy-1-iodohexane

(3S,4S,6S,8R,10S,11R)-12-(benzyloxy)-3,11-bis(methoxymethoxy)-4,6,8,10-tetramethyldodecanal

(3S,4S,6S,8R,10S,11R)-12-(benzyloxy)-3,11-bis(methoxymethoxy)-4,6,8,10-tetramethyldodecanal

1-para-methoxybenzyloxy-2R-tert-butyldimethylsiloxy-3S-methyl-5E-iodohexene

1-para-methoxybenzyloxy-2R-tert-butyldimethylsiloxy-3S-methyl-5E-iodohexene

(3S,4S,6S,8R,10S,11R)-12-(benzyloxy)-3,11-bis(methoxymethoxy)-4,6,8,10-tetramethyldodecanal

(3S,4S,6S,8R,10S,11R)-12-(benzyloxy)-3,11-bis(methoxymethoxy)-4,6,8,10-tetramethyldodecanal

3S,5,7S,9S-tetramethyl-11-benzyloxy-1-paramethoxybenzyloxy-2R,10R-bis-(tert-butyldimethylsiloxy)-4E-undecene

3S,5,7S,9S-tetramethyl-11-benzyloxy-1-paramethoxybenzyloxy-2R,10R-bis-(tert-butyldimethylsiloxy)-4E-undecene

(3S,4S,6S,8R,10S,11R)-12-(benzyloxy)-3,11-bis(methoxymethoxy)-4,6,8,10-tetramethyldodecanal

(3S,4S,6S,8R,10S,11R)-12-(benzyloxy)-3,11-bis(methoxymethoxy)-4,6,8,10-tetramethyldodecanal

2R,10R-bis-(tert-butyldimethylsiloxy)-3S,5S,7R,9S-tetramethyl-11-benzyloxy-1-paramethoxybenzyloxy-undecene

2R,10R-bis-(tert-butyldimethylsiloxy)-3S,5S,7R,9S-tetramethyl-11-benzyloxy-1-paramethoxybenzyloxy-undecene

(3S,4S,6S,8R,10S,11R)-12-(benzyloxy)-3,11-bis(methoxymethoxy)-4,6,8,10-tetramethyldodecanal

(3S,4S,6S,8R,10S,11R)-12-(benzyloxy)-3,11-bis(methoxymethoxy)-4,6,8,10-tetramethyldodecanal

2R,10R-bis-(tert-butyldimethylsiloxy)-3S,5S,7R,9S-tetramethyl-11-benzyloxy-1-hydroxy-undecene

2R,10R-bis-(tert-butyldimethylsiloxy)-3S,5S,7R,9S-tetramethyl-11-benzyloxy-1-hydroxy-undecene

(3S,4S,6S,8R,10S,11R)-12-(benzyloxy)-3,11-bis(methoxymethoxy)-4,6,8,10-tetramethyldodecanal

(3S,4S,6S,8R,10S,11R)-12-(benzyloxy)-3,11-bis(methoxymethoxy)-4,6,8,10-tetramethyldodecanal

上游原料

3R-(tert-butyl-dimethylsilanyloxy)-4-(4-methoxy-benzyloxy)-2R-methyl-butyric acid methyl ester (2S,3R)-3-{[tert-butyl(dimethyl)silyl]oxy}-4-[(4-methoxybenzyl)oxy]-2-methylbutan-1-ol 2R,10R-bis-(tert-butyldimethylsiloxy)-3S,5S,7R,9S-tetramethyl-11-benzyloxy-1-paramethoxybenzyloxy-undecene 1-para-methoxybenzyloxy-2R-tert-butyldimethylsiloxy-3S-methyl-4-hexyne (+)-(2S,3R)-4-benzyloxy-3-(tert-butyldimethylsiloxy)-2-methylbutan-1-ol 5R-tert-butyldimethylsiloxy-2S,4S-dimethyl-6-benzyloxy-1-iodohexane 2R,10R-bis-(tert-butyldimethylsiloxy)-3S,5S,7R,9S-tetramethyl-11-benzyloxy-1-hydroxy-undecene 3S,5,7S,9S-tetramethyl-11-benzyloxy-1-paramethoxybenzyloxy-2R,10R-dihydroxy-4E-undecene 3S,5,7S,9S-tetramethyl-11-benzyloxy-1-paramethoxybenzyloxy-2R,10R-bis-(tert-butyldimethylsiloxy)-4E-undecene 1-para-methoxybenzyloxy-2R-tert-butyldimethylsiloxy-3S-methyl-5E-iodohexene

下游产品

(1R,2R)-2-(6-cyano-16-methoxycarbonyl-(7R,15S)-bis-methoxymethoxy-(8S,10R,12S,14S)-tetramethyl-(1S)-hydroxy-hexadeca-(3E,5Z)-dienyl)-cyclopentanecarboxylic acid methyl ester (1R,2R)-2-[(7R,15S)-dihydroxy-16-methoxycarbonyl-(8S,10R,12S,14S)-tetramethyl-(1S)-triisopropylsilanyloxy-hexanedec-(3E)-en-5-ynyl]cyclopentanecarboxylic acid methyl ester methyl (3S,4S,6S,8R,10S,11R)-3,11-bis(methoxymethoxy)-4,6,8,10-tetramethyl-12-oxododecanoate (1R,2R)-2-(6-cyano-(7R,15S)-dihydroxy-16-methoxycabonyl-(8S,10R,12S,14S)-tetramethyl-(1S)-triisopropylsilanyloxy-hexadeca-(3E,5Z)-dienyl)-cyclopentane carboxylic acid methyl ester (1R,2R)-2-[(7R,15S)-dihydroxy-6-iodo-16-methoxycarbonyl-(8S,10R,12S,14S)-tetramethyl-(1S)-triisopropylsilanyloxy-hexadeca-(3E,5E)-dienyl]-cyclopentanecarboxylic acid methyl ester 抗螺旋体链丝菌素 methyl (3S,4S,6S,8R,10S,11R)-3,11-bis(methoxymethoxy)-4,6,8,10-tetramethyltridec-12-ynoate (1R,2R)-2-[(7R,15S)-diacetoxy-16-methoxycarbonyl-(8S,10R,12S,14S)-tetramethyl-(1S)-triisopropylsilanyloxy-hexadec-(3E)-en-5-ynyl]-cyclopentanecarboxylic acid methyl ester