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[(6Z,11Z)-(1S,2S,3S,8S,9S,10S)-3,9-Bis-(4-methoxy-benzyloxy)-2,8,10-trimethyl-1-((Z)-(S)-1-methyl-penta-2,4-dienyl)-15-(tetrahydro-pyran-2-yloxy)-pentadeca-6,11-dienyloxy]-tert-butyl-dimethyl-silane

CAS号：623926-52-3

英文名：[(6Z,11Z)-(1S,2S,3S,8S,9S,10S)-3,9-Bis-(4-methoxy-benzyloxy)-2,8,10-trimethyl-1-((Z)-(S)-1-methyl-penta-2,4-dienyl)-15-(tetrahydro-pyran-2-yloxy)-pentadeca-6,11-dienyloxy]-tert-butyl-dimethyl-silane

分子式：C51H80O7Si

分子量：833.262

合成路线

261968-20-1

(–)-(2R,3R,4S)-5-(tert-butyldimethylsilanyloxy)-3-(4-methoxybenzyloxy)-2,4-dimethylpentanal

623926-52-3

[(6Z,11Z)-(1S,2S,3S,8S,9S,10S)-3,9-Bis-(4-methoxy-benzyloxy)-2,8,10-trimethyl-1-((Z)-(S)-1-methyl-penta-2,4-dienyl)-15-(tetrahydro-pyran-2-yloxy)-pentadeca-6,11-dienyloxy]-tert-butyl-dimethyl-silane

623926-34-1

(Z)-(2S,3S,4S)-3-(4-methoxybenzyloxy)-2,4-dimethyl-9-(tetrahydropyran-2-yloxy)non-5-en-1-ol

623926-52-3

[(6Z,11Z)-(1S,2S,3S,8S,9S,10S)-3,9-Bis-(4-methoxy-benzyloxy)-2,8,10-trimethyl-1-((Z)-(S)-1-methyl-penta-2,4-dienyl)-15-(tetrahydro-pyran-2-yloxy)-pentadeca-6,11-dienyloxy]-tert-butyl-dimethyl-silane

623926-25-0

tert-Butyl-[(2S,3R,4R)-5-iodo-3-(4-methoxy-benzyloxy)-2,4-dimethyl-pentyloxy]-dimethyl-silane

623926-52-3

[(6Z,11Z)-(1S,2S,3S,8S,9S,10S)-3,9-Bis-(4-methoxy-benzyloxy)-2,8,10-trimethyl-1-((Z)-(S)-1-methyl-penta-2,4-dienyl)-15-(tetrahydro-pyran-2-yloxy)-pentadeca-6,11-dienyloxy]-tert-butyl-dimethyl-silane

496035-39-3

(+)-(2S,3S,4S)-5-(tert-butyldimethylsilanyloxy)-3-(4-methoxybenzyloxy)-2,4-dimethylpentan-1-ol

623926-52-3

[(6Z,11Z)-(1S,2S,3S,8S,9S,10S)-3,9-Bis-(4-methoxy-benzyloxy)-2,8,10-trimethyl-1-((Z)-(S)-1-methyl-penta-2,4-dienyl)-15-(tetrahydro-pyran-2-yloxy)-pentadeca-6,11-dienyloxy]-tert-butyl-dimethyl-silane

623926-29-4

(2R,3S,4S)-3-(tert-butyldimethylsilanyloxy)-2,4-dimethylhex-5-enal

623926-52-3

[(6Z,11Z)-(1S,2S,3S,8S,9S,10S)-3,9-Bis-(4-methoxy-benzyloxy)-2,8,10-trimethyl-1-((Z)-(S)-1-methyl-penta-2,4-dienyl)-15-(tetrahydro-pyran-2-yloxy)-pentadeca-6,11-dienyloxy]-tert-butyl-dimethyl-silane

623926-28-3

(2S,3S,4S)-3-((tert-butyldimethylsilyl)oxy)-2,4-dimethylhex-5-en-1-ol

623926-52-3

[(6Z,11Z)-(1S,2S,3S,8S,9S,10S)-3,9-Bis-(4-methoxy-benzyloxy)-2,8,10-trimethyl-1-((Z)-(S)-1-methyl-penta-2,4-dienyl)-15-(tetrahydro-pyran-2-yloxy)-pentadeca-6,11-dienyloxy]-tert-butyl-dimethyl-silane

623926-27-2

(3S,4S,5S)-4,6-Bis-(tert-butyl-dimethyl-silanyloxy)-3,5-dimethyl-hex-1-ene

623926-52-3

[(6Z,11Z)-(1S,2S,3S,8S,9S,10S)-3,9-Bis-(4-methoxy-benzyloxy)-2,8,10-trimethyl-1-((Z)-(S)-1-methyl-penta-2,4-dienyl)-15-(tetrahydro-pyran-2-yloxy)-pentadeca-6,11-dienyloxy]-tert-butyl-dimethyl-silane

623926-49-8

(Z)-(4S,5S,6S,7S)-6-(tert-Butyl-dimethyl-silanyloxy)-4-(4-methoxy-benzyloxy)-5,7-dimethyl-undeca-8,10-dien-1-ol

623926-52-3

[(6Z,11Z)-(1S,2S,3S,8S,9S,10S)-3,9-Bis-(4-methoxy-benzyloxy)-2,8,10-trimethyl-1-((Z)-(S)-1-methyl-penta-2,4-dienyl)-15-(tetrahydro-pyran-2-yloxy)-pentadeca-6,11-dienyloxy]-tert-butyl-dimethyl-silane

623926-50-1

tert-Butyl-{(Z)-(1S,2S)-1-[(1S,2S)-5-iodo-2-(4-methoxy-benzyloxy)-1-methyl-pentyl]-2-methyl-hexa-3,5-dienyloxy}-dimethyl-silane

623926-52-3

[(6Z,11Z)-(1S,2S,3S,8S,9S,10S)-3,9-Bis-(4-methoxy-benzyloxy)-2,8,10-trimethyl-1-((Z)-(S)-1-methyl-penta-2,4-dienyl)-15-(tetrahydro-pyran-2-yloxy)-pentadeca-6,11-dienyloxy]-tert-butyl-dimethyl-silane

上游原料

tert-Butyl-[(2S,3R,4R)-5-iodo-3-(4-methoxy-benzyloxy)-2,4-dimethyl-pentyloxy]-dimethyl-silane (Z)-(2S,3S,4S)-3-(4-methoxybenzyloxy)-2,4-dimethyl-9-(tetrahydropyran-2-yloxy)non-5-en-1-ol (–)-(2R,3R,4S)-5-(tert-butyldimethylsilanyloxy)-3-(4-methoxybenzyloxy)-2,4-dimethylpentanal (3S,4S,5S)-4,6-Bis-(tert-butyl-dimethyl-silanyloxy)-3,5-dimethyl-hex-1-ene (2S,3S,4S)-3-((tert-butyldimethylsilyl)oxy)-2,4-dimethylhex-5-en-1-ol (2R,3S,4S)-3-(tert-butyldimethylsilanyloxy)-2,4-dimethylhex-5-enal (Z)-(4S,5S,6S,7S)-6-(tert-Butyl-dimethyl-silanyloxy)-4-(4-methoxy-benzyloxy)-5,7-dimethyl-undeca-8,10-dien-1-ol tert-Butyl-{(Z)-(1S,2S)-1-[(1S,2S)-5-iodo-2-(4-methoxy-benzyloxy)-1-methyl-pentyl]-2-methyl-hexa-3,5-dienyloxy}-dimethyl-silane (+)-(2S,3S,4S)-5-(tert-butyldimethylsilanyloxy)-3-(4-methoxybenzyloxy)-2,4-dimethylpentan-1-ol

下游产品

(Z,Z,Z)-(5S,6S,7S,8S,13S,14S,15S)-8,14-bis(4-methoxybenzyloxy)-5,7,13,15-tetramethyl-20-(tetrahydropyran-2-yloxy)eicosa-1,3,11,16-tetraen-6-ol (4-methoxybenzyloxy)acetic acid (Z,Z,Z)-(6S,7S,8S,13S,14S,15S,16S)-15-carbamoyloxy-7,13-bis(4-methoxybenzyloxy)-6,8,14,16-tetramethyleicosa-4,9,17,19-tetraenyl ester furan-2-carboxylic acid (Z,Z,Z)-(6S,7S,8S,13S,14S,15S,16S)-15-carbamoyloxy-7,13-bis(4-methoxybenzyloxy)-6,8,14,16-tetramethyleicosa-4,9,17,19-tetraenyl ester 2,2-dimethylpropionic acid (Z,Z,Z)-(6S,7S,8S,13S,14S,15S,16S)-15-carbamoyloxy-7,13-bis(4-methoxybenzyloxy)-6,8,14,16-tetramethyleicosa-4,9,17,19-tetraenyl ester benzoic acid (Z,Z,Z)-(6S,7S,8S,13S,14S,15S,16S)-15-carbamoyloxy-7,13-bis(4-methoxybenzyloxy)-6,8,14,16-tetramethyleicosa-4,9,17,19-tetraenyl ester