百科

(E)-(9R,11R,12R)-12-Benzyloxy-9-(tert-butyl-dimethyl-silanyloxy)-1,11-bis-(4-methoxy-benzyloxy)-4,4-dimethyl-tridec-2-ene-5,7-dione

(E)-(9R,11R,12R)-12-Benzyloxy-9-(tert-butyl-dimethyl-silanyloxy)-1,11-bis-(4-methoxy-benzyloxy)-4,4-dimethyl-tridec-2-ene-5,7-dione

CAS号：588728-61-4

英文名：(E)-(9R,11R,12R)-12-Benzyloxy-9-(tert-butyl-dimethyl-silanyloxy)-1,11-bis-(4-methoxy-benzyloxy)-4,4-dimethyl-tridec-2-ene-5,7-dione

分子式：C44H62O8Si

分子量：747.044

合成路线

(3R,5R,6R)-6-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-5-(4-methoxy-benzyloxy)-heptanal

(3R,5R,6R)-6-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-5-(4-methoxy-benzyloxy)-heptanal

(E)-(9R,11R,12R)-12-Benzyloxy-9-(tert-butyl-dimethyl-silanyloxy)-1,11-bis-(4-methoxy-benzyloxy)-4,4-dimethyl-tridec-2-ene-5,7-dione

(E)-(9R,11R,12R)-12-Benzyloxy-9-(tert-butyl-dimethyl-silanyloxy)-1,11-bis-(4-methoxy-benzyloxy)-4,4-dimethyl-tridec-2-ene-5,7-dione

(4S,6R,7R)-7-Benzyloxy-6-(4-methoxy-benzyloxy)-oct-1-en-4-ol

(4S,6R,7R)-7-Benzyloxy-6-(4-methoxy-benzyloxy)-oct-1-en-4-ol

(E)-(9R,11R,12R)-12-Benzyloxy-9-(tert-butyl-dimethyl-silanyloxy)-1,11-bis-(4-methoxy-benzyloxy)-4,4-dimethyl-tridec-2-ene-5,7-dione

(E)-(9R,11R,12R)-12-Benzyloxy-9-(tert-butyl-dimethyl-silanyloxy)-1,11-bis-(4-methoxy-benzyloxy)-4,4-dimethyl-tridec-2-ene-5,7-dione

(E)-6-(4-Methoxy-benzyloxy)-3,3-dimethyl-hex-4-en-2-one

(E)-6-(4-Methoxy-benzyloxy)-3,3-dimethyl-hex-4-en-2-one

(E)-(9R,11R,12R)-12-Benzyloxy-9-(tert-butyl-dimethyl-silanyloxy)-1,11-bis-(4-methoxy-benzyloxy)-4,4-dimethyl-tridec-2-ene-5,7-dione

(E)-(9R,11R,12R)-12-Benzyloxy-9-(tert-butyl-dimethyl-silanyloxy)-1,11-bis-(4-methoxy-benzyloxy)-4,4-dimethyl-tridec-2-ene-5,7-dione

上游原料

(3R,5R,6R)-6-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-5-(4-methoxy-benzyloxy)-heptanal (4S,6R,7R)-7-Benzyloxy-6-(4-methoxy-benzyloxy)-oct-1-en-4-ol (E)-6-(4-Methoxy-benzyloxy)-3,3-dimethyl-hex-4-en-2-one

下游产品

(E)-4-[(3aS,4S,6R,7aS)-6-((2R,3R)-3-Benzyloxy-2-hydroxy-butyl)-4-hydroxy-2-oxo-tetrahydro-[1,3]dioxolo[4,5-c]pyran-4-yl]-4-methyl-pent-2-enal