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(5S)-7-(tert-butyldimethylsiloxymethyl)-1,3-dioxa-2-oxo-9-hydroxy-6,6,8-trimethyl-spiro[4,5]dec-7-ene

(5S)-7-(tert-butyldimethylsiloxymethyl)-1,3-dioxa-2-oxo-9-hydroxy-6,6,8-trimethyl-spiro[4,5]dec-7-ene

CAS号：595568-58-4

英文名：(5S)-7-(tert-butyldimethylsiloxymethyl)-1,3-dioxa-2-oxo-9-hydroxy-6,6,8-trimethyl-spiro[4,5]dec-7-ene

分子式：C18H32O5Si

分子量：356.529

合成路线

(4S)-2-(tert-butyldimethylsiloxymethyl)-4-hydroxy-4-(hydroxymethyl)-1,3,3-trimethyl-cyclohex-1-ene

(4S)-2-(tert-butyldimethylsiloxymethyl)-4-hydroxy-4-(hydroxymethyl)-1,3,3-trimethyl-cyclohex-1-ene

(5S)-7-(tert-butyldimethylsiloxymethyl)-1,3-dioxa-2-oxo-9-hydroxy-6,6,8-trimethyl-spiro[4,5]dec-7-ene

(5S)-7-(tert-butyldimethylsiloxymethyl)-1,3-dioxa-2-oxo-9-hydroxy-6,6,8-trimethyl-spiro[4,5]dec-7-ene

(5S)-7-(tert-butyldimethylsiloxymethyl)-1,3-dioxa-2-oxo-6,6,8-trimethyl-spiro[4,5]dec-7-ene

(5S)-7-(tert-butyldimethylsiloxymethyl)-1,3-dioxa-2-oxo-6,6,8-trimethyl-spiro[4,5]dec-7-ene

(5S)-7-(tert-butyldimethylsiloxymethyl)-1,3-dioxa-2-oxo-9-hydroxy-6,6,8-trimethyl-spiro[4,5]dec-7-ene

(5S)-7-(tert-butyldimethylsiloxymethyl)-1,3-dioxa-2-oxo-9-hydroxy-6,6,8-trimethyl-spiro[4,5]dec-7-ene

3-Hydroxymethyl-2,2,4-trimethyl-cyclohex-3-enone

3-Hydroxymethyl-2,2,4-trimethyl-cyclohex-3-enone

(5S)-7-(tert-butyldimethylsiloxymethyl)-1,3-dioxa-2-oxo-9-hydroxy-6,6,8-trimethyl-spiro[4,5]dec-7-ene

(5S)-7-(tert-butyldimethylsiloxymethyl)-1,3-dioxa-2-oxo-9-hydroxy-6,6,8-trimethyl-spiro[4,5]dec-7-ene

5,5-(ethylenedioxy)-2,,6,6-trimethyl-1-iodocyclohexene

5,5-(ethylenedioxy)-2,,6,6-trimethyl-1-iodocyclohexene

(5S)-7-(tert-butyldimethylsiloxymethyl)-1,3-dioxa-2-oxo-9-hydroxy-6,6,8-trimethyl-spiro[4,5]dec-7-ene

(5S)-7-(tert-butyldimethylsiloxymethyl)-1,3-dioxa-2-oxo-9-hydroxy-6,6,8-trimethyl-spiro[4,5]dec-7-ene

6,6,8-trimethyl-1,4-dioxaspiro[4.5]decan-7-one hydrazone

6,6,8-trimethyl-1,4-dioxaspiro[4.5]decan-7-one hydrazone

(5S)-7-(tert-butyldimethylsiloxymethyl)-1,3-dioxa-2-oxo-9-hydroxy-6,6,8-trimethyl-spiro[4,5]dec-7-ene

(5S)-7-(tert-butyldimethylsiloxymethyl)-1,3-dioxa-2-oxo-9-hydroxy-6,6,8-trimethyl-spiro[4,5]dec-7-ene

5-(tert-Butyl-dimethyl-silanyloxymethyl)-4,6,6-trimethyl-cyclohexa-1,4-dienecarbaldehyde

5-(tert-Butyl-dimethyl-silanyloxymethyl)-4,6,6-trimethyl-cyclohexa-1,4-dienecarbaldehyde

(5S)-7-(tert-butyldimethylsiloxymethyl)-1,3-dioxa-2-oxo-9-hydroxy-6,6,8-trimethyl-spiro[4,5]dec-7-ene

(5S)-7-(tert-butyldimethylsiloxymethyl)-1,3-dioxa-2-oxo-9-hydroxy-6,6,8-trimethyl-spiro[4,5]dec-7-ene

2-(tert-butyldimethylsiloxymethyl)-4-hydroxymethyl-1,3,3-trimethyl-cyclohexa-1,4-diene

2-(tert-butyldimethylsiloxymethyl)-4-hydroxymethyl-1,3,3-trimethyl-cyclohexa-1,4-diene

(5S)-7-(tert-butyldimethylsiloxymethyl)-1,3-dioxa-2-oxo-9-hydroxy-6,6,8-trimethyl-spiro[4,5]dec-7-ene

(5S)-7-(tert-butyldimethylsiloxymethyl)-1,3-dioxa-2-oxo-9-hydroxy-6,6,8-trimethyl-spiro[4,5]dec-7-ene

上游原料

(5S)-7-(tert-butyldimethylsiloxymethyl)-1,3-dioxa-2-oxo-6,6,8-trimethyl-spiro[4,5]dec-7-ene (4S)-2-(tert-butyldimethylsiloxymethyl)-4-hydroxy-4-(hydroxymethyl)-1,3,3-trimethyl-cyclohex-1-ene 5,5-(ethylenedioxy)-2,,6,6-trimethyl-1-iodocyclohexene 2-(tert-butyldimethylsiloxymethyl)-4-hydroxymethyl-1,3,3-trimethyl-cyclohexa-1,4-diene 5-(tert-Butyl-dimethyl-silanyloxymethyl)-4,6,6-trimethyl-cyclohexa-1,4-dienecarbaldehyde 3-Hydroxymethyl-2,2,4-trimethyl-cyclohex-3-enone 6,6,8-trimethyl-1,4-dioxaspiro[4.5]decan-7-one hydrazone

下游产品

(5S)-3-(tert-butyldimethylsiloxymethyl)-5-hydroxy-5-benzoyloxymethyl-2,4,4-trimethyl-cyclohex-2-en-1-one (4S,5R)-2-(tert-butyldimethylsiloxymethyl)-4,6-dihydroxy-4-benzoyloxymethyl-1,3,3-trimethyl-cyclohex-1-ene