百科

{(2R,3S,5R,6S)-5-Benzyloxy-6-benzyloxymethyl-3-[(2R,4aR,5aS,8R,9S,10aR,11aS)-2-(4-methoxy-phenyl)-9-vinyl-decahydro-1,3,5,10-tetraoxa-cyclohepta[b]naphthalen-8-yloxy]-tetrahydro-pyran-2-yl}-methanol

CAS号：602301-84-8

英文名：{(2R,3S,5R,6S)-5-Benzyloxy-6-benzyloxymethyl-3-[(2R,4aR,5aS,8R,9S,10aR,11aS)-2-(4-methoxy-phenyl)-9-vinyl-decahydro-1,3,5,10-tetraoxa-cyclohepta[b]naphthalen-8-yloxy]-tetrahydro-pyran-2-yl}-methanol

分子式：C41H50O10

分子量：702.83

合成路线

474248-53-8

[(2R,4aR,6S,7R,8aS)-6-{3-[(2R,3S,5R,6S)-5-Benzyloxy-6-benzyloxymethyl-2-(1-ethoxy-ethoxymethyl)-tetrahydro-pyran-3-yloxy]-3-phenylsulfanyl-propyl}-2-(4-methoxy-phenyl)-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yloxy]-tert-butyl-dimethyl-silane

602301-84-8

{(2R,3S,5R,6S)-5-Benzyloxy-6-benzyloxymethyl-3-[(2R,4aR,5aS,8R,9S,10aR,11aS)-2-(4-methoxy-phenyl)-9-vinyl-decahydro-1,3,5,10-tetraoxa-cyclohepta[b]naphthalen-8-yloxy]-tetrahydro-pyran-2-yl}-methanol

620949-24-8

(2R,4aR,6S,7R,8aS)-6-Hydroxymethyl-2-(4-methoxy-phenyl)-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ol

602301-84-8

{(2R,3S,5R,6S)-5-Benzyloxy-6-benzyloxymethyl-3-[(2R,4aR,5aS,8R,9S,10aR,11aS)-2-(4-methoxy-phenyl)-9-vinyl-decahydro-1,3,5,10-tetraoxa-cyclohepta[b]naphthalen-8-yloxy]-tetrahydro-pyran-2-yl}-methanol

602301-75-7

(2R,4aR,6S,7R,8aS)-7-Benzyloxy-6-benzyloxymethyl-2-(4-methoxy-phenyl)-hexahydro-pyrano[3,2-d][1,3]dioxine

602301-84-8

{(2R,3S,5R,6S)-5-Benzyloxy-6-benzyloxymethyl-3-[(2R,4aR,5aS,8R,9S,10aR,11aS)-2-(4-methoxy-phenyl)-9-vinyl-decahydro-1,3,5,10-tetraoxa-cyclohepta[b]naphthalen-8-yloxy]-tetrahydro-pyran-2-yl}-methanol

474248-51-6

(2R,3S,5R,6S)-5-Benzyloxy-6-benzyloxymethyl-2-(1-ethoxy-ethoxymethyl)-tetrahydro-pyran-3-ol

602301-84-8

{(2R,3S,5R,6S)-5-Benzyloxy-6-benzyloxymethyl-3-[(2R,4aR,5aS,8R,9S,10aR,11aS)-2-(4-methoxy-phenyl)-9-vinyl-decahydro-1,3,5,10-tetraoxa-cyclohepta[b]naphthalen-8-yloxy]-tetrahydro-pyran-2-yl}-methanol

474248-52-7

tert-Butyl-[(2R,4aR,6S,7R,8aS)-2-(4-methoxy-phenyl)-6-(3-phenylsulfanyl-propyl)-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yloxy]-dimethyl-silane

602301-84-8

{(2R,3S,5R,6S)-5-Benzyloxy-6-benzyloxymethyl-3-[(2R,4aR,5aS,8R,9S,10aR,11aS)-2-(4-methoxy-phenyl)-9-vinyl-decahydro-1,3,5,10-tetraoxa-cyclohepta[b]naphthalen-8-yloxy]-tetrahydro-pyran-2-yl}-methanol

918897-15-1

(2R,3S,5R,6S)-5-Benzyloxy-6-benzyloxymethyl-2-hydroxymethyl-tetrahydro-pyran-3-ol

602301-84-8

{(2R,3S,5R,6S)-5-Benzyloxy-6-benzyloxymethyl-3-[(2R,4aR,5aS,8R,9S,10aR,11aS)-2-(4-methoxy-phenyl)-9-vinyl-decahydro-1,3,5,10-tetraoxa-cyclohepta[b]naphthalen-8-yloxy]-tetrahydro-pyran-2-yl}-methanol

602301-79-1

[(2R,4aR,6S,7R,8aS)-6-Allyl-2-(4-methoxy-phenyl)-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yloxy]-tert-butyl-dimethyl-silane

602301-84-8

{(2R,3S,5R,6S)-5-Benzyloxy-6-benzyloxymethyl-3-[(2R,4aR,5aS,8R,9S,10aR,11aS)-2-(4-methoxy-phenyl)-9-vinyl-decahydro-1,3,5,10-tetraoxa-cyclohepta[b]naphthalen-8-yloxy]-tetrahydro-pyran-2-yl}-methanol

602301-78-0

2-[(2R,4aR,6S,7R,8aS)-7-(tert-Butyl-dimethyl-silanyloxy)-2-(4-methoxy-phenyl)-hexahydro-pyrano[3,2-d][1,3]dioxin-6-yl]-ethanol

602301-84-8

{(2R,3S,5R,6S)-5-Benzyloxy-6-benzyloxymethyl-3-[(2R,4aR,5aS,8R,9S,10aR,11aS)-2-(4-methoxy-phenyl)-9-vinyl-decahydro-1,3,5,10-tetraoxa-cyclohepta[b]naphthalen-8-yloxy]-tetrahydro-pyran-2-yl}-methanol

602301-80-4

3-[(2R,4aR,6S,7R,8aS)-7-(tert-Butyl-dimethyl-silanyloxy)-2-(4-methoxy-phenyl)-hexahydro-pyrano[3,2-d][1,3]dioxin-6-yl]-propan-1-ol

602301-84-8

{(2R,3S,5R,6S)-5-Benzyloxy-6-benzyloxymethyl-3-[(2R,4aR,5aS,8R,9S,10aR,11aS)-2-(4-methoxy-phenyl)-9-vinyl-decahydro-1,3,5,10-tetraoxa-cyclohepta[b]naphthalen-8-yloxy]-tetrahydro-pyran-2-yl}-methanol

602301-76-8

[(2R,3S,5R,6S)-5-Benzyloxy-6-benzyloxymethyl-3-(tert-butyl-dimethyl-silanyloxy)-tetrahydro-pyran-2-yl]-methanol

602301-84-8

{(2R,3S,5R,6S)-5-Benzyloxy-6-benzyloxymethyl-3-[(2R,4aR,5aS,8R,9S,10aR,11aS)-2-(4-methoxy-phenyl)-9-vinyl-decahydro-1,3,5,10-tetraoxa-cyclohepta[b]naphthalen-8-yloxy]-tetrahydro-pyran-2-yl}-methanol

上游原料

(2R,4aR,6S,7R,8aS)-7-Benzyloxy-6-benzyloxymethyl-2-(4-methoxy-phenyl)-hexahydro-pyrano[3,2-d][1,3]dioxine [(2R,4aR,6S,7R,8aS)-6-{3-[(2R,3S,5R,6S)-5-Benzyloxy-6-benzyloxymethyl-2-(1-ethoxy-ethoxymethyl)-tetrahydro-pyran-3-yloxy]-3-phenylsulfanyl-propyl}-2-(4-methoxy-phenyl)-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yloxy]-tert-butyl-dimethyl-silane [(2R,3S,5R,6S)-5-Benzyloxy-6-benzyloxymethyl-3-(tert-butyl-dimethyl-silanyloxy)-tetrahydro-pyran-2-yl]-methanol (2R,4aR,6S,7R,8aS)-6-Hydroxymethyl-2-(4-methoxy-phenyl)-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ol 3-[(2R,4aR,6S,7R,8aS)-7-(tert-Butyl-dimethyl-silanyloxy)-2-(4-methoxy-phenyl)-hexahydro-pyrano[3,2-d][1,3]dioxin-6-yl]-propan-1-ol tert-Butyl-[(2R,4aR,6S,7R,8aS)-2-(4-methoxy-phenyl)-6-(3-phenylsulfanyl-propyl)-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yloxy]-dimethyl-silane (2R,3S,5R,6S)-5-Benzyloxy-6-benzyloxymethyl-2-hydroxymethyl-tetrahydro-pyran-3-ol 2-[(2R,4aR,6S,7R,8aS)-7-(tert-Butyl-dimethyl-silanyloxy)-2-(4-methoxy-phenyl)-hexahydro-pyrano[3,2-d][1,3]dioxin-6-yl]-ethanol (2R,3S,5R,6S)-5-Benzyloxy-6-benzyloxymethyl-2-(1-ethoxy-ethoxymethyl)-tetrahydro-pyran-3-ol [(2R,4aR,6S,7R,8aS)-6-Allyl-2-(4-methoxy-phenyl)-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yloxy]-tert-butyl-dimethyl-silane

下游产品

(2R,4aR,5aS,8R,9S,10aR,11aS)-8-((2R,3S,5R,6S)-5-Benzyloxy-6-benzyloxymethyl-2-vinyl-tetrahydro-pyran-3-yloxy)-2-(4-methoxy-phenyl)-9-vinyl-decahydro-1,3,5,10-tetraoxa-cyclohepta[b]naphthalene {(2R,3S,5R,6S)-5-Benzyloxy-6-benzyloxymethyl-3-[(2R,4aR,5aS,8R,9S,10aR,11aS)-2-(4-methoxy-phenyl)-9-vinyl-decahydro-1,3,5,10-tetraoxa-cyclohepta[b]naphthalen-8-yloxy]-tetrahydro-pyran-2-yl}-acetonitrile (2R,4aR,5aS,8R,9S,10aR,11aS)-8-((2R,3S,5R,6S)-2-Allyl-5-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-3-yloxy)-2-(4-methoxy-phenyl)-9-vinyl-decahydro-1,3,5,10-tetraoxa-cyclohepta[b]naphthalene