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(E)-(3R,4R,5R)-6-(tert-Butyl-dimethyl-silanyloxy)-5-methoxy-4-methyl-1-phenyl-hept-1-en-3-ol

(E)-(3R,4R,5R)-6-(tert-Butyl-dimethyl-silanyloxy)-5-methoxy-4-methyl-1-phenyl-hept-1-en-3-ol

CAS号：602277-07-6

英文名：(E)-(3R,4R,5R)-6-(tert-Butyl-dimethyl-silanyloxy)-5-methoxy-4-methyl-1-phenyl-hept-1-en-3-ol

分子式：C21H36O3Si

分子量：364.594

合成路线

(R)-1-((3a'R,5'S,6'R,6a'R)-6'-methyltetrahydrospiro[cyclohexane-1,2'-furo[2,3-d][1,3]dioxol]-5'-yl)ethane-1,2-diol

(R)-1-((3a'R,5'S,6'R,6a'R)-6'-methyltetrahydrospiro[cyclohexane-1,2'-furo[2,3-d][1,3]dioxol]-5'-yl)ethane-1,2-diol

(E)-(3R,4R,5R)-6-(tert-Butyl-dimethyl-silanyloxy)-5-methoxy-4-methyl-1-phenyl-hept-1-en-3-ol

(E)-(3R,4R,5R)-6-(tert-Butyl-dimethyl-silanyloxy)-5-methoxy-4-methyl-1-phenyl-hept-1-en-3-ol

(3a'R,5'S,6'R,6a'R)-6'-methyl-5'-((R)-1,4-dioxaspiro[4.5]decan-2-yl)tetrahydrospiro[cyclohexane-1,2'-furo[2,3-d][1,3]dioxole]

(3a'R,5'S,6'R,6a'R)-6'-methyl-5'-((R)-1,4-dioxaspiro[4.5]decan-2-yl)tetrahydrospiro[cyclohexane-1,2'-furo[2,3-d][1,3]dioxole]

(E)-(3R,4R,5R)-6-(tert-Butyl-dimethyl-silanyloxy)-5-methoxy-4-methyl-1-phenyl-hept-1-en-3-ol

(E)-(3R,4R,5R)-6-(tert-Butyl-dimethyl-silanyloxy)-5-methoxy-4-methyl-1-phenyl-hept-1-en-3-ol

(3a'R,5'S,6a'R)-6'-methylene-5'-((R)-1,4-dioxaspiro[4.5]decan-2-yl)tetrahydrospiro[cyclohexane-1,2'-furo[2,3-d][1,3]dioxole]

(3a'R,5'S,6a'R)-6'-methylene-5'-((R)-1,4-dioxaspiro[4.5]decan-2-yl)tetrahydrospiro[cyclohexane-1,2'-furo[2,3-d][1,3]dioxole]

(E)-(3R,4R,5R)-6-(tert-Butyl-dimethyl-silanyloxy)-5-methoxy-4-methyl-1-phenyl-hept-1-en-3-ol

(E)-(3R,4R,5R)-6-(tert-Butyl-dimethyl-silanyloxy)-5-methoxy-4-methyl-1-phenyl-hept-1-en-3-ol

(3a'R,5'R,6'R,6a'R)-6'-methyl-5'-vinyltetrahydrospiro[cyclohexane-1,2'-furo[2,3-d][1,3]dioxole]

(3a'R,5'R,6'R,6a'R)-6'-methyl-5'-vinyltetrahydrospiro[cyclohexane-1,2'-furo[2,3-d][1,3]dioxole]

(E)-(3R,4R,5R)-6-(tert-Butyl-dimethyl-silanyloxy)-5-methoxy-4-methyl-1-phenyl-hept-1-en-3-ol

(E)-(3R,4R,5R)-6-(tert-Butyl-dimethyl-silanyloxy)-5-methoxy-4-methyl-1-phenyl-hept-1-en-3-ol

(3R,4R,5R)-3-Methoxy-4-methyl-5-((E)-styryl)-tetrahydro-furan-2-ol

(3R,4R,5R)-3-Methoxy-4-methyl-5-((E)-styryl)-tetrahydro-furan-2-ol

(E)-(3R,4R,5R)-6-(tert-Butyl-dimethyl-silanyloxy)-5-methoxy-4-methyl-1-phenyl-hept-1-en-3-ol

(E)-(3R,4R,5R)-6-(tert-Butyl-dimethyl-silanyloxy)-5-methoxy-4-methyl-1-phenyl-hept-1-en-3-ol

(3R,4R,5R)-2,3-Dimethoxy-4-methyl-5-((E)-styryl)-tetrahydro-furan

(3R,4R,5R)-2,3-Dimethoxy-4-methyl-5-((E)-styryl)-tetrahydro-furan

(E)-(3R,4R,5R)-6-(tert-Butyl-dimethyl-silanyloxy)-5-methoxy-4-methyl-1-phenyl-hept-1-en-3-ol

(E)-(3R,4R,5R)-6-(tert-Butyl-dimethyl-silanyloxy)-5-methoxy-4-methyl-1-phenyl-hept-1-en-3-ol

上游原料

(3R,4R,5R)-2,3-Dimethoxy-4-methyl-5-((E)-styryl)-tetrahydro-furan (R)-1-((3a'R,5'S,6'R,6a'R)-6'-methyltetrahydrospiro[cyclohexane-1,2'-furo[2,3-d][1,3]dioxol]-5'-yl)ethane-1,2-diol (3R,4R,5R)-3-Methoxy-4-methyl-5-((E)-styryl)-tetrahydro-furan-2-ol (3a'R,5'S,6a'R)-6'-methylene-5'-((R)-1,4-dioxaspiro[4.5]decan-2-yl)tetrahydrospiro[cyclohexane-1,2'-furo[2,3-d][1,3]dioxole] (3a'R,5'S,6'R,6a'R)-6'-methyl-5'-((R)-1,4-dioxaspiro[4.5]decan-2-yl)tetrahydrospiro[cyclohexane-1,2'-furo[2,3-d][1,3]dioxole] (3a'R,5'R,6'R,6a'R)-6'-methyl-5'-vinyltetrahydrospiro[cyclohexane-1,2'-furo[2,3-d][1,3]dioxole]

下游产品

(E)-(3R,4R,5S)-3,5-Dimethoxy-4-methyl-7-phenyl-hept-6-en-2-one (2S,3S,4R,5S,6E)-3,5-dimethoxy-2,4-dimethyl-7-phenylhept-6-en-1-ol tert-Butyl-((E)-(2R,3R,4S)-2,4-dimethoxy-1,3-dimethyl-6-phenyl-hex-5-enyloxy)-dimethyl-silane (E)-(3R,4R,5S)-3,5-Dimethoxy-4-methyl-7-phenyl-hept-6-en-2-ol