百科

(4R,8S)-4,11-bis(benzyloxy)-8-hydroxyundec-1-yn-6-one

(4R,8S)-4,11-bis(benzyloxy)-8-hydroxyundec-1-yn-6-one

CAS号：570397-49-8

英文名：(4R,8S)-4,11-bis(benzyloxy)-8-hydroxyundec-1-yn-6-one

分子式：C25H30O4

分子量：394.503

合成路线

(4R,8S)-4,11-bis(benzyloxy)-8-[(tert-butyldimethylsilyl)oxy]undec-1-yn-6-one

(4R,8S)-4,11-bis(benzyloxy)-8-[(tert-butyldimethylsilyl)oxy]undec-1-yn-6-one

(4R,8S)-4,11-bis(benzyloxy)-8-hydroxyundec-1-yn-6-one

(4R,8S)-4,11-bis(benzyloxy)-8-hydroxyundec-1-yn-6-one

{[(1S)-4-(benzyloxy)-1-({2-[(2R)-2-(benzyloxy)pent-4-ynyl]-1,3-dithian-2-yl}methyl)butyl]oxy}-tert-butyldimethylsilane

{[(1S)-4-(benzyloxy)-1-({2-[(2R)-2-(benzyloxy)pent-4-ynyl]-1,3-dithian-2-yl}methyl)butyl]oxy}-tert-butyldimethylsilane

(4R,8S)-4,11-bis(benzyloxy)-8-hydroxyundec-1-yn-6-one

(4R,8S)-4,11-bis(benzyloxy)-8-hydroxyundec-1-yn-6-one

上游原料

{[(1S)-4-(benzyloxy)-1-({2-[(2R)-2-(benzyloxy)pent-4-ynyl]-1,3-dithian-2-yl}methyl)butyl]oxy}-tert-butyldimethylsilane (4R,8S)-4,11-bis(benzyloxy)-8-[(tert-butyldimethylsilyl)oxy]undec-1-yn-6-one

下游产品

methyl 2-[(1E,4R)-4-(benzyloxy)-5-{(4R,6S)-6-[3-(benzyloxy)propyl]-2,2-dimethyl-1,3-dioxan-4-yl}pent-1-enyl]-6-methoxybenzoate (4S,6S,8R)-1,8-bis(benzyloxy)undec-10-yne-4,6-diol (3S,5R,7R)-7-(benzyloxy)-3-[3-(benzyloxy)propyl]-5-hydroxy-14-methoxy-3,4,5,6,7,8-hexahydro-1H-2-benzoxacyclododecin-1-one