百科

(2R*)-2-{(2S*,3R*)-2,3-bis(tert-butyldimethylsilyloxy)-4-[(S*)-3-oxo-6-methoxy-3,6-dihydro-2H-pyran-2-yl]butyl}-6-methoxy-2,3-dihydro-6H-pyran-3-one

(2R)-2-{(2S,3R)-2,3-bis(tert-butyldimethylsilyloxy)-4-[(S)-3-oxo-6-methoxy-3,6-dihydro-2H-pyran-2-yl]butyl}-6-methoxy-2,3-dihydro-6H-pyran-3-one

CAS号：637759-55-8

英文名：(2R*)-2-{(2S*,3R*)-2,3-bis(tert-butyldimethylsilyloxy)-4-[(S*)-3-oxo-6-methoxy-3,6-dihydro-2H-pyran-2-yl]butyl}-6-methoxy-2,3-dihydro-6H-pyran-3-one

分子式：C28H50O8Si2

分子量：570.863

合成路线

(3R*,4S*)-3,4-bis(tert-butyldimethylsilyloxy)hexanedial

(3R*,4S*)-3,4-bis(tert-butyldimethylsilyloxy)hexanedial

(2R*)-2-{(2S*,3R*)-2,3-bis(tert-butyldimethylsilyloxy)-4-[(S*)-3-oxo-6-methoxy-3,6-dihydro-2H-pyran-2-yl]butyl}-6-methoxy-2,3-dihydro-6H-pyran-3-one

(2R*)-2-{(2S*,3R*)-2,3-bis(tert-butyldimethylsilyloxy)-4-[(S*)-3-oxo-6-methoxy-3,6-dihydro-2H-pyran-2-yl]butyl}-6-methoxy-2,3-dihydro-6H-pyran-3-one

(3R*,4S*)-3,4-bis(tert-butyldimethylsilyloxy)-1,6-difuran-2-yl-hexane-1,6-dione

(3R*,4S*)-3,4-bis(tert-butyldimethylsilyloxy)-1,6-difuran-2-yl-hexane-1,6-dione

(2R*)-2-{(2S*,3R*)-2,3-bis(tert-butyldimethylsilyloxy)-4-[(S*)-3-oxo-6-methoxy-3,6-dihydro-2H-pyran-2-yl]butyl}-6-methoxy-2,3-dihydro-6H-pyran-3-one

(2R*)-2-{(2S*,3R*)-2,3-bis(tert-butyldimethylsilyloxy)-4-[(S*)-3-oxo-6-methoxy-3,6-dihydro-2H-pyran-2-yl]butyl}-6-methoxy-2,3-dihydro-6H-pyran-3-one

(1R*,3S*,4R*,6S*)-3,4-bis(tert-butyldimethylsilyloxy)-1,6-difuran-2-yl-hexane-1,6-diol

(1R*,3S*,4R*,6S*)-3,4-bis(tert-butyldimethylsilyloxy)-1,6-difuran-2-yl-hexane-1,6-diol

(2R*)-2-{(2S*,3R*)-2,3-bis(tert-butyldimethylsilyloxy)-4-[(S*)-3-oxo-6-methoxy-3,6-dihydro-2H-pyran-2-yl]butyl}-6-methoxy-2,3-dihydro-6H-pyran-3-one

(2R*)-2-{(2S*,3R*)-2,3-bis(tert-butyldimethylsilyloxy)-4-[(S*)-3-oxo-6-methoxy-3,6-dihydro-2H-pyran-2-yl]butyl}-6-methoxy-2,3-dihydro-6H-pyran-3-one

上游原料

(1R*,3S*,4R*,6S*)-3,4-bis(tert-butyldimethylsilyloxy)-1,6-difuran-2-yl-hexane-1,6-diol (3R*,4S*)-3,4-bis(tert-butyldimethylsilyloxy)-1,6-difuran-2-yl-hexane-1,6-dione (3R*,4S*)-3,4-bis(tert-butyldimethylsilyloxy)hexanedial

下游产品

(2R*)-2-{(2S*,3R*)-2,3-bis(tert-butyldimethylsilyloxy)-4-[(S*)-3-oxo-6-methoxy-3,4,5,6-tetrahydro-2H-pyran-2-yl]butyl}-6-methoxy-2,3,4,5-tetrahydro-6H-pyran-3-one