百科

(2R,4S)-4-((2Z,7E)-(4S,9S)-9-Acetoxy-4,8-dimethyl-6-methylene-2-methylsulfanyl-undeca-2,7-dienyl)-2-(2,4,6-trimethyl-phenyl)-[1,3]dioxolane-4-carboxylic acid methyl ester

(2R,4S)-4-((2Z,7E)-(4S,9S)-9-Acetoxy-4,8-dimethyl-6-methylene-2-methylsulfanyl-undeca-2,7-dienyl)-2-(2,4,6-trimethyl-phenyl)-[1,3]dioxolane-4-carboxylic acid methyl ester

CAS号：594855-35-3

英文名：(2R,4S)-4-((2Z,7E)-(4S,9S)-9-Acetoxy-4,8-dimethyl-6-methylene-2-methylsulfanyl-undeca-2,7-dienyl)-2-(2,4,6-trimethyl-phenyl)-[1,3]dioxolane-4-carboxylic acid methyl ester

分子式：C31H44O6S

分子量：544.742

合成路线

(E)-(2S,7S)-2,6-Dimethyl-4-methylene-7-(2-trimethylsilanyl-ethoxymethoxy)-non-5-enal

(E)-(2S,7S)-2,6-Dimethyl-4-methylene-7-(2-trimethylsilanyl-ethoxymethoxy)-non-5-enal

(2R,4S)-4-((2Z,7E)-(4S,9S)-9-Acetoxy-4,8-dimethyl-6-methylene-2-methylsulfanyl-undeca-2,7-dienyl)-2-(2,4,6-trimethyl-phenyl)-[1,3]dioxolane-4-carboxylic acid methyl ester

(2R,4S)-4-((2Z,7E)-(4S,9S)-9-Acetoxy-4,8-dimethyl-6-methylene-2-methylsulfanyl-undeca-2,7-dienyl)-2-(2,4,6-trimethyl-phenyl)-[1,3]dioxolane-4-carboxylic acid methyl ester

(2Z,7E)-(4S,9S)-4,8-Dimethyl-6-methylene-2-methylsulfanyl-9-(2-trimethylsilanyl-ethoxymethoxy)-undeca-2,7-dien-1-ol

(2Z,7E)-(4S,9S)-4,8-Dimethyl-6-methylene-2-methylsulfanyl-9-(2-trimethylsilanyl-ethoxymethoxy)-undeca-2,7-dien-1-ol

(2R,4S)-4-((2Z,7E)-(4S,9S)-9-Acetoxy-4,8-dimethyl-6-methylene-2-methylsulfanyl-undeca-2,7-dienyl)-2-(2,4,6-trimethyl-phenyl)-[1,3]dioxolane-4-carboxylic acid methyl ester

(2R,4S)-4-((2Z,7E)-(4S,9S)-9-Acetoxy-4,8-dimethyl-6-methylene-2-methylsulfanyl-undeca-2,7-dienyl)-2-(2,4,6-trimethyl-phenyl)-[1,3]dioxolane-4-carboxylic acid methyl ester

(2Z,7E)-(4S,9S)-4,8-Dimethyl-6-methylene-2-methylsulfanyl-9-(2-trimethylsilanyl-ethoxymethoxy)-undeca-2,7-dienoic acid ethyl ester

(2Z,7E)-(4S,9S)-4,8-Dimethyl-6-methylene-2-methylsulfanyl-9-(2-trimethylsilanyl-ethoxymethoxy)-undeca-2,7-dienoic acid ethyl ester

(2R,4S)-4-((2Z,7E)-(4S,9S)-9-Acetoxy-4,8-dimethyl-6-methylene-2-methylsulfanyl-undeca-2,7-dienyl)-2-(2,4,6-trimethyl-phenyl)-[1,3]dioxolane-4-carboxylic acid methyl ester

(2R,4S)-4-((2Z,7E)-(4S,9S)-9-Acetoxy-4,8-dimethyl-6-methylene-2-methylsulfanyl-undeca-2,7-dienyl)-2-(2,4,6-trimethyl-phenyl)-[1,3]dioxolane-4-carboxylic acid methyl ester

上游原料

(2Z,7E)-(4S,9S)-4,8-Dimethyl-6-methylene-2-methylsulfanyl-9-(2-trimethylsilanyl-ethoxymethoxy)-undeca-2,7-dienoic acid ethyl ester (2Z,7E)-(4S,9S)-4,8-Dimethyl-6-methylene-2-methylsulfanyl-9-(2-trimethylsilanyl-ethoxymethoxy)-undeca-2,7-dien-1-ol (E)-(2S,7S)-2,6-Dimethyl-4-methylene-7-(2-trimethylsilanyl-ethoxymethoxy)-non-5-enal

下游产品

(11E,16Z)-(2R,5S,7R,10S,15S)-10-Ethyl-7,11,15-trimethyl-13-methylene-17-methylsulfanyl-2-(2,4,6-trimethyl-phenyl)-1,3,9-trioxa-spiro[4.13]octadeca-11,16-diene-6,8-dione