百科

(2S,5R)-1-(tert-butyldimethylsilanyloxy)-2-methyl-5-(triethylsilanyloxy)-8-(triisopropylsilanyl)oct-7-yn-3-one

(2S,5R)-1-(tert-butyldimethylsilanyloxy)-2-methyl-5-(triethylsilanyloxy)-8-(triisopropylsilanyl)oct-7-yn-3-one

CAS号：639087-17-5

英文名：(2S,5R)-1-(tert-butyldimethylsilanyloxy)-2-methyl-5-(triethylsilanyloxy)-8-(triisopropylsilanyl)oct-7-yn-3-one

分子式：C30H62O3Si3

分子量：555.068

合成路线

(2S)-1-(tert-butyldimethylsiloxy)-2-(1,3-dithian-2-yl)propane

(2S)-1-(tert-butyldimethylsiloxy)-2-(1,3-dithian-2-yl)propane

(2S,5R)-1-(tert-butyldimethylsilanyloxy)-2-methyl-5-(triethylsilanyloxy)-8-(triisopropylsilanyl)oct-7-yn-3-one

(2S,5R)-1-(tert-butyldimethylsilanyloxy)-2-methyl-5-(triethylsilanyloxy)-8-(triisopropylsilanyl)oct-7-yn-3-one

tert-butyldimethyl[(2S)-2-[2-[(2-oxiranyl)methyl]-1,3-dithian-2-yl]propoxy]silane

tert-butyldimethyl[(2S)-2-[2-[(2-oxiranyl)methyl]-1,3-dithian-2-yl]propoxy]silane

(2S,5R)-1-(tert-butyldimethylsilanyloxy)-2-methyl-5-(triethylsilanyloxy)-8-(triisopropylsilanyl)oct-7-yn-3-one

(2S,5R)-1-(tert-butyldimethylsilanyloxy)-2-methyl-5-(triethylsilanyloxy)-8-(triisopropylsilanyl)oct-7-yn-3-one

(2R)-1-{2-[(1S)-2-(tert-butyldimethylsilanyloxy)-1-methylethyl][1,3]dithian-2-yl}-5-(triisopropylsilanyl)pent-4-yn-2-ol

(2R)-1-{2-[(1S)-2-(tert-butyldimethylsilanyloxy)-1-methylethyl][1,3]dithian-2-yl}-5-(triisopropylsilanyl)pent-4-yn-2-ol

(2S,5R)-1-(tert-butyldimethylsilanyloxy)-2-methyl-5-(triethylsilanyloxy)-8-(triisopropylsilanyl)oct-7-yn-3-one

(2S,5R)-1-(tert-butyldimethylsilanyloxy)-2-methyl-5-(triethylsilanyloxy)-8-(triisopropylsilanyl)oct-7-yn-3-one

上游原料

(2S)-1-(tert-butyldimethylsiloxy)-2-(1,3-dithian-2-yl)propane (2R)-1-{2-[(1S)-2-(tert-butyldimethylsilanyloxy)-1-methylethyl][1,3]dithian-2-yl}-5-(triisopropylsilanyl)pent-4-yn-2-ol tert-butyldimethyl[(2S)-2-[2-[(2-oxiranyl)methyl]-1,3-dithian-2-yl]propoxy]silane

下游产品

acetic acid (2S,4S,6R,8S,10S)-8-[(3R)-4-(tert-butyldimethylsilanyloxy)-3-methyl-2-methylenebutyl]-10-hydroxy-2-[2-(p-methoxybenzyloxy)ethyl]-10-methyl-1,7-dioxaspiro[5.5]undec-4-yl ester (2R,5R)-2-methyl-3-methyleneoct-7-yne-1,5-diol acetic acid (2S,4S,6R,8S,10S)-8-[(3R)-4-(tert-butyldimethylsilanyloxy)-3-methyl-2-methylenebutyl]-2-[2-(p-methoxybenzyloxy)ethyl]-10-methyl-10-(triethylsilanyloxy)-1,7-dioxaspiro[5.5]undec-4-yl ester (8R,10S,12S,15S)-15-[(3R)-4-hydroxy-3-methyl-2-methylenebutyl]-10-[2-(p-methoxybenzyloxy)ethyl]-9,14-dioxa-1,5-dithiadispiro[5.1.5.3]hexadecan-12-ol 1-{(4S,6S)-6-[2-(p-methoxybenzyloxy)ethyl]-2,2-dimethyl[1,3]dioxan-4-yl}-3-[2-[(2S,5R)-5-methyl-4-methylene-2,6-bis(triethylsilanyloxy)hexyl][1,3]dithian-2-yl]propan-2-one {(2S,4S,6R,8S,10S)-4-acetoxy-8-[(3R)-4-(tert-butyldimethylsilanyloxy)-3-methyl-2-methylenebutyl]-10-methyl-10-(triethylsilanyloxy)-1,7-dioxaspiro[5.5]undec-2-yl}acetic acid allyl ester (2S,6R,8S,10S)-2-[(3R)-4-(tert-butyldimethylsilanyloxy)-3-methyl-2-methylenebutyl]-10-hydroxy-8-[2-(p-methoxybenzyloxy)ethyl]-1,7-dioxaspiro[5.5]undecan-4-one acetic acid (2S,4S,6R,8S,10S)-8-[(3R)-4-(tert-butyldimethylsilanyloxy)-3-methyl-2-methylenebutyl]-2-(2-hydroxyethyl)-10-methyl-10-(triethylsilanyloxy)-1,7-dioxaspiro[5.5]undec-4-yl ester (6S,9R)-1-{(4R,6S)-6-[2-(p-methoxybenzyloxy)ethyl]-2,2-dimethyl[1,3]dioxan-4-yl}-9-methyl-8-methylene-6,10-bis(triethylsilanyloxy)dec-3-yn-2-ol [(2R,4S,6S,8S,10S)-4-Acetoxy-10-methyl-8-((R)-3-methyl-2-methylene-4-oxo-butyl)-10-triethylsilanyloxy-1,7-dioxa-spiro[5.5]undec-2-yl]-acetic acid allyl ester {(2S,4S,6R,8S,10S)-4-acetoxy-8-[(3R)-4-(tert-butyldimethylsilanyloxy)-3-methyl-2-methylenebutyl]-10-methyl-10-(triethylsilanyloxy)-1,7-dioxaspiro[5.5]undec-2-yl}acetic acid