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(3S,4S)-2-[2-(5,5-dimethyl-1-oxaspiro[2.5]oct-4-yl)ethyl]-(2S)-5-methoxy-2,7-dimethyl-2H-chroman

(3S,4S)-2-[2-(5,5-dimethyl-1-oxaspiro[2.5]oct-4-yl)ethyl]-(2S)-5-methoxy-2,7-dimethyl-2H-chroman

CAS号：618120-19-7

英文名：(3S,4S)-2-[2-(5,5-dimethyl-1-oxaspiro[2.5]oct-4-yl)ethyl]-(2S)-5-methoxy-2,7-dimethyl-2H-chroman

分子式：C23H32O3

分子量：356.498

合成路线

(S)-(+)-(2',2'-dimethyl-6'-methylene-1'-cyclohexyl)methanol

(S)-(+)-(2',2'-dimethyl-6'-methylene-1'-cyclohexyl)methanol

(3S,4S)-2-[2-(5,5-dimethyl-1-oxaspiro[2.5]oct-4-yl)ethyl]-(2S)-5-methoxy-2,7-dimethyl-2H-chroman

(3S,4S)-2-[2-(5,5-dimethyl-1-oxaspiro[2.5]oct-4-yl)ethyl]-(2S)-5-methoxy-2,7-dimethyl-2H-chroman

(S)-(-)-2,2-dimethyl-6-methylene-1-[1'-(phenylthio)methyl]cyclohexane

(S)-(-)-2,2-dimethyl-6-methylene-1-[1'-(phenylthio)methyl]cyclohexane

(3S,4S)-2-[2-(5,5-dimethyl-1-oxaspiro[2.5]oct-4-yl)ethyl]-(2S)-5-methoxy-2,7-dimethyl-2H-chroman

(3S,4S)-2-[2-(5,5-dimethyl-1-oxaspiro[2.5]oct-4-yl)ethyl]-(2S)-5-methoxy-2,7-dimethyl-2H-chroman

(S)-1-[1′-benzenesulfonyl]methyl-2,2-dimehtyl-6-methylenecyclohexane

(S)-1-[1′-benzenesulfonyl]methyl-2,2-dimehtyl-6-methylenecyclohexane

(3S,4S)-2-[2-(5,5-dimethyl-1-oxaspiro[2.5]oct-4-yl)ethyl]-(2S)-5-methoxy-2,7-dimethyl-2H-chroman

(3S,4S)-2-[2-(5,5-dimethyl-1-oxaspiro[2.5]oct-4-yl)ethyl]-(2S)-5-methoxy-2,7-dimethyl-2H-chroman

(R)-5-methoxy-2,7-dimethyl-2-vinylchroman

(R)-5-methoxy-2,7-dimethyl-2-vinylchroman

(3S,4S)-2-[2-(5,5-dimethyl-1-oxaspiro[2.5]oct-4-yl)ethyl]-(2S)-5-methoxy-2,7-dimethyl-2H-chroman

(3S,4S)-2-[2-(5,5-dimethyl-1-oxaspiro[2.5]oct-4-yl)ethyl]-(2S)-5-methoxy-2,7-dimethyl-2H-chroman

(E)-5-(2-hydroxy-6-methoxyphenyl)-3-methylpent-2-enyl methyl carbonate

(E)-5-(2-hydroxy-6-methoxyphenyl)-3-methylpent-2-enyl methyl carbonate

(3S,4S)-2-[2-(5,5-dimethyl-1-oxaspiro[2.5]oct-4-yl)ethyl]-(2S)-5-methoxy-2,7-dimethyl-2H-chroman

(3S,4S)-2-[2-(5,5-dimethyl-1-oxaspiro[2.5]oct-4-yl)ethyl]-(2S)-5-methoxy-2,7-dimethyl-2H-chroman

(1S)-2-[2-(2,2-dimethyl-6-methylenecyclohexyl)vinyl]-(2R)-5-methoxy-2,7-dimethylchroman

(1S)-2-[2-(2,2-dimethyl-6-methylenecyclohexyl)vinyl]-(2R)-5-methoxy-2,7-dimethylchroman

(3S,4S)-2-[2-(5,5-dimethyl-1-oxaspiro[2.5]oct-4-yl)ethyl]-(2S)-5-methoxy-2,7-dimethyl-2H-chroman

(3S,4S)-2-[2-(5,5-dimethyl-1-oxaspiro[2.5]oct-4-yl)ethyl]-(2S)-5-methoxy-2,7-dimethyl-2H-chroman

Toluene-4-sulfonic acid (1S,2S)-1-hydroxy-2-[2-((S)-5-methoxy-2,7-dimethyl-2H-chromen-2-yl)-ethyl]-3,3-dimethyl-cyclohexylmethyl ester

Toluene-4-sulfonic acid (1S,2S)-1-hydroxy-2-[2-((S)-5-methoxy-2,7-dimethyl-2H-chromen-2-yl)-ethyl]-3,3-dimethyl-cyclohexylmethyl ester

(3S,4S)-2-[2-(5,5-dimethyl-1-oxaspiro[2.5]oct-4-yl)ethyl]-(2S)-5-methoxy-2,7-dimethyl-2H-chroman

(3S,4S)-2-[2-(5,5-dimethyl-1-oxaspiro[2.5]oct-4-yl)ethyl]-(2S)-5-methoxy-2,7-dimethyl-2H-chroman

(1S,2S)-1-hydroxymethyl-2-[(2S)-2-(5-methoxy-2,7-dimethyl-2H-chromen-2-yl)ethyl]-3,3-dimethylcyclohexanol

(1S,2S)-1-hydroxymethyl-2-[(2S)-2-(5-methoxy-2,7-dimethyl-2H-chromen-2-yl)ethyl]-3,3-dimethylcyclohexanol

(3S,4S)-2-[2-(5,5-dimethyl-1-oxaspiro[2.5]oct-4-yl)ethyl]-(2S)-5-methoxy-2,7-dimethyl-2H-chroman

(3S,4S)-2-[2-(5,5-dimethyl-1-oxaspiro[2.5]oct-4-yl)ethyl]-(2S)-5-methoxy-2,7-dimethyl-2H-chroman

上游原料

(S)-1-[1′-benzenesulfonyl]methyl-2,2-dimehtyl-6-methylenecyclohexane Toluene-4-sulfonic acid (1S,2S)-1-hydroxy-2-[2-((S)-5-methoxy-2,7-dimethyl-2H-chromen-2-yl)-ethyl]-3,3-dimethyl-cyclohexylmethyl ester (1S,2S)-1-hydroxymethyl-2-[(2S)-2-(5-methoxy-2,7-dimethyl-2H-chromen-2-yl)ethyl]-3,3-dimethylcyclohexanol (R)-5-methoxy-2,7-dimethyl-2-vinylchroman (S)-(-)-2,2-dimethyl-6-methylene-1-[1'-(phenylthio)methyl]cyclohexane (1S)-2-[2-(2,2-dimethyl-6-methylenecyclohexyl)vinyl]-(2R)-5-methoxy-2,7-dimethylchroman (S)-(+)-(2',2'-dimethyl-6'-methylene-1'-cyclohexyl)methanol (E)-5-(2-hydroxy-6-methoxyphenyl)-3-methylpent-2-enyl methyl carbonate

下游产品

(-)-5-epi-siccanin methyl ether (-)-siccanochromene methyl ether