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(2S,3R,8R,9S)-8-(tert-butyl-dimethyl-silanyloxy)-2-ethyl-9-(3-iodo-allyl)-2,3,4,7,8,9-hexahydro-oxonin-3-ol

(2S,3R,8R,9S)-8-(tert-butyl-dimethyl-silanyloxy)-2-ethyl-9-(3-iodo-allyl)-2,3,4,7,8,9-hexahydro-oxonin-3-ol

CAS号：558459-50-0

英文名：(2S,3R,8R,9S)-8-(tert-butyl-dimethyl-silanyloxy)-2-ethyl-9-(3-iodo-allyl)-2,3,4,7,8,9-hexahydro-oxonin-3-ol

分子式：C19H35IO3Si

分子量：466.469

合成路线

[(2S,3R,8R,9S)-8-benzyloxy-2-(3,3-dimethyl-oxiranylmethyl)-9-ethyl-2,3,4,7,8,9-hexahydro-oxonin-3-yloxy]-tert-butyl-dimethyl-silane

[(2S,3R,8R,9S)-8-benzyloxy-2-(3,3-dimethyl-oxiranylmethyl)-9-ethyl-2,3,4,7,8,9-hexahydro-oxonin-3-yloxy]-tert-butyl-dimethyl-silane

(2S,3R,8R,9S)-8-(tert-butyl-dimethyl-silanyloxy)-2-ethyl-9-(3-iodo-allyl)-2,3,4,7,8,9-hexahydro-oxonin-3-ol

(2S,3R,8R,9S)-8-(tert-butyl-dimethyl-silanyloxy)-2-ethyl-9-(3-iodo-allyl)-2,3,4,7,8,9-hexahydro-oxonin-3-ol

3-[2-((1S,2R)-2-benzyloxy-1-ethyl-pent-4-enyloxy)-(2S)-5-methyl-hex-4-enoyl]-(4R)-4-isopropyl-oxazolidin-2-one

3-[2-((1S,2R)-2-benzyloxy-1-ethyl-pent-4-enyloxy)-(2S)-5-methyl-hex-4-enoyl]-(4R)-4-isopropyl-oxazolidin-2-one

(2S,3R,8R,9S)-8-(tert-butyl-dimethyl-silanyloxy)-2-ethyl-9-(3-iodo-allyl)-2,3,4,7,8,9-hexahydro-oxonin-3-ol

(2S,3R,8R,9S)-8-(tert-butyl-dimethyl-silanyloxy)-2-ethyl-9-(3-iodo-allyl)-2,3,4,7,8,9-hexahydro-oxonin-3-ol

5-[(1S,2R)-2-benzyloxy-1-ethyl-pent-4-enyloxy]-(4R,5S)-8-methyl-nona-1,7-dien-4-ol

5-[(1S,2R)-2-benzyloxy-1-ethyl-pent-4-enyloxy]-(4R,5S)-8-methyl-nona-1,7-dien-4-ol

(2S,3R,8R,9S)-8-(tert-butyl-dimethyl-silanyloxy)-2-ethyl-9-(3-iodo-allyl)-2,3,4,7,8,9-hexahydro-oxonin-3-ol

(2S,3R,8R,9S)-8-(tert-butyl-dimethyl-silanyloxy)-2-ethyl-9-(3-iodo-allyl)-2,3,4,7,8,9-hexahydro-oxonin-3-ol

上游原料

3-[2-((1S,2R)-2-benzyloxy-1-ethyl-pent-4-enyloxy)-(2S)-5-methyl-hex-4-enoyl]-(4R)-4-isopropyl-oxazolidin-2-one 5-[(1S,2R)-2-benzyloxy-1-ethyl-pent-4-enyloxy]-(4R,5S)-8-methyl-nona-1,7-dien-4-ol [(2S,3R,8R,9S)-8-benzyloxy-2-(3,3-dimethyl-oxiranylmethyl)-9-ethyl-2,3,4,7,8,9-hexahydro-oxonin-3-yloxy]-tert-butyl-dimethyl-silane

下游产品

(2S,3S,8R,9S)-3-bromo-8-(tert-butyl-dimethyl-silanyloxy)-2-ethyl-9-(5-triethylsilanyl-pent-2-en-4-ynyl)-2,3,4,7,8,9-hexahydro-oxonine