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4-{4-[7-(tert-butyl-dimethyl-silanyloxymethyl)-4-hydroxy-2-methoxy-5-methyl-non-5-enyl]-10-methoxy-5,5-dimethyl-2-naphthalen-2-yl-11-triethylsilanyloxy-1,3,7-trioxa-spiro[5.5]undec-8-yl}-3-methoxy-2-methoxymethoxy-butyric acid methyl ester

4-{4-[7-(tert-butyl-dimethyl-silanyloxymethyl)-4-hydroxy-2-methoxy-5-methyl-non-5-enyl]-10-methoxy-5,5-dimethyl-2-naphthalen-2-yl-11-triethylsilanyloxy-1,3,7-trioxa-spiro[5.5]undec-8-yl}-3-methoxy-2-methoxymethoxy-butyric acid methyl ester

CAS号：566927-85-3

英文名：4-{4-[7-(tert-butyl-dimethyl-silanyloxymethyl)-4-hydroxy-2-methoxy-5-methyl-non-5-enyl]-10-methoxy-5,5-dimethyl-2-naphthalen-2-yl-11-triethylsilanyloxy-1,3,7-trioxa-spiro[5.5]undec-8-yl}-3-methoxy-2-methoxymethoxy-butyric acid methyl ester

分子式：C53H90O13Si2

分子量：991.445

合成路线

Triethyl-{(1S,3S,4S)-3-methoxy-1-[2-(4-methoxy-benzyloxy)-ethyl]-4-methoxymethoxy-hex-5-enyloxy}-silane

Triethyl-{(1S,3S,4S)-3-methoxy-1-[2-(4-methoxy-benzyloxy)-ethyl]-4-methoxymethoxy-hex-5-enyloxy}-silane

4-{4-[7-(tert-butyl-dimethyl-silanyloxymethyl)-4-hydroxy-2-methoxy-5-methyl-non-5-enyl]-10-methoxy-5,5-dimethyl-2-naphthalen-2-yl-11-triethylsilanyloxy-1,3,7-trioxa-spiro[5.5]undec-8-yl}-3-methoxy-2-methoxymethoxy-butyric acid methyl ester

4-{4-[7-(tert-butyl-dimethyl-silanyloxymethyl)-4-hydroxy-2-methoxy-5-methyl-non-5-enyl]-10-methoxy-5,5-dimethyl-2-naphthalen-2-yl-11-triethylsilanyloxy-1,3,7-trioxa-spiro[5.5]undec-8-yl}-3-methoxy-2-methoxymethoxy-butyric acid methyl ester

(2S,3S,4S,6S)-2-(2-Benzyloxy-1,1-dimethyl-ethyl)-2-methoxy-6-((2S,3S)-2-methoxy-3-methoxymethoxy-pent-4-enyl)-tetrahydro-pyran-3,4-diol

(2S,3S,4S,6S)-2-(2-Benzyloxy-1,1-dimethyl-ethyl)-2-methoxy-6-((2S,3S)-2-methoxy-3-methoxymethoxy-pent-4-enyl)-tetrahydro-pyran-3,4-diol

4-{4-[7-(tert-butyl-dimethyl-silanyloxymethyl)-4-hydroxy-2-methoxy-5-methyl-non-5-enyl]-10-methoxy-5,5-dimethyl-2-naphthalen-2-yl-11-triethylsilanyloxy-1,3,7-trioxa-spiro[5.5]undec-8-yl}-3-methoxy-2-methoxymethoxy-butyric acid methyl ester

4-{4-[7-(tert-butyl-dimethyl-silanyloxymethyl)-4-hydroxy-2-methoxy-5-methyl-non-5-enyl]-10-methoxy-5,5-dimethyl-2-naphthalen-2-yl-11-triethylsilanyloxy-1,3,7-trioxa-spiro[5.5]undec-8-yl}-3-methoxy-2-methoxymethoxy-butyric acid methyl ester

(3R)-1-[(4-methoxybenzyl)oxy]hex-5-en-3-ol

(3R)-1-[(4-methoxybenzyl)oxy]hex-5-en-3-ol

4-{4-[7-(tert-butyl-dimethyl-silanyloxymethyl)-4-hydroxy-2-methoxy-5-methyl-non-5-enyl]-10-methoxy-5,5-dimethyl-2-naphthalen-2-yl-11-triethylsilanyloxy-1,3,7-trioxa-spiro[5.5]undec-8-yl}-3-methoxy-2-methoxymethoxy-butyric acid methyl ester

4-{4-[7-(tert-butyl-dimethyl-silanyloxymethyl)-4-hydroxy-2-methoxy-5-methyl-non-5-enyl]-10-methoxy-5,5-dimethyl-2-naphthalen-2-yl-11-triethylsilanyloxy-1,3,7-trioxa-spiro[5.5]undec-8-yl}-3-methoxy-2-methoxymethoxy-butyric acid methyl ester

(3S,4S,6S)-8-(4-Methoxy-benzyloxy)-3-methoxymethoxy-6-triethylsilanyloxy-oct-1-en-4-ol

(3S,4S,6S)-8-(4-Methoxy-benzyloxy)-3-methoxymethoxy-6-triethylsilanyloxy-oct-1-en-4-ol

4-{4-[7-(tert-butyl-dimethyl-silanyloxymethyl)-4-hydroxy-2-methoxy-5-methyl-non-5-enyl]-10-methoxy-5,5-dimethyl-2-naphthalen-2-yl-11-triethylsilanyloxy-1,3,7-trioxa-spiro[5.5]undec-8-yl}-3-methoxy-2-methoxymethoxy-butyric acid methyl ester

4-{4-[7-(tert-butyl-dimethyl-silanyloxymethyl)-4-hydroxy-2-methoxy-5-methyl-non-5-enyl]-10-methoxy-5,5-dimethyl-2-naphthalen-2-yl-11-triethylsilanyloxy-1,3,7-trioxa-spiro[5.5]undec-8-yl}-3-methoxy-2-methoxymethoxy-butyric acid methyl ester

(2S,3S,4S,6S)-2-(2-Benzyloxy-1,1-dimethyl-ethyl)-2,4-dimethoxy-6-((2S,3S)-2-methoxy-3-methoxymethoxy-pent-4-enyl)-tetrahydro-pyran-3-ol

(2S,3S,4S,6S)-2-(2-Benzyloxy-1,1-dimethyl-ethyl)-2,4-dimethoxy-6-((2S,3S)-2-methoxy-3-methoxymethoxy-pent-4-enyl)-tetrahydro-pyran-3-ol

4-{4-[7-(tert-butyl-dimethyl-silanyloxymethyl)-4-hydroxy-2-methoxy-5-methyl-non-5-enyl]-10-methoxy-5,5-dimethyl-2-naphthalen-2-yl-11-triethylsilanyloxy-1,3,7-trioxa-spiro[5.5]undec-8-yl}-3-methoxy-2-methoxymethoxy-butyric acid methyl ester

4-{4-[7-(tert-butyl-dimethyl-silanyloxymethyl)-4-hydroxy-2-methoxy-5-methyl-non-5-enyl]-10-methoxy-5,5-dimethyl-2-naphthalen-2-yl-11-triethylsilanyloxy-1,3,7-trioxa-spiro[5.5]undec-8-yl}-3-methoxy-2-methoxymethoxy-butyric acid methyl ester

(7S,9S,10S)-1-Benzyloxy-5-hydroxy-9-methoxy-10-methoxymethoxy-2,2-dimethyl-7-triethylsilanyloxy-dodec-11-en-3-one

(7S,9S,10S)-1-Benzyloxy-5-hydroxy-9-methoxy-10-methoxymethoxy-2,2-dimethyl-7-triethylsilanyloxy-dodec-11-en-3-one

4-{4-[7-(tert-butyl-dimethyl-silanyloxymethyl)-4-hydroxy-2-methoxy-5-methyl-non-5-enyl]-10-methoxy-5,5-dimethyl-2-naphthalen-2-yl-11-triethylsilanyloxy-1,3,7-trioxa-spiro[5.5]undec-8-yl}-3-methoxy-2-methoxymethoxy-butyric acid methyl ester

4-{4-[7-(tert-butyl-dimethyl-silanyloxymethyl)-4-hydroxy-2-methoxy-5-methyl-non-5-enyl]-10-methoxy-5,5-dimethyl-2-naphthalen-2-yl-11-triethylsilanyloxy-1,3,7-trioxa-spiro[5.5]undec-8-yl}-3-methoxy-2-methoxymethoxy-butyric acid methyl ester

[(2S,3S,4S,6R)-2-(2-Benzyloxy-1,1-dimethyl-ethyl)-2,4-dimethoxy-6-((2S,3S)-2-methoxy-3-methoxymethoxy-pent-4-enyl)-tetrahydro-pyran-3-yloxy]-triethyl-silane

[(2S,3S,4S,6R)-2-(2-Benzyloxy-1,1-dimethyl-ethyl)-2,4-dimethoxy-6-((2S,3S)-2-methoxy-3-methoxymethoxy-pent-4-enyl)-tetrahydro-pyran-3-yloxy]-triethyl-silane

4-{4-[7-(tert-butyl-dimethyl-silanyloxymethyl)-4-hydroxy-2-methoxy-5-methyl-non-5-enyl]-10-methoxy-5,5-dimethyl-2-naphthalen-2-yl-11-triethylsilanyloxy-1,3,7-trioxa-spiro[5.5]undec-8-yl}-3-methoxy-2-methoxymethoxy-butyric acid methyl ester

4-{4-[7-(tert-butyl-dimethyl-silanyloxymethyl)-4-hydroxy-2-methoxy-5-methyl-non-5-enyl]-10-methoxy-5,5-dimethyl-2-naphthalen-2-yl-11-triethylsilanyloxy-1,3,7-trioxa-spiro[5.5]undec-8-yl}-3-methoxy-2-methoxymethoxy-butyric acid methyl ester

(2R,3S)-4-[(2R,4S,5S,6S)-6-(1,1-Dimethyl-2-oxo-ethyl)-4,6-dimethoxy-5-triethylsilanyloxy-tetrahydro-pyran-2-yl]-3-methoxy-2-methoxymethoxy-butyric acid methyl ester

(2R,3S)-4-[(2R,4S,5S,6S)-6-(1,1-Dimethyl-2-oxo-ethyl)-4,6-dimethoxy-5-triethylsilanyloxy-tetrahydro-pyran-2-yl]-3-methoxy-2-methoxymethoxy-butyric acid methyl ester

4-{4-[7-(tert-butyl-dimethyl-silanyloxymethyl)-4-hydroxy-2-methoxy-5-methyl-non-5-enyl]-10-methoxy-5,5-dimethyl-2-naphthalen-2-yl-11-triethylsilanyloxy-1,3,7-trioxa-spiro[5.5]undec-8-yl}-3-methoxy-2-methoxymethoxy-butyric acid methyl ester

4-{4-[7-(tert-butyl-dimethyl-silanyloxymethyl)-4-hydroxy-2-methoxy-5-methyl-non-5-enyl]-10-methoxy-5,5-dimethyl-2-naphthalen-2-yl-11-triethylsilanyloxy-1,3,7-trioxa-spiro[5.5]undec-8-yl}-3-methoxy-2-methoxymethoxy-butyric acid methyl ester

(2R,3S)-4-[(2R,4S,5S,6S)-6-(2-Hydroxy-1,1-dimethyl-ethyl)-4,6-dimethoxy-5-triethylsilanyloxy-tetrahydro-pyran-2-yl]-3-methoxy-2-methoxymethoxy-butyric acid methyl ester

(2R,3S)-4-[(2R,4S,5S,6S)-6-(2-Hydroxy-1,1-dimethyl-ethyl)-4,6-dimethoxy-5-triethylsilanyloxy-tetrahydro-pyran-2-yl]-3-methoxy-2-methoxymethoxy-butyric acid methyl ester

4-{4-[7-(tert-butyl-dimethyl-silanyloxymethyl)-4-hydroxy-2-methoxy-5-methyl-non-5-enyl]-10-methoxy-5,5-dimethyl-2-naphthalen-2-yl-11-triethylsilanyloxy-1,3,7-trioxa-spiro[5.5]undec-8-yl}-3-methoxy-2-methoxymethoxy-butyric acid methyl ester

4-{4-[7-(tert-butyl-dimethyl-silanyloxymethyl)-4-hydroxy-2-methoxy-5-methyl-non-5-enyl]-10-methoxy-5,5-dimethyl-2-naphthalen-2-yl-11-triethylsilanyloxy-1,3,7-trioxa-spiro[5.5]undec-8-yl}-3-methoxy-2-methoxymethoxy-butyric acid methyl ester

(2R,3S)-3-Methoxy-4-[(2R,4R,6R,8R,10S,11S)-10-methoxy-5,5-dimethyl-2-naphthalen-2-yl-4-(2-oxo-ethyl)-11-triethylsilanyloxy-1,3,7-trioxa-spiro[5.5]undec-8-yl]-2-methoxymethoxy-butyric acid methyl ester

(2R,3S)-3-Methoxy-4-[(2R,4R,6R,8R,10S,11S)-10-methoxy-5,5-dimethyl-2-naphthalen-2-yl-4-(2-oxo-ethyl)-11-triethylsilanyloxy-1,3,7-trioxa-spiro[5.5]undec-8-yl]-2-methoxymethoxy-butyric acid methyl ester

4-{4-[7-(tert-butyl-dimethyl-silanyloxymethyl)-4-hydroxy-2-methoxy-5-methyl-non-5-enyl]-10-methoxy-5,5-dimethyl-2-naphthalen-2-yl-11-triethylsilanyloxy-1,3,7-trioxa-spiro[5.5]undec-8-yl}-3-methoxy-2-methoxymethoxy-butyric acid methyl ester

4-{4-[7-(tert-butyl-dimethyl-silanyloxymethyl)-4-hydroxy-2-methoxy-5-methyl-non-5-enyl]-10-methoxy-5,5-dimethyl-2-naphthalen-2-yl-11-triethylsilanyloxy-1,3,7-trioxa-spiro[5.5]undec-8-yl}-3-methoxy-2-methoxymethoxy-butyric acid methyl ester

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上游原料

[(2S,3S,4S,6R)-2-(2-Benzyloxy-1,1-dimethyl-ethyl)-2,4-dimethoxy-6-((2S,3S)-2-methoxy-3-methoxymethoxy-pent-4-enyl)-tetrahydro-pyran-3-yloxy]-triethyl-silane (S,Z)-5-(((tert-butyldimethylsilyl)oxy)methyl)-3-methylhept-3-en-2-one (2S,3S,4S,6S)-2-(2-Benzyloxy-1,1-dimethyl-ethyl)-2-methoxy-6-((2S,3S)-2-methoxy-3-methoxymethoxy-pent-4-enyl)-tetrahydro-pyran-3,4-diol Triethyl-{(1S,3S,4S)-3-methoxy-1-[2-(4-methoxy-benzyloxy)-ethyl]-4-methoxymethoxy-hex-5-enyloxy}-silane (S)-5-Ethyl-3-methyl-5,6-dihydro-pyran-2-one (2S,4S)-6-(2-Benzyloxy-1,1-dimethyl-ethyl)-2-((2S,3S)-2-methoxy-3-methoxymethoxy-pent-4-enyl)-3,4-dihydro-2H-pyran-4-ol (3R)-1-[(4-methoxybenzyl)oxy]hex-5-en-3-ol (R)-6-(2-Benzyloxy-1,1-dimethyl-ethyl)-2-((2S,3S)-2-methoxy-3-methoxymethoxy-pent-4-enyl)-2,3-dihydro-pyran-4-one (2R,3S)-4-[(2R,4S,5S,6S)-6-(1,1-Dimethyl-2-oxo-ethyl)-4,6-dimethoxy-5-triethylsilanyloxy-tetrahydro-pyran-2-yl]-3-methoxy-2-methoxymethoxy-butyric acid methyl ester (2R,3S)-4-[(2R,4S,5S,6S)-6-(2-Benzyloxy-1,1-dimethyl-ethyl)-4,6-dimethoxy-5-triethylsilanyloxy-tetrahydro-pyran-2-yl]-3-methoxy-2-methoxymethoxy-butyric acid methyl ester (2R,3S)-3-Methoxy-4-[(2R,4R,6R,8R,10S,11S)-10-methoxy-5,5-dimethyl-2-naphthalen-2-yl-4-(2-oxo-ethyl)-11-triethylsilanyloxy-1,3,7-trioxa-spiro[5.5]undec-8-yl]-2-methoxymethoxy-butyric acid methyl ester (2R,3S)-4-[(2R,4S,5S,6S)-6-(2-Hydroxy-1,1-dimethyl-ethyl)-4,6-dimethoxy-5-triethylsilanyloxy-tetrahydro-pyran-2-yl]-3-methoxy-2-methoxymethoxy-butyric acid methyl ester (3R,5S,6S)-5-Methoxy-6-methoxymethoxy-3-triethylsilanyloxy-oct-7-enal (7S,9S,10S)-1-Benzyloxy-5-hydroxy-9-methoxy-10-methoxymethoxy-2,2-dimethyl-7-triethylsilanyloxy-dodec-11-en-3-one (3S,5S,6S)-5-Methoxy-6-methoxymethoxy-3-triethylsilanyloxy-oct-7-en-1-ol (2S,3S,4S,6S)-2-(2-Benzyloxy-1,1-dimethyl-ethyl)-2,4-dimethoxy-6-((2S,3S)-2-methoxy-3-methoxymethoxy-pent-4-enyl)-tetrahydro-pyran-3-ol (3S,4S,6S)-8-(4-Methoxy-benzyloxy)-3-methoxymethoxy-6-triethylsilanyloxy-oct-1-en-4-ol (S)-5-(4-Methoxy-benzyloxy)-3-triethylsilanyloxy-pentanal

下游产品

4-{4-[7-(tert-butyl-dimethyl-silanyloxymethyl)-4-hydroxy-2-methoxy-5-methyl-non-5-enyl]-10-methoxy-5,5-dimethyl-2-naphthalen-2-yl-11-triethylsilanyloxy-1,3,7-trioxa-spiro[5.5]undec-8-yl}-3-methoxy-2-methoxymethoxy-butyric acid 9-[3-(tert-butyl-dimethyl-silanyloxymethyl)-1-methyl-pent-1-enyl]-7,13,17-trimethoxy-12-methoxymethoxy-20,20-dimethyl-3-naphthalen-2-yl-18-triethylsilanyloxy-2,4,10,19-tetraoxa-tricyclo[13.3.1.11,5]eicosan-11-one