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methyl (6R,7R,8S)-7-(tert-butyldimethylsiloxy)-2-methoxy-4,6,8-trimethyl-11-trimethylsilylundeca-2,4-dien-10-ynoate

methyl (6R,7R,8S)-7-(tert-butyldimethylsiloxy)-2-methoxy-4,6,8-trimethyl-11-trimethylsilylundeca-2,4-dien-10-ynoate

CAS号：556051-27-5

英文名：methyl (6R,7R,8S)-7-(tert-butyldimethylsiloxy)-2-methoxy-4,6,8-trimethyl-11-trimethylsilylundeca-2,4-dien-10-ynoate

分子式：C25H46O4Si2

分子量：466.801

合成路线

(2R,3S,4S)-3-(tert-butyldimethylsiloxy)-2,4-dimethyl-6-oxohexyl 2,2-dimethylpropionate

(2R,3S,4S)-3-(tert-butyldimethylsiloxy)-2,4-dimethyl-6-oxohexyl 2,2-dimethylpropionate

methyl (6R,7R,8S)-7-(tert-butyldimethylsiloxy)-2-methoxy-4,6,8-trimethyl-11-trimethylsilylundeca-2,4-dien-10-ynoate

methyl (6R,7R,8S)-7-(tert-butyldimethylsiloxy)-2-methoxy-4,6,8-trimethyl-11-trimethylsilylundeca-2,4-dien-10-ynoate

(3S,4S,5R)-4-(tert-Butyl-dimethyl-silanyloxy)-6-(2,2-dimethyl-propionyloxy)-3,5-dimethyl-hexanoic acid methyl ester

(3S,4S,5R)-4-(tert-Butyl-dimethyl-silanyloxy)-6-(2,2-dimethyl-propionyloxy)-3,5-dimethyl-hexanoic acid methyl ester

methyl (6R,7R,8S)-7-(tert-butyldimethylsiloxy)-2-methoxy-4,6,8-trimethyl-11-trimethylsilylundeca-2,4-dien-10-ynoate

methyl (6R,7R,8S)-7-(tert-butyldimethylsiloxy)-2-methoxy-4,6,8-trimethyl-11-trimethylsilylundeca-2,4-dien-10-ynoate

(7α,8α,9α)-7,9-dimethyl-1,4-dioxaspiro[4.5]decan-8-ol

(7α,8α,9α)-7,9-dimethyl-1,4-dioxaspiro[4.5]decan-8-ol

methyl (6R,7R,8S)-7-(tert-butyldimethylsiloxy)-2-methoxy-4,6,8-trimethyl-11-trimethylsilylundeca-2,4-dien-10-ynoate

methyl (6R,7R,8S)-7-(tert-butyldimethylsiloxy)-2-methoxy-4,6,8-trimethyl-11-trimethylsilylundeca-2,4-dien-10-ynoate

(1s,2R,6S)-tert-butyldimethyl<(2,6-dimethyl-4-oxo-1-cyclohexyl)oxy>silane

(1s,2R,6S)-tert-butyldimethyl<(2,6-dimethyl-4-oxo-1-cyclohexyl)oxy>silane

methyl (6R,7R,8S)-7-(tert-butyldimethylsiloxy)-2-methoxy-4,6,8-trimethyl-11-trimethylsilylundeca-2,4-dien-10-ynoate

methyl (6R,7R,8S)-7-(tert-butyldimethylsiloxy)-2-methoxy-4,6,8-trimethyl-11-trimethylsilylundeca-2,4-dien-10-ynoate

(7R,8s,9S)-tert-butyldimethyl<(7,9-dimethyl-1,4-dioxaspiro<4.5>decan-8-oyl)oxy>silane

(7R,8s,9S)-tert-butyldimethyl<(7,9-dimethyl-1,4-dioxaspiro<4.5>decan-8-oyl)oxy>silane

methyl (6R,7R,8S)-7-(tert-butyldimethylsiloxy)-2-methoxy-4,6,8-trimethyl-11-trimethylsilylundeca-2,4-dien-10-ynoate

methyl (6R,7R,8S)-7-(tert-butyldimethylsiloxy)-2-methoxy-4,6,8-trimethyl-11-trimethylsilylundeca-2,4-dien-10-ynoate

methyl (3R,4R,5S)-4-(tert-butyldimethylsiloxy)-6-hydroxy-3,5-dimethylhexanoate

methyl (3R,4R,5S)-4-(tert-butyldimethylsiloxy)-6-hydroxy-3,5-dimethylhexanoate

methyl (6R,7R,8S)-7-(tert-butyldimethylsiloxy)-2-methoxy-4,6,8-trimethyl-11-trimethylsilylundeca-2,4-dien-10-ynoate

methyl (6R,7R,8S)-7-(tert-butyldimethylsiloxy)-2-methoxy-4,6,8-trimethyl-11-trimethylsilylundeca-2,4-dien-10-ynoate

(2R,3S,4S)-3-(tert-butyldimethylsiloxy)-2,4-dimethyl-7-trimethylsilylhept-6-ynal

(2R,3S,4S)-3-(tert-butyldimethylsiloxy)-2,4-dimethyl-7-trimethylsilylhept-6-ynal

methyl (6R,7R,8S)-7-(tert-butyldimethylsiloxy)-2-methoxy-4,6,8-trimethyl-11-trimethylsilylundeca-2,4-dien-10-ynoate

methyl (6R,7R,8S)-7-(tert-butyldimethylsiloxy)-2-methoxy-4,6,8-trimethyl-11-trimethylsilylundeca-2,4-dien-10-ynoate

上游原料

(2R,3S,4S)-3-(tert-butyldimethylsiloxy)-2,4-dimethyl-7-trimethylsilylhept-6-ynal (3S,4S,5R)-4-(tert-Butyl-dimethyl-silanyloxy)-6-(2,2-dimethyl-propionyloxy)-3,5-dimethyl-hexanoic acid methyl ester (7R,8s,9S)-tert-butyldimethyl<(7,9-dimethyl-1,4-dioxaspiro<4.5>decan-8-oyl)oxy>silane (7α,8α,9α)-7,9-dimethyl-1,4-dioxaspiro[4.5]decan-8-ol (1s,2R,6S)-tert-butyldimethyl<(2,6-dimethyl-4-oxo-1-cyclohexyl)oxy>silane (2R,3S,4S)-3-(tert-butyldimethylsiloxy)-2,4-dimethyl-6-oxohexyl 2,2-dimethylpropionate methyl (3R,4R,5S)-4-(tert-butyldimethylsiloxy)-6-hydroxy-3,5-dimethylhexanoate

下游产品

(2Z,4E)-(6R,7S,8S)-7-(tert-Butyl-dimethyl-silanyloxy)-2-methoxy-4,6,8-trimethyl-undeca-2,4-dien-10-ynoic acid methyl ester