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[(2R,4S,5S,6S)-4-(tert-Butyl-dimethyl-silanyloxy)-6-(tert-butyl-dimethyl-silanyloxymethyl)-5-methyl-tetrahydro-pyran-2-yl]-acetaldehyde

[(2R,4S,5S,6S)-4-(tert-Butyl-dimethyl-silanyloxy)-6-(tert-butyl-dimethyl-silanyloxymethyl)-5-methyl-tetrahydro-pyran-2-yl]-acetaldehyde

CAS号：632358-08-8

英文名：[(2R,4S,5S,6S)-4-(tert-Butyl-dimethyl-silanyloxy)-6-(tert-butyl-dimethyl-silanyloxymethyl)-5-methyl-tetrahydro-pyran-2-yl]-acetaldehyde

分子式：C21H44O4Si2

分子量：416.743

合成路线

(2S,3R,4S,6S)-6-(2-(benzyloxy)ethyl)-2-(((tert-butyldimethylsilyl)oxy)methyl)-3-methyltetrahydro-2H-pyran-4-ol

(2S,3R,4S,6S)-6-(2-(benzyloxy)ethyl)-2-(((tert-butyldimethylsilyl)oxy)methyl)-3-methyltetrahydro-2H-pyran-4-ol

[(2R,4S,5S,6S)-4-(tert-Butyl-dimethyl-silanyloxy)-6-(tert-butyl-dimethyl-silanyloxymethyl)-5-methyl-tetrahydro-pyran-2-yl]-acetaldehyde

[(2R,4S,5S,6S)-4-(tert-Butyl-dimethyl-silanyloxy)-6-(tert-butyl-dimethyl-silanyloxymethyl)-5-methyl-tetrahydro-pyran-2-yl]-acetaldehyde

(2S,3S,6S)-6-(2-(benzyloxy)ethyl)-2-(((tert-butyldimethylsilyl)oxy)methyl)-3-methyltetrahydro-4H-pyran-4-one

(2S,3S,6S)-6-(2-(benzyloxy)ethyl)-2-(((tert-butyldimethylsilyl)oxy)methyl)-3-methyltetrahydro-4H-pyran-4-one

[(2R,4S,5S,6S)-4-(tert-Butyl-dimethyl-silanyloxy)-6-(tert-butyl-dimethyl-silanyloxymethyl)-5-methyl-tetrahydro-pyran-2-yl]-acetaldehyde

[(2R,4S,5S,6S)-4-(tert-Butyl-dimethyl-silanyloxy)-6-(tert-butyl-dimethyl-silanyloxymethyl)-5-methyl-tetrahydro-pyran-2-yl]-acetaldehyde

上游原料

(2S,3R,4S,6S)-6-(2-(benzyloxy)ethyl)-2-(((tert-butyldimethylsilyl)oxy)methyl)-3-methyltetrahydro-2H-pyran-4-ol (2S,3S,6S)-6-(2-(benzyloxy)ethyl)-2-(((tert-butyldimethylsilyl)oxy)methyl)-3-methyltetrahydro-4H-pyran-4-one

下游产品

2,2-Dimethyl-propionic acid (3E,5Z)-6-[(2R,3S,4S,6S)-4-(tert-butyl-dimethyl-silanyloxy)-6-((E)-3-iodo-allyl)-3-methyl-tetrahydro-pyran-2-yl]-5-methyl-hexa-3,5-dienyl ester ((2S,3S,4S,6S)-6-allyl-4-((tert-butyldimethylsilyl)oxy)-3-methyltetrahydro-2H-pyran-2-yl)methanol ((2S,3S,4S,6S)-4-((tert-butyldimethylsilyl)oxy)-6-((E)-4-((tertbutyldimethylsilyl)oxy)but-2-en-1-yl)-3-methyltetrahydro-2H-pyran-2-yl)methanol