百科

ethyl (1S,3R,4R,5R,6R,7R)-3-{5,6-dimethyl-7-ethyl-6-hydroxy-4-(4-methoxybenzyloxy)-2,8-dioxabicyclo[3.3.0]oct-3-yl}-prop-2-enoate

ethyl (1S,3R,4R,5R,6R,7R)-3-{5,6-dimethyl-7-ethyl-6-hydroxy-4-(4-methoxybenzyloxy)-2,8-dioxabicyclo[3.3.0]oct-3-yl}-prop-2-enoate

CAS号：536737-82-3

英文名：ethyl (1S,3R,4R,5R,6R,7R)-3-{5,6-dimethyl-7-ethyl-6-hydroxy-4-(4-methoxybenzyloxy)-2,8-dioxabicyclo[3.3.0]oct-3-yl}-prop-2-enoate

分子式：C23H32O7

分子量：420.496

合成路线

(2RS,3R,4R,5R)-3-[(2R,3R)-2,3-dihydroxy-2-pentyl]-5-(triisopropylsiloxymethyl)-2-methoxy-4-(4-methoxybenzyloxy)-3-methyloxolane

(2RS,3R,4R,5R)-3-[(2R,3R)-2,3-dihydroxy-2-pentyl]-5-(triisopropylsiloxymethyl)-2-methoxy-4-(4-methoxybenzyloxy)-3-methyloxolane

ethyl (1S,3R,4R,5R,6R,7R)-3-{5,6-dimethyl-7-ethyl-6-hydroxy-4-(4-methoxybenzyloxy)-2,8-dioxabicyclo[3.3.0]oct-3-yl}-prop-2-enoate

ethyl (1S,3R,4R,5R,6R,7R)-3-{5,6-dimethyl-7-ethyl-6-hydroxy-4-(4-methoxybenzyloxy)-2,8-dioxabicyclo[3.3.0]oct-3-yl}-prop-2-enoate

上游原料

(2RS,3R,4R,5R)-3-[(2R,3R)-2,3-dihydroxy-2-pentyl]-5-(triisopropylsiloxymethyl)-2-methoxy-4-(4-methoxybenzyloxy)-3-methyloxolane

下游产品

(E)-3-((2R,3R,3aR,4R,5R,6aS)-5-Ethyl-3,4-dihydroxy-3a,4-dimethyl-hexahydro-furo[2,3-b]furan-2-yl)-propenal (1S,3R,4R,5R,6R,7R)-3-(3-acetoxyprop-1(E)-enyl)-4,6-bis(trimethylsiloxy)-5,6-dimethyl-7-ethyl-2,8-dioxabicyclo[3.3.0]octane