百科

(2S,3S,8R,9S)-3-bromo-8-(tert-butyl-dimethyl-silanyloxy)-2-ethyl-9-(5-triethylsilanyl-pent-2-en-4-ynyl)-2,3,4,7,8,9-hexahydro-oxonine

CAS号：558459-53-3

英文名：(2S,3S,8R,9S)-3-bromo-8-(tert-butyl-dimethyl-silanyloxy)-2-ethyl-9-(5-triethylsilanyl-pent-2-en-4-ynyl)-2,3,4,7,8,9-hexahydro-oxonine

分子式：C27H49BrO2Si2

分子量：541.752

合成路线

558459-40-8

[(2S,3R,8R,9S)-8-benzyloxy-2-(3,3-dimethyl-oxiranylmethyl)-9-ethyl-2,3,4,7,8,9-hexahydro-oxonin-3-yloxy]-tert-butyl-dimethyl-silane

558459-53-3

(2S,3S,8R,9S)-3-bromo-8-(tert-butyl-dimethyl-silanyloxy)-2-ethyl-9-(5-triethylsilanyl-pent-2-en-4-ynyl)-2,3,4,7,8,9-hexahydro-oxonine

558459-48-6

[(2R,3S,8R,9S)-8-hydroxy-3-(tert-butyl-dimethyl-silanyloxy)-9-ethyl-2,3,4,7,8,9-hexahydro-oxonin-2-yl]-acetaldehyde

558459-53-3

(2S,3S,8R,9S)-3-bromo-8-(tert-butyl-dimethyl-silanyloxy)-2-ethyl-9-(5-triethylsilanyl-pent-2-en-4-ynyl)-2,3,4,7,8,9-hexahydro-oxonine

558459-35-1

3-[2-((1S,2R)-2-benzyloxy-1-ethyl-pent-4-enyloxy)-(2S)-5-methyl-hex-4-enoyl]-(4R)-4-isopropyl-oxazolidin-2-one

558459-53-3

(2S,3S,8R,9S)-3-bromo-8-(tert-butyl-dimethyl-silanyloxy)-2-ethyl-9-(5-triethylsilanyl-pent-2-en-4-ynyl)-2,3,4,7,8,9-hexahydro-oxonine

558459-37-3

5-[(1S,2R)-2-benzyloxy-1-ethyl-pent-4-enyloxy]-(4R,5S)-8-methyl-nona-1,7-dien-4-ol

558459-53-3

(2S,3S,8R,9S)-3-bromo-8-(tert-butyl-dimethyl-silanyloxy)-2-ethyl-9-(5-triethylsilanyl-pent-2-en-4-ynyl)-2,3,4,7,8,9-hexahydro-oxonine

558459-29-3

[(1S,2R)-2-benzyloxy-1-ethyl-pent-4-enyloxy]-acetic acid

558459-53-3

(2S,3S,8R,9S)-3-bromo-8-(tert-butyl-dimethyl-silanyloxy)-2-ethyl-9-(5-triethylsilanyl-pent-2-en-4-ynyl)-2,3,4,7,8,9-hexahydro-oxonine

558459-50-0

(2S,3R,8R,9S)-8-(tert-butyl-dimethyl-silanyloxy)-2-ethyl-9-(3-iodo-allyl)-2,3,4,7,8,9-hexahydro-oxonin-3-ol

558459-53-3

(2S,3S,8R,9S)-3-bromo-8-(tert-butyl-dimethyl-silanyloxy)-2-ethyl-9-(5-triethylsilanyl-pent-2-en-4-ynyl)-2,3,4,7,8,9-hexahydro-oxonine

558459-47-5

1-[(2S,3R,8R,9S)-3-(tert-butyl-dimethyl-silanyloxy)-9-ethyl-8-hydroxy-2,3,4,7,8,9-hexahydro-oxonin-2-yl]-3-methyl-butane-2,3-diol

558459-53-3

(2S,3S,8R,9S)-3-bromo-8-(tert-butyl-dimethyl-silanyloxy)-2-ethyl-9-(5-triethylsilanyl-pent-2-en-4-ynyl)-2,3,4,7,8,9-hexahydro-oxonine

558459-25-9

[(1R,2S)-1-allyl-2-((1S,2R)-2-benzyloxy-1-ethyl-pent-4-enyloxy)-5-methyl-hex-4-enyloxy]-tert-butyl-dimethyl-silane

558459-53-3

(2S,3S,8R,9S)-3-bromo-8-(tert-butyl-dimethyl-silanyloxy)-2-ethyl-9-(5-triethylsilanyl-pent-2-en-4-ynyl)-2,3,4,7,8,9-hexahydro-oxonine

558459-39-5

{(1R)-1-[(1S)-1-((1S,2R)-2-benzyloxy-1-ethyl-pent-4-enyloxy)-2-(3,3-dimethyloxiranyl)-ethyl]-but-3-enyloxy}-tert-butyl-dimethyl-silane

558459-53-3

(2S,3S,8R,9S)-3-bromo-8-(tert-butyl-dimethyl-silanyloxy)-2-ethyl-9-(5-triethylsilanyl-pent-2-en-4-ynyl)-2,3,4,7,8,9-hexahydro-oxonine

558459-46-4

1-[(2S,3R,8R,9S)-3-(tert-butyldimethyl-silanyloxy)-9-ethyl-8-benzyloxy-2,3,4,7,8,9-hexahydro-oxonin-2-yl]-3-methylbutane-2,3-diol

558459-53-3

(2S,3S,8R,9S)-3-bromo-8-(tert-butyl-dimethyl-silanyloxy)-2-ethyl-9-(5-triethylsilanyl-pent-2-en-4-ynyl)-2,3,4,7,8,9-hexahydro-oxonine

上游原料

(2S,3R,8R,9S)-8-(tert-butyl-dimethyl-silanyloxy)-2-ethyl-9-(3-iodo-allyl)-2,3,4,7,8,9-hexahydro-oxonin-3-ol 3-[2-((1S,2R)-2-benzyloxy-1-ethyl-pent-4-enyloxy)-(2S)-5-methyl-hex-4-enoyl]-(4R)-4-isopropyl-oxazolidin-2-one 5-[(1S,2R)-2-benzyloxy-1-ethyl-pent-4-enyloxy]-(4R,5S)-8-methyl-nona-1,7-dien-4-ol 1-[(2S,3R,8R,9S)-3-(tert-butyldimethyl-silanyloxy)-9-ethyl-8-benzyloxy-2,3,4,7,8,9-hexahydro-oxonin-2-yl]-3-methylbutane-2,3-diol 2-((1S,2R)-2-benzyloxy-1-ethyl-pent-4-enyloxy)-(2S)-5-methyl-hex-4-en-1-ol 3-[2-((1S,2R)-2-benzyloxy-1-ethyl-pent-4-enyloxy)-acetyl]-4-isopropyl-oxazolidin-2-one [(2S,3R,8R,9S)-8-benzyloxy-2-(3,3-dimethyl-oxiranylmethyl)-9-ethyl-2,3,4,7,8,9-hexahydro-oxonin-3-yloxy]-tert-butyl-dimethyl-silane {(1R)-1-[(1S)-1-((1S,2R)-2-benzyloxy-1-ethyl-pent-4-enyloxy)-2-(3,3-dimethyloxiranyl)-ethyl]-but-3-enyloxy}-tert-butyl-dimethyl-silane [(2R,3S,8R,9S)-8-hydroxy-3-(tert-butyl-dimethyl-silanyloxy)-9-ethyl-2,3,4,7,8,9-hexahydro-oxonin-2-yl]-acetaldehyde [(1S,2R)-2-benzyloxy-1-ethyl-pent-4-enyloxy]-acetic acid (3S,4R)-4-benzyloxy-hept-6-en-3-ol 1-[(2S,3R,8R,9S)-3-(tert-butyl-dimethyl-silanyloxy)-9-ethyl-8-hydroxy-2,3,4,7,8,9-hexahydro-oxonin-2-yl]-3-methyl-butane-2,3-diol [(1R,2S)-1-allyl-2-((1S,2R)-2-benzyloxy-1-ethyl-pent-4-enyloxy)-5-methyl-hex-4-enyloxy]-tert-butyl-dimethyl-silane

下游产品

(Z,2S,3R,8S,9S)-8-bromo-9-ethyl-3-hydroxy-2-((Z)-pent-2-en-4-ynyl)-2,3,4,7,8,9-hexahydrooxonine