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[(2R,4R,6S)-6-((Z)-(R)-7-Benzyloxy-4-hydroxy-2-oxo-6-triethylsilanyloxy-hept-3-enyl)-2-(4-methoxy-phenyl)-[1,3]dioxan-4-yl]-acetic acid tert-butyl ester

[(2R,4R,6S)-6-((Z)-(R)-7-Benzyloxy-4-hydroxy-2-oxo-6-triethylsilanyloxy-hept-3-enyl)-2-(4-methoxy-phenyl)-[1,3]dioxan-4-yl]-acetic acid tert-butyl ester

CAS号：625124-66-5

英文名：[(2R,4R,6S)-6-((Z)-(R)-7-Benzyloxy-4-hydroxy-2-oxo-6-triethylsilanyloxy-hept-3-enyl)-2-(4-methoxy-phenyl)-[1,3]dioxan-4-yl]-acetic acid tert-butyl ester

分子式：C37H54O9Si

分子量：670.905

合成路线

[(2R,4R,6S)-6-((2RS,6R)-7-benzyloxy-2-hydroxy-4-oxo-6-triethylsilanyloxyheptyl)-2-(4-methoxyphenyl)-[1,3]dioxan-4-yl]acetic acid tert-butyl ester

[(2R,4R,6S)-6-((2RS,6R)-7-benzyloxy-2-hydroxy-4-oxo-6-triethylsilanyloxyheptyl)-2-(4-methoxyphenyl)-[1,3]dioxan-4-yl]acetic acid tert-butyl ester

[(2R,4R,6S)-6-((Z)-(R)-7-Benzyloxy-4-hydroxy-2-oxo-6-triethylsilanyloxy-hept-3-enyl)-2-(4-methoxy-phenyl)-[1,3]dioxan-4-yl]-acetic acid tert-butyl ester

[(2R,4R,6S)-6-((Z)-(R)-7-Benzyloxy-4-hydroxy-2-oxo-6-triethylsilanyloxy-hept-3-enyl)-2-(4-methoxy-phenyl)-[1,3]dioxan-4-yl]-acetic acid tert-butyl ester

tert-butyl 2-[(6S,4R)-6-(hydroxymethyl)-2-(4-methoxyphenyl)-1,3-dioxan-4-yl]acetate

tert-butyl 2-[(6S,4R)-6-(hydroxymethyl)-2-(4-methoxyphenyl)-1,3-dioxan-4-yl]acetate

[(2R,4R,6S)-6-((Z)-(R)-7-Benzyloxy-4-hydroxy-2-oxo-6-triethylsilanyloxy-hept-3-enyl)-2-(4-methoxy-phenyl)-[1,3]dioxan-4-yl]-acetic acid tert-butyl ester

[(2R,4R,6S)-6-((Z)-(R)-7-Benzyloxy-4-hydroxy-2-oxo-6-triethylsilanyloxy-hept-3-enyl)-2-(4-methoxy-phenyl)-[1,3]dioxan-4-yl]-acetic acid tert-butyl ester

tert-butyl (3R,5S)-3,5-dihydroxy-6-triisoppropylsilanyloxyhexanoate

tert-butyl (3R,5S)-3,5-dihydroxy-6-triisoppropylsilanyloxyhexanoate

[(2R,4R,6S)-6-((Z)-(R)-7-Benzyloxy-4-hydroxy-2-oxo-6-triethylsilanyloxy-hept-3-enyl)-2-(4-methoxy-phenyl)-[1,3]dioxan-4-yl]-acetic acid tert-butyl ester

[(2R,4R,6S)-6-((Z)-(R)-7-Benzyloxy-4-hydroxy-2-oxo-6-triethylsilanyloxy-hept-3-enyl)-2-(4-methoxy-phenyl)-[1,3]dioxan-4-yl]-acetic acid tert-butyl ester

tert-butyl (2S,4R,6S)-2-(4-methoxyphenyl)-6-(2-oxoethyl)-[1,3]dioxan-4-ylacetate

tert-butyl (2S,4R,6S)-2-(4-methoxyphenyl)-6-(2-oxoethyl)-[1,3]dioxan-4-ylacetate

[(2R,4R,6S)-6-((Z)-(R)-7-Benzyloxy-4-hydroxy-2-oxo-6-triethylsilanyloxy-hept-3-enyl)-2-(4-methoxy-phenyl)-[1,3]dioxan-4-yl]-acetic acid tert-butyl ester

[(2R,4R,6S)-6-((Z)-(R)-7-Benzyloxy-4-hydroxy-2-oxo-6-triethylsilanyloxy-hept-3-enyl)-2-(4-methoxy-phenyl)-[1,3]dioxan-4-yl]-acetic acid tert-butyl ester

上游原料

[(2R,4R,6S)-6-((2RS,6R)-7-benzyloxy-2-hydroxy-4-oxo-6-triethylsilanyloxyheptyl)-2-(4-methoxyphenyl)-[1,3]dioxan-4-yl]acetic acid tert-butyl ester tert-butyl (3R,5S)-3,5-dihydroxy-6-triisoppropylsilanyloxyhexanoate tert-butyl 2-[(6S,4R)-6-(hydroxymethyl)-2-(4-methoxyphenyl)-1,3-dioxan-4-yl]acetate tert-butyl (2S,4R,6S)-2-(4-methoxyphenyl)-6-(2-oxoethyl)-[1,3]dioxan-4-ylacetate

下游产品

[(2R,4S,6R,8R)-8-benzyloxymethyl-4-hydroxy-10-oxo-1,7-dioxaspiro[5.5]undec-2-yl]acetic acid tert-butyl ester [(2R,4S,6R,8R,10S)-8-benzyloxymethyl-4,10-dihydroxy-10-methyl-1,7-dioxaspiro[5.5]undec-2-yl]acetic acid tert-butyl ester