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(1E,3E,5E,12E)-(8S,9R,11S)-11-Benzyloxy-14-(tert-butyl-dimethyl-silanyloxy)-2,6,8,12-tetramethyl-1-(2-methyl-oxazol-4-yl)-9-trimethylsilanyloxy-tetradeca-1,3,5,12-tetraen-7-one

CAS号：544429-38-1

英文名：(1E,3E,5E,12E)-(8S,9R,11S)-11-Benzyloxy-14-(tert-butyl-dimethyl-silanyloxy)-2,6,8,12-tetramethyl-1-(2-methyl-oxazol-4-yl)-9-trimethylsilanyloxy-tetradeca-1,3,5,12-tetraen-7-one

分子式：C38H59NO5Si2

分子量：666.05

合成路线

169898-15-1

(E)-(2S,3R,5S)-5-Benzyloxy-8-(tert-butyl-dimethyl-silanyloxy)-3-hydroxy-2,6-dimethyl-oct-6-enoic acid methoxy-methyl-amide

544429-38-1

(1E,3E,5E,12E)-(8S,9R,11S)-11-Benzyloxy-14-(tert-butyl-dimethyl-silanyloxy)-2,6,8,12-tetramethyl-1-(2-methyl-oxazol-4-yl)-9-trimethylsilanyloxy-tetradeca-1,3,5,12-tetraen-7-one

237735-58-9

methyl (4E)-6-[(t-butyldimethylsilyl)oxy]-4-methyl-3-hydroxy-4-hexenoate

544429-38-1

(1E,3E,5E,12E)-(8S,9R,11S)-11-Benzyloxy-14-(tert-butyl-dimethyl-silanyloxy)-2,6,8,12-tetramethyl-1-(2-methyl-oxazol-4-yl)-9-trimethylsilanyloxy-tetradeca-1,3,5,12-tetraen-7-one

169898-10-6

((E)-(S)-4-Benzyloxy-3-methyl-hepta-2,6-dienyloxy)-tert-butyl-dimethyl-silane

544429-38-1

(1E,3E,5E,12E)-(8S,9R,11S)-11-Benzyloxy-14-(tert-butyl-dimethyl-silanyloxy)-2,6,8,12-tetramethyl-1-(2-methyl-oxazol-4-yl)-9-trimethylsilanyloxy-tetradeca-1,3,5,12-tetraen-7-one

169898-11-7

(E)-(S)-3-Benzyloxy-6-(tert-butyl-dimethyl-silanyloxy)-4-methyl-hex-4-enal

544429-38-1

(1E,3E,5E,12E)-(8S,9R,11S)-11-Benzyloxy-14-(tert-butyl-dimethyl-silanyloxy)-2,6,8,12-tetramethyl-1-(2-methyl-oxazol-4-yl)-9-trimethylsilanyloxy-tetradeca-1,3,5,12-tetraen-7-one

169898-09-3

(E)-(S)-7-(tert-Butyl-dimethyl-silanyloxy)-5-methyl-hepta-1,5-dien-4-ol

544429-38-1

(1E,3E,5E,12E)-(8S,9R,11S)-11-Benzyloxy-14-(tert-butyl-dimethyl-silanyloxy)-2,6,8,12-tetramethyl-1-(2-methyl-oxazol-4-yl)-9-trimethylsilanyloxy-tetradeca-1,3,5,12-tetraen-7-one

237735-59-0

methyl (4E,3S)-6-[(t-butyldimethylsilyl)oxy]-4-methyl-3-hydroxy-4-hexenoate

544429-38-1

(1E,3E,5E,12E)-(8S,9R,11S)-11-Benzyloxy-14-(tert-butyl-dimethyl-silanyloxy)-2,6,8,12-tetramethyl-1-(2-methyl-oxazol-4-yl)-9-trimethylsilanyloxy-tetradeca-1,3,5,12-tetraen-7-one

544429-33-6

(E)-(S)-3-Benzyloxy-6-(tert-butyl-dimethyl-silanyloxy)-4-methyl-hex-4-enoic acid methyl ester

544429-38-1

(1E,3E,5E,12E)-(8S,9R,11S)-11-Benzyloxy-14-(tert-butyl-dimethyl-silanyloxy)-2,6,8,12-tetramethyl-1-(2-methyl-oxazol-4-yl)-9-trimethylsilanyloxy-tetradeca-1,3,5,12-tetraen-7-one

544429-37-0

(E)-(2S,3R,5S)-5-Benzyloxy-8-(tert-butyl-dimethyl-silanyloxy)-2,6-dimethyl-3-trimethylsilanyloxy-oct-6-enal

544429-38-1

(1E,3E,5E,12E)-(8S,9R,11S)-11-Benzyloxy-14-(tert-butyl-dimethyl-silanyloxy)-2,6,8,12-tetramethyl-1-(2-methyl-oxazol-4-yl)-9-trimethylsilanyloxy-tetradeca-1,3,5,12-tetraen-7-one

544429-36-9

(E)-(2S,3R,5S)-5-Benzyloxy-8-(tert-butyl-dimethyl-silanyloxy)-2,6-dimethyl-3-trimethylsilanyloxy-oct-6-enoic acid methoxy-methyl-amide

544429-38-1

(1E,3E,5E,12E)-(8S,9R,11S)-11-Benzyloxy-14-(tert-butyl-dimethyl-silanyloxy)-2,6,8,12-tetramethyl-1-(2-methyl-oxazol-4-yl)-9-trimethylsilanyloxy-tetradeca-1,3,5,12-tetraen-7-one

544429-70-1

[(E)-(3R,4R,6S)-6-Benzyloxy-9-(tert-butyl-dimethyl-silanyloxy)-2-hydroxy-1,3,7-trimethyl-4-trimethylsilanyloxy-non-7-enyl]-phosphonic acid diethyl ester

544429-38-1

(1E,3E,5E,12E)-(8S,9R,11S)-11-Benzyloxy-14-(tert-butyl-dimethyl-silanyloxy)-2,6,8,12-tetramethyl-1-(2-methyl-oxazol-4-yl)-9-trimethylsilanyloxy-tetradeca-1,3,5,12-tetraen-7-one

上游原料

(E)-(S)-3-Benzyloxy-6-(tert-butyl-dimethyl-silanyloxy)-4-methyl-hex-4-enal methyl (4E,3S)-6-[(t-butyldimethylsilyl)oxy]-4-methyl-3-hydroxy-4-hexenoate (E)-(2S,3R,5S)-5-Benzyloxy-8-(tert-butyl-dimethyl-silanyloxy)-2,6-dimethyl-3-trimethylsilanyloxy-oct-6-enoic acid methoxy-methyl-amide [(E)-(3R,4R,6S)-6-Benzyloxy-9-(tert-butyl-dimethyl-silanyloxy)-2-hydroxy-1,3,7-trimethyl-4-trimethylsilanyloxy-non-7-enyl]-phosphonic acid diethyl ester (E)-(2S,3R,5S)-5-Benzyloxy-8-(tert-butyl-dimethyl-silanyloxy)-3-hydroxy-2,6-dimethyl-oct-6-enoic acid methoxy-methyl-amide ((E)-(S)-4-Benzyloxy-3-methyl-hepta-2,6-dienyloxy)-tert-butyl-dimethyl-silane (E)-(S)-3-Benzyloxy-6-(tert-butyl-dimethyl-silanyloxy)-4-methyl-hex-4-enoic acid methyl ester methyl (4E)-6-[(t-butyldimethylsilyl)oxy]-4-methyl-3-hydroxy-4-hexenoate (E)-(2S,3R,5S)-5-Benzyloxy-8-(tert-butyl-dimethyl-silanyloxy)-2,6-dimethyl-3-trimethylsilanyloxy-oct-6-enal (E)-(S)-7-(tert-Butyl-dimethyl-silanyloxy)-5-methyl-hepta-1,5-dien-4-ol

下游产品

(1E,3E,5E,12E)-(8S,9R,11S)-11-Benzyloxy-14-(tert-butyl-dimethyl-silanyloxy)-9-hydroxy-2,6,8,12-tetramethyl-1-(2-methyl-oxazol-4-yl)-tetradeca-1,3,5,12-tetraen-7-one (2E,9E,11E,13E)-(4S,6R,7S,8R)-4-Benzyloxy-1-(tert-butyl-dimethyl-silanyloxy)-8-methoxy-3,7,9,13-tetramethyl-14-(2-methyl-oxazol-4-yl)-tetradeca-2,9,11,13-tetraen-6-ol (2E,9E,11E,18E,20E,22E)-(5S,7R,8R,13S,15R,16S,17R)-7,13-Bis-benzyloxy-5-(2-benzyloxy-ethyl)-15-hydroxy-17-methoxy-8,12,16,18,22-pentamethyl-23-(2-methyl-oxazol-4-yl)-tricosa-2,9,11,18,20,22-hexaenoic acid (2E,9E,11E,13E)-(4S,6R,7S,8R)-4-Benzyloxy-1-(tert-butyl-dimethyl-silanyloxy)-3,7,9,13-tetramethyl-14-(2-methyl-oxazol-4-yl)-tetradeca-2,9,11,13-tetraene-6,8-diol