百科

tert-butyl (2-((2R,3S,6S)-6-(iodomethyl)-3-methyltetrahydro-2H-pyran-2-yl)ethoxy)diphenylsilane

tert-butyl (2-((2R,3S,6S)-6-(iodomethyl)-3-methyltetrahydro-2H-pyran-2-yl)ethoxy)diphenylsilane

CAS号：623566-49-4

英文名：tert-butyl (2-((2R,3S,6S)-6-(iodomethyl)-3-methyltetrahydro-2H-pyran-2-yl)ethoxy)diphenylsilane

分子式：C25H35IO2Si

分子量：522.534

合成路线

(6S)-[2-(dimethylphenylsilyl)-ethyl]-(5S)-methyl-tetrahydropyran-(2S)-carboxylic acid methyl ester

(6S)-[2-(dimethylphenylsilyl)-ethyl]-(5S)-methyl-tetrahydropyran-(2S)-carboxylic acid methyl ester

tert-butyl (2-((2R,3S,6S)-6-(iodomethyl)-3-methyltetrahydro-2H-pyran-2-yl)ethoxy)diphenylsilane

tert-butyl (2-((2R,3S,6S)-6-(iodomethyl)-3-methyltetrahydro-2H-pyran-2-yl)ethoxy)diphenylsilane

(2S,5S,6S)-6-[2-(dimethylphenylsilyl)vinyl]-5-methyl-5,6-dihydro-2H-pyran-2-carboxylic acid methyl ester

(2S,5S,6S)-6-[2-(dimethylphenylsilyl)vinyl]-5-methyl-5,6-dihydro-2H-pyran-2-carboxylic acid methyl ester

tert-butyl (2-((2R,3S,6S)-6-(iodomethyl)-3-methyltetrahydro-2H-pyran-2-yl)ethoxy)diphenylsilane

tert-butyl (2-((2R,3S,6S)-6-(iodomethyl)-3-methyltetrahydro-2H-pyran-2-yl)ethoxy)diphenylsilane

(6S)-(2-hydroxy-ethyl)-(5S)-methyl-tetrahydropyran-(2S)-carboxylic acid methyl ester

(6S)-(2-hydroxy-ethyl)-(5S)-methyl-tetrahydropyran-(2S)-carboxylic acid methyl ester

tert-butyl (2-((2R,3S,6S)-6-(iodomethyl)-3-methyltetrahydro-2H-pyran-2-yl)ethoxy)diphenylsilane

tert-butyl (2-((2R,3S,6S)-6-(iodomethyl)-3-methyltetrahydro-2H-pyran-2-yl)ethoxy)diphenylsilane

(6S)-[2-(tert-butyldiphenylsilyl)-ethyl]-(5S)-methyl-tetrahydropyran-(2S)-carboxylic acid methyl ester

(6S)-[2-(tert-butyldiphenylsilyl)-ethyl]-(5S)-methyl-tetrahydropyran-(2S)-carboxylic acid methyl ester

tert-butyl (2-((2R,3S,6S)-6-(iodomethyl)-3-methyltetrahydro-2H-pyran-2-yl)ethoxy)diphenylsilane

tert-butyl (2-((2R,3S,6S)-6-(iodomethyl)-3-methyltetrahydro-2H-pyran-2-yl)ethoxy)diphenylsilane

上游原料

(6S)-[2-(tert-butyldiphenylsilyl)-ethyl]-(5S)-methyl-tetrahydropyran-(2S)-carboxylic acid methyl ester (6S)-(2-hydroxy-ethyl)-(5S)-methyl-tetrahydropyran-(2S)-carboxylic acid methyl ester (2S,5S,6S)-6-[2-(dimethylphenylsilyl)vinyl]-5-methyl-5,6-dihydro-2H-pyran-2-carboxylic acid methyl ester (6S)-[2-(dimethylphenylsilyl)-ethyl]-(5S)-methyl-tetrahydropyran-(2S)-carboxylic acid methyl ester

下游产品

(6-{5-[6-(2-benzyloxy-6-methyl-hept-3-enyl)-3-methyl-tetrahydro-pyran-2-yl]-4-hydroxy-2-oxo-pentyl}-2,2-dimethyl-[1,3]-dioxan-4-yl)acetic acid tert-butyl ester [(6S)-((2R)-benzyloxy-6-methyl-hept-3-enyl)-(3S)-methyltetrahydro-pyran-(2S)-yl]-ethanol 1-{(6R)-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-(5S)-methyl-tetrahydro-pyran-(2S)-yl}-6-methyl-hept-3-en-2-one [(2R,3S,6S)-6-((2R)-2-benzyloxy-6-methylhept-3-enyl)-3-methyltetrahydropyran-2-yl]acetaldehyde