化合物简介
[2.2.2.2.2.2]( 1,2,3,4,5,6)Cyclophane or superphane is a 6-fold bridged cyclophane with all arene positions in the benzene dimer taken up by ethylene spacers. The compound has been of some scientific interest as a model for testing aromaticity and was first synthesised by Boekelheide in 1979. Superphane is the base compound for a large group of derivatives with structural variations. The analogs with 2 to 5 bridges are also known compounds. The benzene rings have been replaced by other aromatic units, such as those based on ferrocene or stabilized cyclobutadiene. Numerous derivatives are known with variations in the type and length of the bridging units.
基本信息
中文名称
5,12:6,11:13,16:14,15-四乙桥三环[8.2.2.24,7]十六碳-1(12),4,6,10,13,15-六烯
英文名称
<2.2.2.2.2.2>(1,2,3,4,5,6)cyclophane
中文别名
英文别名
[2.2.2.2.2.2](1,2,3,4,5,6)Cyclophane、<2.2.2.2.2.2>(1,2,3,4,5,6)-Cyclophan、Superphane、heptacyclo[16.6.0.02,9.05,22.06,13.010,17.014,21]tetracosa-1,5,9,13,17,21-hexaene (non-preferred name)、[26]-(1,2,3,4,5,6)-cyclophane
CAS号
60144-50-5
分子式
C24H24
分子量
312.447
精确质量
312.188
PSA
0.0
LOGP
3.9648
物化性质
密度
1.265g/cm3
沸点
380.6ºC at 760 mmHg
闪点
200.4ºC
折射率
1.723