百科

1-[(2S,3R,8R,9S)-3-(tert-butyl-dimethyl-silanyloxy)-9-ethyl-8-hydroxy-2,3,4,7,8,9-hexahydro-oxonin-2-yl]-3-methyl-butane-2,3-diol

1-[(2S,3R,8R,9S)-3-(tert-butyl-dimethyl-silanyloxy)-9-ethyl-8-hydroxy-2,3,4,7,8,9-hexahydro-oxonin-2-yl]-3-methyl-butane-2,3-diol

CAS号：558459-47-5

英文名：1-[(2S,3R,8R,9S)-3-(tert-butyl-dimethyl-silanyloxy)-9-ethyl-8-hydroxy-2,3,4,7,8,9-hexahydro-oxonin-2-yl]-3-methyl-butane-2,3-diol

分子式：C21H42O5Si

分子量：402.641

合成路线

[(2S,3R,8R,9S)-8-benzyloxy-2-(3,3-dimethyl-oxiranylmethyl)-9-ethyl-2,3,4,7,8,9-hexahydro-oxonin-3-yloxy]-tert-butyl-dimethyl-silane

[(2S,3R,8R,9S)-8-benzyloxy-2-(3,3-dimethyl-oxiranylmethyl)-9-ethyl-2,3,4,7,8,9-hexahydro-oxonin-3-yloxy]-tert-butyl-dimethyl-silane

1-[(2S,3R,8R,9S)-3-(tert-butyl-dimethyl-silanyloxy)-9-ethyl-8-hydroxy-2,3,4,7,8,9-hexahydro-oxonin-2-yl]-3-methyl-butane-2,3-diol

1-[(2S,3R,8R,9S)-3-(tert-butyl-dimethyl-silanyloxy)-9-ethyl-8-hydroxy-2,3,4,7,8,9-hexahydro-oxonin-2-yl]-3-methyl-butane-2,3-diol

3-[2-((1S,2R)-2-benzyloxy-1-ethyl-pent-4-enyloxy)-(2S)-5-methyl-hex-4-enoyl]-(4R)-4-isopropyl-oxazolidin-2-one

3-[2-((1S,2R)-2-benzyloxy-1-ethyl-pent-4-enyloxy)-(2S)-5-methyl-hex-4-enoyl]-(4R)-4-isopropyl-oxazolidin-2-one

1-[(2S,3R,8R,9S)-3-(tert-butyl-dimethyl-silanyloxy)-9-ethyl-8-hydroxy-2,3,4,7,8,9-hexahydro-oxonin-2-yl]-3-methyl-butane-2,3-diol

1-[(2S,3R,8R,9S)-3-(tert-butyl-dimethyl-silanyloxy)-9-ethyl-8-hydroxy-2,3,4,7,8,9-hexahydro-oxonin-2-yl]-3-methyl-butane-2,3-diol

5-[(1S,2R)-2-benzyloxy-1-ethyl-pent-4-enyloxy]-(4R,5S)-8-methyl-nona-1,7-dien-4-ol

5-[(1S,2R)-2-benzyloxy-1-ethyl-pent-4-enyloxy]-(4R,5S)-8-methyl-nona-1,7-dien-4-ol

1-[(2S,3R,8R,9S)-3-(tert-butyl-dimethyl-silanyloxy)-9-ethyl-8-hydroxy-2,3,4,7,8,9-hexahydro-oxonin-2-yl]-3-methyl-butane-2,3-diol

1-[(2S,3R,8R,9S)-3-(tert-butyl-dimethyl-silanyloxy)-9-ethyl-8-hydroxy-2,3,4,7,8,9-hexahydro-oxonin-2-yl]-3-methyl-butane-2,3-diol

上游原料

3-[2-((1S,2R)-2-benzyloxy-1-ethyl-pent-4-enyloxy)-(2S)-5-methyl-hex-4-enoyl]-(4R)-4-isopropyl-oxazolidin-2-one 5-[(1S,2R)-2-benzyloxy-1-ethyl-pent-4-enyloxy]-(4R,5S)-8-methyl-nona-1,7-dien-4-ol [(2S,3R,8R,9S)-8-benzyloxy-2-(3,3-dimethyl-oxiranylmethyl)-9-ethyl-2,3,4,7,8,9-hexahydro-oxonin-3-yloxy]-tert-butyl-dimethyl-silane

下游产品

(2S,3S,8R,9S)-3-bromo-8-(tert-butyl-dimethyl-silanyloxy)-2-ethyl-9-(5-triethylsilanyl-pent-2-en-4-ynyl)-2,3,4,7,8,9-hexahydro-oxonine [(2R,3S,8R,9S)-8-hydroxy-3-(tert-butyl-dimethyl-silanyloxy)-9-ethyl-2,3,4,7,8,9-hexahydro-oxonin-2-yl]-acetaldehyde