百科

{(2R,4S,5R,6R)-6-[2-(tert-butyldimethylsilanyloxy)-ethyl]-5-(tert-butyldimethylsilanyloxymethyl)-5-methyl-4-triethylsilanyloxytetrahydropyran-2-yl}methanol

{(2R,4S,5R,6R)-6-[2-(tert-butyldimethylsilanyloxy)-ethyl]-5-(tert-butyldimethylsilanyloxymethyl)-5-methyl-4-triethylsilanyloxytetrahydropyran-2-yl}methanol

CAS号：635727-05-8

英文名：{(2R,4S,5R,6R)-6-[2-(tert-butyldimethylsilanyloxy)-ethyl]-5-(tert-butyldimethylsilanyloxymethyl)-5-methyl-4-triethylsilanyloxytetrahydropyran-2-yl}methanol

分子式：C28H62O5Si3

分子量：563.045

合成路线

(1S)-1-(2,2,5-trimethyl-1,3-dioxan-5-yl)but-3-en-1-ol

(1S)-1-(2,2,5-trimethyl-1,3-dioxan-5-yl)but-3-en-1-ol

{(2R,4S,5R,6R)-6-[2-(tert-butyldimethylsilanyloxy)-ethyl]-5-(tert-butyldimethylsilanyloxymethyl)-5-methyl-4-triethylsilanyloxytetrahydropyran-2-yl}methanol

{(2R,4S,5R,6R)-6-[2-(tert-butyldimethylsilanyloxy)-ethyl]-5-(tert-butyldimethylsilanyloxymethyl)-5-methyl-4-triethylsilanyloxytetrahydropyran-2-yl}methanol

{(2R,4S,5S)-4-allyl-5-methyl-2-phenyl-1,3-dioxan-5-yl}methanol

{(2R,4S,5S)-4-allyl-5-methyl-2-phenyl-1,3-dioxan-5-yl}methanol

{(2R,4S,5R,6R)-6-[2-(tert-butyldimethylsilanyloxy)-ethyl]-5-(tert-butyldimethylsilanyloxymethyl)-5-methyl-4-triethylsilanyloxytetrahydropyran-2-yl}methanol

{(2R,4S,5R,6R)-6-[2-(tert-butyldimethylsilanyloxy)-ethyl]-5-(tert-butyldimethylsilanyloxymethyl)-5-methyl-4-triethylsilanyloxytetrahydropyran-2-yl}methanol

(1R)-1-[(2R,4S,5R)-4-allyl-5-methyl-2-phenyl-1,3-dioxan-5-yl]but-3-en-1-ol

(1R)-1-[(2R,4S,5R)-4-allyl-5-methyl-2-phenyl-1,3-dioxan-5-yl]but-3-en-1-ol

{(2R,4S,5R,6R)-6-[2-(tert-butyldimethylsilanyloxy)-ethyl]-5-(tert-butyldimethylsilanyloxymethyl)-5-methyl-4-triethylsilanyloxytetrahydropyran-2-yl}methanol

{(2R,4S,5R,6R)-6-[2-(tert-butyldimethylsilanyloxy)-ethyl]-5-(tert-butyldimethylsilanyloxymethyl)-5-methyl-4-triethylsilanyloxytetrahydropyran-2-yl}methanol

上游原料

{(2R,4S,5S)-4-allyl-5-methyl-2-phenyl-1,3-dioxan-5-yl}methanol (1S)-1-(2,2,5-trimethyl-1,3-dioxan-5-yl)but-3-en-1-ol (1R)-1-[(2R,4S,5R)-4-allyl-5-methyl-2-phenyl-1,3-dioxan-5-yl]but-3-en-1-ol

下游产品

2-{4-[(2R,4S,5S,6R)-6-[2-(tert-butyldimethylsilanyloxy)ethyl]-5-(tert-butyldimethylsilanyloxymethyl)-5-methyl-4-triethylsilanyloxytetrahydropyran-2-yl]-(3E)-butene-1-sulfonyl}benzothiazole