百科

Acetic acid (E)-3-[(2R,3R,3aR,4R,5R,6aS)-5-ethyl-4-hydroxy-3-(4-methoxy-benzyloxy)-3a,4-dimethyl-hexahydro-furo[2,3-b]furan-2-yl]-allyl ester

Acetic acid (E)-3-[(2R,3R,3aR,4R,5R,6aS)-5-ethyl-4-hydroxy-3-(4-methoxy-benzyloxy)-3a,4-dimethyl-hexahydro-furo[2,3-b]furan-2-yl]-allyl ester

CAS号：536738-15-5

英文名：Acetic acid (E)-3-[(2R,3R,3aR,4R,5R,6aS)-5-ethyl-4-hydroxy-3-(4-methoxy-benzyloxy)-3a,4-dimethyl-hexahydro-furo[2,3-b]furan-2-yl]-allyl ester

分子式：C23H32O7

分子量：420.496

合成路线

(2RS,3R,4R,5R)-3-[(2R,3R)-2,3-dihydroxy-2-pentyl]-5-(triisopropylsiloxymethyl)-2-methoxy-4-(4-methoxybenzyloxy)-3-methyloxolane

(2RS,3R,4R,5R)-3-[(2R,3R)-2,3-dihydroxy-2-pentyl]-5-(triisopropylsiloxymethyl)-2-methoxy-4-(4-methoxybenzyloxy)-3-methyloxolane

Acetic acid (E)-3-[(2R,3R,3aR,4R,5R,6aS)-5-ethyl-4-hydroxy-3-(4-methoxy-benzyloxy)-3a,4-dimethyl-hexahydro-furo[2,3-b]furan-2-yl]-allyl ester

Acetic acid (E)-3-[(2R,3R,3aR,4R,5R,6aS)-5-ethyl-4-hydroxy-3-(4-methoxy-benzyloxy)-3a,4-dimethyl-hexahydro-furo[2,3-b]furan-2-yl]-allyl ester

(2S,3R,3aR,4R,5R,6aR)-5-Ethyl-4-hydroxy-3-(4-methoxy-benzyloxy)-3a,4-dimethyl-hexahydro-furo[2,3-b]furan-2-carbaldehyde

(2S,3R,3aR,4R,5R,6aR)-5-Ethyl-4-hydroxy-3-(4-methoxy-benzyloxy)-3a,4-dimethyl-hexahydro-furo[2,3-b]furan-2-carbaldehyde

Acetic acid (E)-3-[(2R,3R,3aR,4R,5R,6aS)-5-ethyl-4-hydroxy-3-(4-methoxy-benzyloxy)-3a,4-dimethyl-hexahydro-furo[2,3-b]furan-2-yl]-allyl ester

Acetic acid (E)-3-[(2R,3R,3aR,4R,5R,6aS)-5-ethyl-4-hydroxy-3-(4-methoxy-benzyloxy)-3a,4-dimethyl-hexahydro-furo[2,3-b]furan-2-yl]-allyl ester

上游原料

(2S,3R,3aR,4R,5R,6aR)-5-Ethyl-4-hydroxy-3-(4-methoxy-benzyloxy)-3a,4-dimethyl-hexahydro-furo[2,3-b]furan-2-carbaldehyde (2RS,3R,4R,5R)-3-[(2R,3R)-2,3-dihydroxy-2-pentyl]-5-(triisopropylsiloxymethyl)-2-methoxy-4-(4-methoxybenzyloxy)-3-methyloxolane

下游产品

(1S,3R,4R,5R,6R,7R)-3-(3-acetoxyprop-1(E)-enyl)-4,6-bis(trimethylsiloxy)-5,6-dimethyl-7-ethyl-2,8-dioxabicyclo[3.3.0]octane