百科

(2S,3R,4R,5S,6S)-2-(((2R,3R,4S,5S)-4,5-diacetoxy-2-bromotetrahydro-2H-pyran-3-yl)oxy)-6-methyltetrahydro-2H-pyran-3,4,5-triyl tribenzoate

(2S,3R,4R,5S,6S)-2-(((2R,3R,4S,5S)-4,5-diacetoxy-2-bromotetrahydro-2H-pyran-3-yl)oxy)-6-methyltetrahydro-2H-pyran-3,4,5-triyl tribenzoate

CAS号：616201-12-8

英文名：(2S,3R,4R,5S,6S)-2-(((2R,3R,4S,5S)-4,5-diacetoxy-2-bromotetrahydro-2H-pyran-3-yl)oxy)-6-methyltetrahydro-2H-pyran-3,4,5-triyl tribenzoate

分子式：C36H35BrO13

分子量：755.559

合成路线

allyl 3,4-di-O-isopropylidene-β-L-arabinopyranoside

allyl 3,4-di-O-isopropylidene-β-L-arabinopyranoside

(2S,3R,4R,5S,6S)-2-(((2R,3R,4S,5S)-4,5-diacetoxy-2-bromotetrahydro-2H-pyran-3-yl)oxy)-6-methyltetrahydro-2H-pyran-3,4,5-triyl tribenzoate

(2S,3R,4R,5S,6S)-2-(((2R,3R,4S,5S)-4,5-diacetoxy-2-bromotetrahydro-2H-pyran-3-yl)oxy)-6-methyltetrahydro-2H-pyran-3,4,5-triyl tribenzoate

(2S,3R,4R,5S,6S)-2-(((2S,3R,4S,5S)-2-(allyloxy)-4,5-dihydroxytetrahydro-2H-pyran-3-yl)oxy)-6-methyltetrahydro-2H-pyran-3,4,5-triyl tribenzoate

(2S,3R,4R,5S,6S)-2-(((2S,3R,4S,5S)-2-(allyloxy)-4,5-dihydroxytetrahydro-2H-pyran-3-yl)oxy)-6-methyltetrahydro-2H-pyran-3,4,5-triyl tribenzoate

(2S,3R,4R,5S,6S)-2-(((2R,3R,4S,5S)-4,5-diacetoxy-2-bromotetrahydro-2H-pyran-3-yl)oxy)-6-methyltetrahydro-2H-pyran-3,4,5-triyl tribenzoate

(2S,3R,4R,5S,6S)-2-(((2R,3R,4S,5S)-4,5-diacetoxy-2-bromotetrahydro-2H-pyran-3-yl)oxy)-6-methyltetrahydro-2H-pyran-3,4,5-triyl tribenzoate

(2S,3R,4R,5S,6S)-2-(((2S,3R,4S,5S)-4,5-diacetoxy-2-(allyloxy)tetrahydro-2H-pyran-3-yl)oxy)-6-methyltetrahydro-2H-pyran-3,4,5-triyl tribenzoate

(2S,3R,4R,5S,6S)-2-(((2S,3R,4S,5S)-4,5-diacetoxy-2-(allyloxy)tetrahydro-2H-pyran-3-yl)oxy)-6-methyltetrahydro-2H-pyran-3,4,5-triyl tribenzoate

(2S,3R,4R,5S,6S)-2-(((2R,3R,4S,5S)-4,5-diacetoxy-2-bromotetrahydro-2H-pyran-3-yl)oxy)-6-methyltetrahydro-2H-pyran-3,4,5-triyl tribenzoate

(2S,3R,4R,5S,6S)-2-(((2R,3R,4S,5S)-4,5-diacetoxy-2-bromotetrahydro-2H-pyran-3-yl)oxy)-6-methyltetrahydro-2H-pyran-3,4,5-triyl tribenzoate

4-Nitro-benzoic acid (3R,4S,5S)-4,5-diacetoxy-3-((2S,3R,4R,5S,6S)-3,4,5-tris-benzoyloxy-6-methyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-2-yl ester

4-Nitro-benzoic acid (3R,4S,5S)-4,5-diacetoxy-3-((2S,3R,4R,5S,6S)-3,4,5-tris-benzoyloxy-6-methyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-2-yl ester

(2S,3R,4R,5S,6S)-2-(((2R,3R,4S,5S)-4,5-diacetoxy-2-bromotetrahydro-2H-pyran-3-yl)oxy)-6-methyltetrahydro-2H-pyran-3,4,5-triyl tribenzoate

(2S,3R,4R,5S,6S)-2-(((2R,3R,4S,5S)-4,5-diacetoxy-2-bromotetrahydro-2H-pyran-3-yl)oxy)-6-methyltetrahydro-2H-pyran-3,4,5-triyl tribenzoate

上游原料

4-Nitro-benzoic acid (3R,4S,5S)-4,5-diacetoxy-3-((2S,3R,4R,5S,6S)-3,4,5-tris-benzoyloxy-6-methyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-2-yl ester (2S,3R,4R,5S,6S)-2-(((2S,3R,4S,5S)-2-(allyloxy)-4,5-dihydroxytetrahydro-2H-pyran-3-yl)oxy)-6-methyltetrahydro-2H-pyran-3,4,5-triyl tribenzoate allyl 3,4-di-O-isopropylidene-β-L-arabinopyranoside (2S,3R,4R,5S,6S)-2-(((2S,3R,4S,5S)-4,5-diacetoxy-2-(allyloxy)tetrahydro-2H-pyran-3-yl)oxy)-6-methyltetrahydro-2H-pyran-3,4,5-triyl tribenzoate

下游产品

(2S,3R,4R,5S,6S)-2-(((2S,3R,4S,5S)-4,5-diacetoxy-2-((5-acetoxy-2-(3-acetoxy-4-((4-methoxybenzyl)oxy)phenyl)-7-((4-methoxybenzyl)oxy)-4-oxo-4H-chromen-3-yl)oxy)tetrahydro-2H-pyran-3-yl)oxy)-6-methyltetrahydro-2H-pyran-3,4,5-triyl tribenzoate