百科

2-{6-[6-(tert-butyl-dimethyl-silanyloxy)-10-iodo-2-methoxy-1,4-dimethyl-deca-3,7,9-trienyl]-4-hydroxy-2-methoxy-5-methyl-tetrahydropyran-2-yl}-acetic acid methyl ester

2-{6-[6-(tert-butyl-dimethyl-silanyloxy)-10-iodo-2-methoxy-1,4-dimethyl-deca-3,7,9-trienyl]-4-hydroxy-2-methoxy-5-methyl-tetrahydropyran-2-yl}-acetic acid methyl ester

CAS号：627101-53-5

英文名：2-{6-[6-(tert-butyl-dimethyl-silanyloxy)-10-iodo-2-methoxy-1,4-dimethyl-deca-3,7,9-trienyl]-4-hydroxy-2-methoxy-5-methyl-tetrahydropyran-2-yl}-acetic acid methyl ester

分子式：C29H51IO7Si

分子量：666.701

合成路线

(6E,10E,12E)(2R,3S,4R,5R,9R)-9-(tert-butyldimethyl-silanyloxy)-1-(3,4-dimethoxy-benzyloxy)-13-iodo-5-methoxy-2,4,7-trimethyl-3-triethylsilanyloxy-trideca-6,10,12-triene

(6E,10E,12E)(2R,3S,4R,5R,9R)-9-(tert-butyldimethyl-silanyloxy)-1-(3,4-dimethoxy-benzyloxy)-13-iodo-5-methoxy-2,4,7-trimethyl-3-triethylsilanyloxy-trideca-6,10,12-triene

2-{6-[6-(tert-butyl-dimethyl-silanyloxy)-10-iodo-2-methoxy-1,4-dimethyl-deca-3,7,9-trienyl]-4-hydroxy-2-methoxy-5-methyl-tetrahydropyran-2-yl}-acetic acid methyl ester

2-{6-[6-(tert-butyl-dimethyl-silanyloxy)-10-iodo-2-methoxy-1,4-dimethyl-deca-3,7,9-trienyl]-4-hydroxy-2-methoxy-5-methyl-tetrahydropyran-2-yl}-acetic acid methyl ester

(6E,10E,12E)(2R,3S,4R,5R,9R)-9-(tert-butyldimethyl-silanyloxy)-13-iodo-5-methoxy-2,4,7-trimethyl-3-triethylsilanyloxy-trideca-6,10,12-trienol

(6E,10E,12E)(2R,3S,4R,5R,9R)-9-(tert-butyldimethyl-silanyloxy)-13-iodo-5-methoxy-2,4,7-trimethyl-3-triethylsilanyloxy-trideca-6,10,12-trienol

2-{6-[6-(tert-butyl-dimethyl-silanyloxy)-10-iodo-2-methoxy-1,4-dimethyl-deca-3,7,9-trienyl]-4-hydroxy-2-methoxy-5-methyl-tetrahydropyran-2-yl}-acetic acid methyl ester

2-{6-[6-(tert-butyl-dimethyl-silanyloxy)-10-iodo-2-methoxy-1,4-dimethyl-deca-3,7,9-trienyl]-4-hydroxy-2-methoxy-5-methyl-tetrahydropyran-2-yl}-acetic acid methyl ester

(2E,5S,6E,8E)-5-(tert-butyldimethylsilyloxy)-9-iodo-3-methyl-2,6,8-trienal

(2E,5S,6E,8E)-5-(tert-butyldimethylsilyloxy)-9-iodo-3-methyl-2,6,8-trienal

2-{6-[6-(tert-butyl-dimethyl-silanyloxy)-10-iodo-2-methoxy-1,4-dimethyl-deca-3,7,9-trienyl]-4-hydroxy-2-methoxy-5-methyl-tetrahydropyran-2-yl}-acetic acid methyl ester

2-{6-[6-(tert-butyl-dimethyl-silanyloxy)-10-iodo-2-methoxy-1,4-dimethyl-deca-3,7,9-trienyl]-4-hydroxy-2-methoxy-5-methyl-tetrahydropyran-2-yl}-acetic acid methyl ester

methyl-(2E,5S,6E,8E)-5-(tert-butyldimethylsilyloxy)-9-iodo-3-methyl-2,6,8-nontrienoate

methyl-(2E,5S,6E,8E)-5-(tert-butyldimethylsilyloxy)-9-iodo-3-methyl-2,6,8-nontrienoate

2-{6-[6-(tert-butyl-dimethyl-silanyloxy)-10-iodo-2-methoxy-1,4-dimethyl-deca-3,7,9-trienyl]-4-hydroxy-2-methoxy-5-methyl-tetrahydropyran-2-yl}-acetic acid methyl ester

2-{6-[6-(tert-butyl-dimethyl-silanyloxy)-10-iodo-2-methoxy-1,4-dimethyl-deca-3,7,9-trienyl]-4-hydroxy-2-methoxy-5-methyl-tetrahydropyran-2-yl}-acetic acid methyl ester

上游原料

(2E,5S,6E,8E)-5-(tert-butyldimethylsilyloxy)-9-iodo-3-methyl-2,6,8-trienal (6E,10E,12E)(2R,3S,4R,5R,9R)-9-(tert-butyldimethyl-silanyloxy)-13-iodo-5-methoxy-2,4,7-trimethyl-3-triethylsilanyloxy-trideca-6,10,12-trienol (6E,10E,12E)(2R,3S,4R,5R,9R)-9-(tert-butyldimethyl-silanyloxy)-1-(3,4-dimethoxy-benzyloxy)-13-iodo-5-methoxy-2,4,7-trimethyl-3-triethylsilanyloxy-trideca-6,10,12-triene methyl-(2E,5S,6E,8E)-5-(tert-butyldimethylsilyloxy)-9-iodo-3-methyl-2,6,8-nontrienoate

下游产品

2-{6-[6-(tert-butyl-dimethyl-silanyloxy)-10-iodo-2-methoxy-1,4-dimethyl-deca-3,7,9-trienyl]-4-hydroxy-2-methoxy-5-methyl-tetrahydropyran-2-yl}-acetic acid methyl ester