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(Z)-(4R,5R,6S,7S)-4-(tert-Butyl-dimethyl-silanyloxy)-6-(4-methoxy-benzyloxy)-5,7-dimethyl-undeca-8,10-dienal

(Z)-(4R,5R,6S,7S)-4-(tert-Butyl-dimethyl-silanyloxy)-6-(4-methoxy-benzyloxy)-5,7-dimethyl-undeca-8,10-dienal

CAS号：623926-62-5

英文名：(Z)-(4R,5R,6S,7S)-4-(tert-Butyl-dimethyl-silanyloxy)-6-(4-methoxy-benzyloxy)-5,7-dimethyl-undeca-8,10-dienal

分子式：C27H44O4Si

分子量：460.721

合成路线

(4R,5S,6S,7S)-1,6-bis(tert-butyldimethylsilanyloxy)-5,7-dimethylnon-8-en-4-ol

(4R,5S,6S,7S)-1,6-bis(tert-butyldimethylsilanyloxy)-5,7-dimethylnon-8-en-4-ol

(Z)-(4R,5R,6S,7S)-4-(tert-Butyl-dimethyl-silanyloxy)-6-(4-methoxy-benzyloxy)-5,7-dimethyl-undeca-8,10-dienal

(Z)-(4R,5R,6S,7S)-4-(tert-Butyl-dimethyl-silanyloxy)-6-(4-methoxy-benzyloxy)-5,7-dimethyl-undeca-8,10-dienal

1-[(1S,2R,3R)-3,6-Bis-(tert-butyl-dimethyl-silanyloxy)-2-methyl-1-((S)-1-methyl-allyl)-hexyloxymethyl]-4-methoxy-benzene

1-[(1S,2R,3R)-3,6-Bis-(tert-butyl-dimethyl-silanyloxy)-2-methyl-1-((S)-1-methyl-allyl)-hexyloxymethyl]-4-methoxy-benzene

(Z)-(4R,5R,6S,7S)-4-(tert-Butyl-dimethyl-silanyloxy)-6-(4-methoxy-benzyloxy)-5,7-dimethyl-undeca-8,10-dienal

(Z)-(4R,5R,6S,7S)-4-(tert-Butyl-dimethyl-silanyloxy)-6-(4-methoxy-benzyloxy)-5,7-dimethyl-undeca-8,10-dienal

(2S,3S,4S)-3-((tert-butyldimethylsilyl)oxy)-2,4-dimethylhex-5-en-1-ol

(2S,3S,4S)-3-((tert-butyldimethylsilyl)oxy)-2,4-dimethylhex-5-en-1-ol

(Z)-(4R,5R,6S,7S)-4-(tert-Butyl-dimethyl-silanyloxy)-6-(4-methoxy-benzyloxy)-5,7-dimethyl-undeca-8,10-dienal

(Z)-(4R,5R,6S,7S)-4-(tert-Butyl-dimethyl-silanyloxy)-6-(4-methoxy-benzyloxy)-5,7-dimethyl-undeca-8,10-dienal

上游原料

1-[(1S,2R,3R)-3,6-Bis-(tert-butyl-dimethyl-silanyloxy)-2-methyl-1-((S)-1-methyl-allyl)-hexyloxymethyl]-4-methoxy-benzene (4R,5S,6S,7S)-1,6-bis(tert-butyldimethylsilanyloxy)-5,7-dimethylnon-8-en-4-ol (2S,3S,4S)-3-((tert-butyldimethylsilyl)oxy)-2,4-dimethylhex-5-en-1-ol

下游产品

2,2-dimethylpropionic acid (Z,Z,Z)-(6S,7S,8S,13R,14S,15S,16S)-13-carbamoyloxy-7,15-bis(4-methoxybenzyloxy)-6,8,14,16-tetramethyleicosa-4,9,17,19-tetraenyl ester Acetic acid (4Z,9Z)-(1R,6S,7R,8S)-7-(4-methoxy-benzyloxy)-1-[(Z)-(1S,2S,3S)-2-(4-methoxy-benzyloxy)-1,3-dimethyl-hepta-4,6-dienyl]-6,8-dimethyl-13-(tetrahydro-pyran-2-yloxy)-trideca-4,9-dienyl ester Acetic acid (4Z,9Z)-(1R,6S,7S,8S)-7-(4-methoxy-benzyloxy)-1-[(Z)-(1S,2S,3S)-2-(4-methoxy-benzyloxy)-1,3-dimethyl-hepta-4,6-dienyl]-6,8-dimethyl-13-(tetrahydro-pyran-2-yloxy)-trideca-4,9-dienyl ester Carbamic acid (4Z,9Z)-(1R,6S,7S,8S)-7-(4-methoxy-benzyloxy)-1-[(Z)-(1S,2S,3S)-2-(4-methoxy-benzyloxy)-1,3-dimethyl-hepta-4,6-dienyl]-6,8-dimethyl-13-(tetrahydro-pyran-2-yloxy)-trideca-4,9-dienyl ester