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(1S,3R,4R,5R,6R,7R)-3-(3-acetoxyprop-1(E)-enyl)-4,6-bis(trimethylsiloxy)-5,6-dimethyl-7-ethyl-2,8-dioxabicyclo[3.3.0]octane

(1S,3R,4R,5R,6R,7R)-3-(3-acetoxyprop-1(E)-enyl)-4,6-bis(trimethylsiloxy)-5,6-dimethyl-7-ethyl-2,8-dioxabicyclo[3.3.0]octane

CAS号：536737-91-4

英文名：(1S,3R,4R,5R,6R,7R)-3-(3-acetoxyprop-1(E)-enyl)-4,6-bis(trimethylsiloxy)-5,6-dimethyl-7-ethyl-2,8-dioxabicyclo[3.3.0]octane

分子式：C21H40O6Si2

分子量：444.71

合成路线

(2RS,3R,4R,5R)-3-[(2R,3R)-2,3-dihydroxy-2-pentyl]-5-(triisopropylsiloxymethyl)-2-methoxy-4-(4-methoxybenzyloxy)-3-methyloxolane

(2RS,3R,4R,5R)-3-[(2R,3R)-2,3-dihydroxy-2-pentyl]-5-(triisopropylsiloxymethyl)-2-methoxy-4-(4-methoxybenzyloxy)-3-methyloxolane

(1S,3R,4R,5R,6R,7R)-3-(3-acetoxyprop-1(E)-enyl)-4,6-bis(trimethylsiloxy)-5,6-dimethyl-7-ethyl-2,8-dioxabicyclo[3.3.0]octane

(1S,3R,4R,5R,6R,7R)-3-(3-acetoxyprop-1(E)-enyl)-4,6-bis(trimethylsiloxy)-5,6-dimethyl-7-ethyl-2,8-dioxabicyclo[3.3.0]octane

(2S,3R,3aR,4R,5R,6aR)-5-Ethyl-4-hydroxy-3-(4-methoxy-benzyloxy)-3a,4-dimethyl-hexahydro-furo[2,3-b]furan-2-carbaldehyde

(2S,3R,3aR,4R,5R,6aR)-5-Ethyl-4-hydroxy-3-(4-methoxy-benzyloxy)-3a,4-dimethyl-hexahydro-furo[2,3-b]furan-2-carbaldehyde

(1S,3R,4R,5R,6R,7R)-3-(3-acetoxyprop-1(E)-enyl)-4,6-bis(trimethylsiloxy)-5,6-dimethyl-7-ethyl-2,8-dioxabicyclo[3.3.0]octane

(1S,3R,4R,5R,6R,7R)-3-(3-acetoxyprop-1(E)-enyl)-4,6-bis(trimethylsiloxy)-5,6-dimethyl-7-ethyl-2,8-dioxabicyclo[3.3.0]octane

(1S,3R,4R,5R,6R,7R)-5,6-dimethyl-7-ethyl-4-(4-methoxybenzyloxy)-3-(triisopropylsiloxymethyl)-2,8-dioxabicyclo[3.3.0]octan-6-ol

(1S,3R,4R,5R,6R,7R)-5,6-dimethyl-7-ethyl-4-(4-methoxybenzyloxy)-3-(triisopropylsiloxymethyl)-2,8-dioxabicyclo[3.3.0]octan-6-ol

(1S,3R,4R,5R,6R,7R)-3-(3-acetoxyprop-1(E)-enyl)-4,6-bis(trimethylsiloxy)-5,6-dimethyl-7-ethyl-2,8-dioxabicyclo[3.3.0]octane

(1S,3R,4R,5R,6R,7R)-3-(3-acetoxyprop-1(E)-enyl)-4,6-bis(trimethylsiloxy)-5,6-dimethyl-7-ethyl-2,8-dioxabicyclo[3.3.0]octane

(1S,3R,4R,5R,6R,7R)-5,6-dimethyl-7-ethyl-3-(3-hydroxyprop-1(E)-enyl)-4-(4-methoxybenzyloxy)-2,8-dioxabicyclo[3.3.0]octan-6-ol

(1S,3R,4R,5R,6R,7R)-5,6-dimethyl-7-ethyl-3-(3-hydroxyprop-1(E)-enyl)-4-(4-methoxybenzyloxy)-2,8-dioxabicyclo[3.3.0]octan-6-ol

(1S,3R,4R,5R,6R,7R)-3-(3-acetoxyprop-1(E)-enyl)-4,6-bis(trimethylsiloxy)-5,6-dimethyl-7-ethyl-2,8-dioxabicyclo[3.3.0]octane

(1S,3R,4R,5R,6R,7R)-3-(3-acetoxyprop-1(E)-enyl)-4,6-bis(trimethylsiloxy)-5,6-dimethyl-7-ethyl-2,8-dioxabicyclo[3.3.0]octane

Acetic acid (E)-3-[(2R,3R,3aR,4R,5R,6aS)-5-ethyl-4-hydroxy-3-(4-methoxy-benzyloxy)-3a,4-dimethyl-hexahydro-furo[2,3-b]furan-2-yl]-allyl ester

Acetic acid (E)-3-[(2R,3R,3aR,4R,5R,6aS)-5-ethyl-4-hydroxy-3-(4-methoxy-benzyloxy)-3a,4-dimethyl-hexahydro-furo[2,3-b]furan-2-yl]-allyl ester

(1S,3R,4R,5R,6R,7R)-3-(3-acetoxyprop-1(E)-enyl)-4,6-bis(trimethylsiloxy)-5,6-dimethyl-7-ethyl-2,8-dioxabicyclo[3.3.0]octane

(1S,3R,4R,5R,6R,7R)-3-(3-acetoxyprop-1(E)-enyl)-4,6-bis(trimethylsiloxy)-5,6-dimethyl-7-ethyl-2,8-dioxabicyclo[3.3.0]octane

ethyl (1S,3R,4R,5R,6R,7R)-3-{5,6-dimethyl-7-ethyl-6-hydroxy-4-(4-methoxybenzyloxy)-2,8-dioxabicyclo[3.3.0]oct-3-yl}-prop-2-enoate

ethyl (1S,3R,4R,5R,6R,7R)-3-{5,6-dimethyl-7-ethyl-6-hydroxy-4-(4-methoxybenzyloxy)-2,8-dioxabicyclo[3.3.0]oct-3-yl}-prop-2-enoate

(1S,3R,4R,5R,6R,7R)-3-(3-acetoxyprop-1(E)-enyl)-4,6-bis(trimethylsiloxy)-5,6-dimethyl-7-ethyl-2,8-dioxabicyclo[3.3.0]octane

(1S,3R,4R,5R,6R,7R)-3-(3-acetoxyprop-1(E)-enyl)-4,6-bis(trimethylsiloxy)-5,6-dimethyl-7-ethyl-2,8-dioxabicyclo[3.3.0]octane

(2R,3R,4R,5R,6R)-3-(4-methoxybenzyloxy)-4-(1,3-dioxolan-2-yl)-4,5-dimethyloct-1,2,5,6-tetraol

(2R,3R,4R,5R,6R)-3-(4-methoxybenzyloxy)-4-(1,3-dioxolan-2-yl)-4,5-dimethyloct-1,2,5,6-tetraol

(1S,3R,4R,5R,6R,7R)-3-(3-acetoxyprop-1(E)-enyl)-4,6-bis(trimethylsiloxy)-5,6-dimethyl-7-ethyl-2,8-dioxabicyclo[3.3.0]octane

(1S,3R,4R,5R,6R,7R)-3-(3-acetoxyprop-1(E)-enyl)-4,6-bis(trimethylsiloxy)-5,6-dimethyl-7-ethyl-2,8-dioxabicyclo[3.3.0]octane

Triisopropyl-[(2R,3R,4S,5S)-5-methoxy-3-(4-methoxy-benzyloxy)-4-methyl-4-((E)-1-methyl-but-1-enyl)-tetrahydro-furan-2-ylmethoxy]-silane

Triisopropyl-[(2R,3R,4S,5S)-5-methoxy-3-(4-methoxy-benzyloxy)-4-methyl-4-((E)-1-methyl-but-1-enyl)-tetrahydro-furan-2-ylmethoxy]-silane

(1S,3R,4R,5R,6R,7R)-3-(3-acetoxyprop-1(E)-enyl)-4,6-bis(trimethylsiloxy)-5,6-dimethyl-7-ethyl-2,8-dioxabicyclo[3.3.0]octane

(1S,3R,4R,5R,6R,7R)-3-(3-acetoxyprop-1(E)-enyl)-4,6-bis(trimethylsiloxy)-5,6-dimethyl-7-ethyl-2,8-dioxabicyclo[3.3.0]octane

上游原料

(2S,3R,3aR,4R,5R,6aR)-5-Ethyl-4-hydroxy-3-(4-methoxy-benzyloxy)-3a,4-dimethyl-hexahydro-furo[2,3-b]furan-2-carbaldehyde (2R,3R,4R,5R,6R)-3-(4-methoxybenzyloxy)-4-(1,3-dioxolan-2-yl)-4,5-dimethyloct-1,2,5,6-tetraol (1S,3R,4R,5R,6R,7R)-5,6-dimethyl-7-ethyl-3-(3-hydroxyprop-1(E)-enyl)-4-(4-methoxybenzyloxy)-2,8-dioxabicyclo[3.3.0]octan-6-ol (2RS,3R,4R,5R)-3-[(2R,3R)-2,3-dihydroxy-2-pentyl]-5-(triisopropylsiloxymethyl)-2-methoxy-4-(4-methoxybenzyloxy)-3-methyloxolane Acetic acid (E)-3-[(2R,3R,3aR,4R,5R,6aS)-5-ethyl-4-hydroxy-3-(4-methoxy-benzyloxy)-3a,4-dimethyl-hexahydro-furo[2,3-b]furan-2-yl]-allyl ester ethyl (1S,3R,4R,5R,6R,7R)-3-{5,6-dimethyl-7-ethyl-6-hydroxy-4-(4-methoxybenzyloxy)-2,8-dioxabicyclo[3.3.0]oct-3-yl}-prop-2-enoate Triisopropyl-[(2R,3R,4S,5S)-5-methoxy-3-(4-methoxy-benzyloxy)-4-methyl-4-((E)-1-methyl-but-1-enyl)-tetrahydro-furan-2-ylmethoxy]-silane (1S,3R,4R,5R,6R,7R)-5,6-dimethyl-7-ethyl-4-(4-methoxybenzyloxy)-3-(triisopropylsiloxymethyl)-2,8-dioxabicyclo[3.3.0]octan-6-ol

下游产品

astelotoxin bis(trimethylsilyl) ether (E)-3-((2R,3R,3aR,4R,5R,6aS)-5-Ethyl-3a,4-dimethyl-3,4-bis-trimethylsilanyloxy-hexahydro-furo[2,3-b]furan-2-yl)-propenal (E)-3-((2R,3R,3aR,4R,5R,6aS)-5-Ethyl-3a,4-dimethyl-3,4-bis-trimethylsilanyloxy-hexahydro-furo[2,3-b]furan-2-yl)-prop-2-en-1-ol