百科

(3aS,4S,6R,7aS)-6-((2R,3R)-3-Benzyloxy-2-hydroxy-butyl)-4-((E)-4-hydroxy-1,1-dimethyl-but-2-enyl)-4-methoxy-tetrahydro-[1,3]dioxolo[4,5-c]pyran-2-one

(3aS,4S,6R,7aS)-6-((2R,3R)-3-Benzyloxy-2-hydroxy-butyl)-4-((E)-4-hydroxy-1,1-dimethyl-but-2-enyl)-4-methoxy-tetrahydro-[1,3]dioxolo[4,5-c]pyran-2-one

CAS号：639786-36-0

英文名：(3aS,4S,6R,7aS)-6-((2R,3R)-3-Benzyloxy-2-hydroxy-butyl)-4-((E)-4-hydroxy-1,1-dimethyl-but-2-enyl)-4-methoxy-tetrahydro-[1,3]dioxolo[4,5-c]pyran-2-one

分子式：C24H34O8

分子量：450.522

合成路线

(3R,5R,6R)-6-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-5-(4-methoxy-benzyloxy)-heptanal

(3R,5R,6R)-6-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-5-(4-methoxy-benzyloxy)-heptanal

(3aS,4S,6R,7aS)-6-((2R,3R)-3-Benzyloxy-2-hydroxy-butyl)-4-((E)-4-hydroxy-1,1-dimethyl-but-2-enyl)-4-methoxy-tetrahydro-[1,3]dioxolo[4,5-c]pyran-2-one

(3aS,4S,6R,7aS)-6-((2R,3R)-3-Benzyloxy-2-hydroxy-butyl)-4-((E)-4-hydroxy-1,1-dimethyl-but-2-enyl)-4-methoxy-tetrahydro-[1,3]dioxolo[4,5-c]pyran-2-one

(4S,6R,7R)-7-Benzyloxy-6-(4-methoxy-benzyloxy)-oct-1-en-4-ol

(4S,6R,7R)-7-Benzyloxy-6-(4-methoxy-benzyloxy)-oct-1-en-4-ol

(3aS,4S,6R,7aS)-6-((2R,3R)-3-Benzyloxy-2-hydroxy-butyl)-4-((E)-4-hydroxy-1,1-dimethyl-but-2-enyl)-4-methoxy-tetrahydro-[1,3]dioxolo[4,5-c]pyran-2-one

(3aS,4S,6R,7aS)-6-((2R,3R)-3-Benzyloxy-2-hydroxy-butyl)-4-((E)-4-hydroxy-1,1-dimethyl-but-2-enyl)-4-methoxy-tetrahydro-[1,3]dioxolo[4,5-c]pyran-2-one

(E)-6-(4-Methoxy-benzyloxy)-3,3-dimethyl-hex-4-en-2-one

(E)-6-(4-Methoxy-benzyloxy)-3,3-dimethyl-hex-4-en-2-one

(3aS,4S,6R,7aS)-6-((2R,3R)-3-Benzyloxy-2-hydroxy-butyl)-4-((E)-4-hydroxy-1,1-dimethyl-but-2-enyl)-4-methoxy-tetrahydro-[1,3]dioxolo[4,5-c]pyran-2-one

(3aS,4S,6R,7aS)-6-((2R,3R)-3-Benzyloxy-2-hydroxy-butyl)-4-((E)-4-hydroxy-1,1-dimethyl-but-2-enyl)-4-methoxy-tetrahydro-[1,3]dioxolo[4,5-c]pyran-2-one

上游原料

(3R,5R,6R)-6-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-5-(4-methoxy-benzyloxy)-heptanal (4S,6R,7R)-7-Benzyloxy-6-(4-methoxy-benzyloxy)-oct-1-en-4-ol (E)-6-(4-Methoxy-benzyloxy)-3,3-dimethyl-hex-4-en-2-one

下游产品

(E)-4-[(3aS,4S,6R,7aS)-6-((2R,3R)-3-Benzyloxy-2-hydroxy-butyl)-4-hydroxy-2-oxo-tetrahydro-[1,3]dioxolo[4,5-c]pyran-4-yl]-4-methyl-pent-2-enal