百科

(2R,7R)-2-((S)-1-Benzyloxy-propyl)-7-[(Z)-(S)-1-(tert-butyl-dimethyl-silanyloxy)-6-trimethylsilanyl-hex-3-en-5-ynyl]-2,3,6,7-tetrahydro-oxepine

(2R,7R)-2-((S)-1-Benzyloxy-propyl)-7-[(Z)-(S)-1-(tert-butyl-dimethyl-silanyloxy)-6-trimethylsilanyl-hex-3-en-5-ynyl]-2,3,6,7-tetrahydro-oxepine

CAS号：600728-65-2

英文名：(2R,7R)-2-((S)-1-Benzyloxy-propyl)-7-[(Z)-(S)-1-(tert-butyl-dimethyl-silanyloxy)-6-trimethylsilanyl-hex-3-en-5-ynyl]-2,3,6,7-tetrahydro-oxepine

分子式：C31H50O3Si2

分子量：526.898

合成路线

(S)-3-[(2R,7R)-7-((S)-1-Benzyloxy-propyl)-2,3,6,7-tetrahydro-oxepin-2-yl]-3-(tert-butyl-dimethyl-silanyloxy)-propan-1-ol

(S)-3-[(2R,7R)-7-((S)-1-Benzyloxy-propyl)-2,3,6,7-tetrahydro-oxepin-2-yl]-3-(tert-butyl-dimethyl-silanyloxy)-propan-1-ol

(2R,7R)-2-((S)-1-Benzyloxy-propyl)-7-[(Z)-(S)-1-(tert-butyl-dimethyl-silanyloxy)-6-trimethylsilanyl-hex-3-en-5-ynyl]-2,3,6,7-tetrahydro-oxepine

(2R,7R)-2-((S)-1-Benzyloxy-propyl)-7-[(Z)-(S)-1-(tert-butyl-dimethyl-silanyloxy)-6-trimethylsilanyl-hex-3-en-5-ynyl]-2,3,6,7-tetrahydro-oxepine

(S)-3-[(2R,7R)-7-((S)-1-Benzyloxy-propyl)-2,3,6,7-tetrahydro-oxepin-2-yl]-3-(tert-butyl-dimethyl-silanyloxy)-propionaldehyde

(S)-3-[(2R,7R)-7-((S)-1-Benzyloxy-propyl)-2,3,6,7-tetrahydro-oxepin-2-yl]-3-(tert-butyl-dimethyl-silanyloxy)-propionaldehyde

(2R,7R)-2-((S)-1-Benzyloxy-propyl)-7-[(Z)-(S)-1-(tert-butyl-dimethyl-silanyloxy)-6-trimethylsilanyl-hex-3-en-5-ynyl]-2,3,6,7-tetrahydro-oxepine

(2R,7R)-2-((S)-1-Benzyloxy-propyl)-7-[(Z)-(S)-1-(tert-butyl-dimethyl-silanyloxy)-6-trimethylsilanyl-hex-3-en-5-ynyl]-2,3,6,7-tetrahydro-oxepine

上游原料

(S)-3-[(2R,7R)-7-((S)-1-Benzyloxy-propyl)-2,3,6,7-tetrahydro-oxepin-2-yl]-3-(tert-butyl-dimethyl-silanyloxy)-propionaldehyde (S)-3-[(2R,7R)-7-((S)-1-Benzyloxy-propyl)-2,3,6,7-tetrahydro-oxepin-2-yl]-3-(tert-butyl-dimethyl-silanyloxy)-propan-1-ol

下游产品

(S)-1-[(2R,7R)-7-((Z)-(R)-1-Chloro-hex-3-en-5-ynyl)-2,3,6,7-tetrahydro-oxepin-2-yl]-propan-1-ol (Z)-(S)-1-[(2R,7R)-7-((S)-1-Benzyloxy-propyl)-2,3,6,7-tetrahydro-oxepin-2-yl]-hex-3-en-5-yn-1-ol (2R,7R)-2-((S)-1-Benzyloxy-propyl)-7-((Z)-(R)-1-chloro-hex-3-en-5-ynyl)-2,3,6,7-tetrahydro-oxepine