百科

(5R,10S,11S,12S,Z)-11-((4-methoxybenzyl)oxy)-5-((2R,3S,4S,Z)-3-((4-methoxybenzyl)oxy)-4-methylocta-5,7-dien-2-yl)-2,2,3,3,10,12,15,15,16,16-decamethyl-4,14-dioxa-3,15-disilaheptadec-8-ene

(5R,10S,11S,12S,Z)-11-((4-methoxybenzyl)oxy)-5-((2R,3S,4S,Z)-3-((4-methoxybenzyl)oxy)-4-methylocta-5,7-dien-2-yl)-2,2,3,3,10,12,15,15,16,16-decamethyl-4,14-dioxa-3,15-disilaheptadec-8-ene

CAS号：623926-74-9

英文名：(5R,10S,11S,12S,Z)-11-((4-methoxybenzyl)oxy)-5-((2R,3S,4S,Z)-3-((4-methoxybenzyl)oxy)-4-methylocta-5,7-dien-2-yl)-2,2,3,3,10,12,15,15,16,16-decamethyl-4,14-dioxa-3,15-disilaheptadec-8-ene

分子式：C48H80O6Si2

分子量：809.316

合成路线

tert-Butyl-[(2S,3R,4R)-5-iodo-3-(4-methoxy-benzyloxy)-2,4-dimethyl-pentyloxy]-dimethyl-silane

tert-Butyl-[(2S,3R,4R)-5-iodo-3-(4-methoxy-benzyloxy)-2,4-dimethyl-pentyloxy]-dimethyl-silane

(5R,10S,11S,12S,Z)-11-((4-methoxybenzyl)oxy)-5-((2R,3S,4S,Z)-3-((4-methoxybenzyl)oxy)-4-methylocta-5,7-dien-2-yl)-2,2,3,3,10,12,15,15,16,16-decamethyl-4,14-dioxa-3,15-disilaheptadec-8-ene

(5R,10S,11S,12S,Z)-11-((4-methoxybenzyl)oxy)-5-((2R,3S,4S,Z)-3-((4-methoxybenzyl)oxy)-4-methylocta-5,7-dien-2-yl)-2,2,3,3,10,12,15,15,16,16-decamethyl-4,14-dioxa-3,15-disilaheptadec-8-ene

(4R,5S,6S,7S)-1,6-bis(tert-butyldimethylsilanyloxy)-5,7-dimethylnon-8-en-4-ol

(4R,5S,6S,7S)-1,6-bis(tert-butyldimethylsilanyloxy)-5,7-dimethylnon-8-en-4-ol

(5R,10S,11S,12S,Z)-11-((4-methoxybenzyl)oxy)-5-((2R,3S,4S,Z)-3-((4-methoxybenzyl)oxy)-4-methylocta-5,7-dien-2-yl)-2,2,3,3,10,12,15,15,16,16-decamethyl-4,14-dioxa-3,15-disilaheptadec-8-ene

(5R,10S,11S,12S,Z)-11-((4-methoxybenzyl)oxy)-5-((2R,3S,4S,Z)-3-((4-methoxybenzyl)oxy)-4-methylocta-5,7-dien-2-yl)-2,2,3,3,10,12,15,15,16,16-decamethyl-4,14-dioxa-3,15-disilaheptadec-8-ene

1-[(1S,2R,3R)-3,6-Bis-(tert-butyl-dimethyl-silanyloxy)-2-methyl-1-((S)-1-methyl-allyl)-hexyloxymethyl]-4-methoxy-benzene

1-[(1S,2R,3R)-3,6-Bis-(tert-butyl-dimethyl-silanyloxy)-2-methyl-1-((S)-1-methyl-allyl)-hexyloxymethyl]-4-methoxy-benzene

(5R,10S,11S,12S,Z)-11-((4-methoxybenzyl)oxy)-5-((2R,3S,4S,Z)-3-((4-methoxybenzyl)oxy)-4-methylocta-5,7-dien-2-yl)-2,2,3,3,10,12,15,15,16,16-decamethyl-4,14-dioxa-3,15-disilaheptadec-8-ene

(5R,10S,11S,12S,Z)-11-((4-methoxybenzyl)oxy)-5-((2R,3S,4S,Z)-3-((4-methoxybenzyl)oxy)-4-methylocta-5,7-dien-2-yl)-2,2,3,3,10,12,15,15,16,16-decamethyl-4,14-dioxa-3,15-disilaheptadec-8-ene

(2S,3S,4S)-3-((tert-butyldimethylsilyl)oxy)-2,4-dimethylhex-5-en-1-ol

(2S,3S,4S)-3-((tert-butyldimethylsilyl)oxy)-2,4-dimethylhex-5-en-1-ol

(5R,10S,11S,12S,Z)-11-((4-methoxybenzyl)oxy)-5-((2R,3S,4S,Z)-3-((4-methoxybenzyl)oxy)-4-methylocta-5,7-dien-2-yl)-2,2,3,3,10,12,15,15,16,16-decamethyl-4,14-dioxa-3,15-disilaheptadec-8-ene

(5R,10S,11S,12S,Z)-11-((4-methoxybenzyl)oxy)-5-((2R,3S,4S,Z)-3-((4-methoxybenzyl)oxy)-4-methylocta-5,7-dien-2-yl)-2,2,3,3,10,12,15,15,16,16-decamethyl-4,14-dioxa-3,15-disilaheptadec-8-ene

上游原料

tert-Butyl-[(2S,3R,4R)-5-iodo-3-(4-methoxy-benzyloxy)-2,4-dimethyl-pentyloxy]-dimethyl-silane 1-[(1S,2R,3R)-3,6-Bis-(tert-butyl-dimethyl-silanyloxy)-2-methyl-1-((S)-1-methyl-allyl)-hexyloxymethyl]-4-methoxy-benzene (4R,5S,6S,7S)-1,6-bis(tert-butyldimethylsilanyloxy)-5,7-dimethylnon-8-en-4-ol (2S,3S,4S)-3-((tert-butyldimethylsilyl)oxy)-2,4-dimethylhex-5-en-1-ol

下游产品

Acetic acid (4Z,9Z)-(1R,6S,7R,8S)-7-(4-methoxy-benzyloxy)-1-[(Z)-(1S,2S,3S)-2-(4-methoxy-benzyloxy)-1,3-dimethyl-hepta-4,6-dienyl]-6,8-dimethyl-13-(tetrahydro-pyran-2-yloxy)-trideca-4,9-dienyl ester