百科

(E,5S,11S,12R,15R,16R,19R,20R)-11,20-di(methoxymethoxy)-12,15:16,19-diepoxy-21-heptacosen-26-yn-5-ol

(E,5S,11S,12R,15R,16R,19R,20R)-11,20-di(methoxymethoxy)-12,15:16,19-diepoxy-21-heptacosen-26-yn-5-ol

CAS号：503603-99-4

英文名：(E,5S,11S,12R,15R,16R,19R,20R)-11,20-di(methoxymethoxy)-12,15:16,19-diepoxy-21-heptacosen-26-yn-5-ol

分子式：C31H54O7

分子量：538.756

合成路线

(4R,5R,8S,9S,15S)-4,5,15-tri(tert-butyldimethylsilyloxy)-8-(p-toluenesulfonoxy)-9-(methoxymethoxy)-1-nonadecanol

(4R,5R,8S,9S,15S)-4,5,15-tri(tert-butyldimethylsilyloxy)-8-(p-toluenesulfonoxy)-9-(methoxymethoxy)-1-nonadecanol

(E,5S,11S,12R,15R,16R,19R,20R)-11,20-di(methoxymethoxy)-12,15:16,19-diepoxy-21-heptacosen-26-yn-5-ol

(E,5S,11S,12R,15R,16R,19R,20R)-11,20-di(methoxymethoxy)-12,15:16,19-diepoxy-21-heptacosen-26-yn-5-ol

上游原料

(4R,5R,8S,9S,15S)-4,5,15-tri(tert-butyldimethylsilyloxy)-8-(p-toluenesulfonoxy)-9-(methoxymethoxy)-1-nonadecanol

下游产品

(S)-3-{(4E,11E)-(R)-13-[(2R,5R,2'R,5'R)-5'-((1S,7S)-7-Hydroxy-1-methoxymethoxy-undecyl)-octahydro-[2,2']bifuranyl-5-yl]-13-methoxymethoxy-trideca-4,11-dien-6-ynyl}-5-methyl-5H-furan-2-one (S)-3-{(R)-13-[(2R,5R,2'R,5'R)-5'-((1S,7S)-7-Hydroxy-1-methoxymethoxy-undecyl)-octahydro-[2,2']bifuranyl-5-yl]-13-methoxymethoxy-tridecyl}-5-methyl-5H-furan-2-one bullanin