百科

(S)-3-[(S)-2-((1E,6E)-(3S,5S)-3-Benzyloxy-7-iodo-5-methyl-hepta-1,6-dienyl)-3-methyl-5-oxo-cyclopent-1-enyl]-butyraldehyde

(S)-3-[(S)-2-((1E,6E)-(3S,5S)-3-Benzyloxy-7-iodo-5-methyl-hepta-1,6-dienyl)-3-methyl-5-oxo-cyclopent-1-enyl]-butyraldehyde

CAS号：658080-35-4

英文名：(S)-3-[(S)-2-((1E,6E)-(3S,5S)-3-Benzyloxy-7-iodo-5-methyl-hepta-1,6-dienyl)-3-methyl-5-oxo-cyclopent-1-enyl]-butyraldehyde

分子式：C25H31IO3

分子量：506.416

合成路线

(S)-3-((E)-(3S,5S)-3-Benzyloxy-6-hydroxy-5-methyl-hex-1-enyl)-2-[(S)-3-(tert-butyl-diphenyl-silanyloxy)-1-methyl-propyl]-4-methyl-cyclopent-2-enone

(S)-3-((E)-(3S,5S)-3-Benzyloxy-6-hydroxy-5-methyl-hex-1-enyl)-2-[(S)-3-(tert-butyl-diphenyl-silanyloxy)-1-methyl-propyl]-4-methyl-cyclopent-2-enone

(S)-3-[(S)-2-((1E,6E)-(3S,5S)-3-Benzyloxy-7-iodo-5-methyl-hepta-1,6-dienyl)-3-methyl-5-oxo-cyclopent-1-enyl]-butyraldehyde

(S)-3-[(S)-2-((1E,6E)-(3S,5S)-3-Benzyloxy-7-iodo-5-methyl-hepta-1,6-dienyl)-3-methyl-5-oxo-cyclopent-1-enyl]-butyraldehyde

(S)-2-[(S)-3-(tert-Butyl-diphenyl-silanyloxy)-1-methyl-propyl]-4-methyl-cyclopent-2-enone

(S)-2-[(S)-3-(tert-Butyl-diphenyl-silanyloxy)-1-methyl-propyl]-4-methyl-cyclopent-2-enone

(S)-3-[(S)-2-((1E,6E)-(3S,5S)-3-Benzyloxy-7-iodo-5-methyl-hepta-1,6-dienyl)-3-methyl-5-oxo-cyclopent-1-enyl]-butyraldehyde

(S)-3-[(S)-2-((1E,6E)-(3S,5S)-3-Benzyloxy-7-iodo-5-methyl-hepta-1,6-dienyl)-3-methyl-5-oxo-cyclopent-1-enyl]-butyraldehyde

tert-Butyl-((S)-3-methyl-4-trityloxy-butoxy)-diphenyl-silane

tert-Butyl-((S)-3-methyl-4-trityloxy-butoxy)-diphenyl-silane

(S)-3-[(S)-2-((1E,6E)-(3S,5S)-3-Benzyloxy-7-iodo-5-methyl-hepta-1,6-dienyl)-3-methyl-5-oxo-cyclopent-1-enyl]-butyraldehyde

(S)-3-[(S)-2-((1E,6E)-(3S,5S)-3-Benzyloxy-7-iodo-5-methyl-hepta-1,6-dienyl)-3-methyl-5-oxo-cyclopent-1-enyl]-butyraldehyde

tert-Butyl-((S)-3-methyl-4-phenylsulfanyl-butoxy)-diphenyl-silane

tert-Butyl-((S)-3-methyl-4-phenylsulfanyl-butoxy)-diphenyl-silane

(S)-3-[(S)-2-((1E,6E)-(3S,5S)-3-Benzyloxy-7-iodo-5-methyl-hepta-1,6-dienyl)-3-methyl-5-oxo-cyclopent-1-enyl]-butyraldehyde

(S)-3-[(S)-2-((1E,6E)-(3S,5S)-3-Benzyloxy-7-iodo-5-methyl-hepta-1,6-dienyl)-3-methyl-5-oxo-cyclopent-1-enyl]-butyraldehyde

(2S,6S)-5-Benzenesulfonyl-8-(tert-butyl-diphenyl-silanyloxy)-2,6-dimethyl-4-oxo-octanal

(2S,6S)-5-Benzenesulfonyl-8-(tert-butyl-diphenyl-silanyloxy)-2,6-dimethyl-4-oxo-octanal

(S)-3-[(S)-2-((1E,6E)-(3S,5S)-3-Benzyloxy-7-iodo-5-methyl-hepta-1,6-dienyl)-3-methyl-5-oxo-cyclopent-1-enyl]-butyraldehyde

(S)-3-[(S)-2-((1E,6E)-(3S,5S)-3-Benzyloxy-7-iodo-5-methyl-hepta-1,6-dienyl)-3-methyl-5-oxo-cyclopent-1-enyl]-butyraldehyde

上游原料

(S)-3-((E)-(3S,5S)-3-Benzyloxy-6-hydroxy-5-methyl-hex-1-enyl)-2-[(S)-3-(tert-butyl-diphenyl-silanyloxy)-1-methyl-propyl]-4-methyl-cyclopent-2-enone tert-Butyl-((S)-3-methyl-4-phenylsulfanyl-butoxy)-diphenyl-silane (S)-2-[(S)-3-(tert-Butyl-diphenyl-silanyloxy)-1-methyl-propyl]-4-methyl-cyclopent-2-enone tert-Butyl-((S)-3-methyl-4-trityloxy-butoxy)-diphenyl-silane (2S,6S)-5-Benzenesulfonyl-8-(tert-butyl-diphenyl-silanyloxy)-2,6-dimethyl-4-oxo-octanal

下游产品

(4E,9E)-(3S,6S,8S,11S,13S)-6-Benzyloxy-11-hydroxy-3,8,13-trimethyl-2,3,6,7,8,11,12,13-octahydro-cyclopentacyclododecen-1-one (4E,9E)-(3S,6S,8S,11R,13S)-6-Benzyloxy-11-hydroxy-3,8,13-trimethyl-2,3,6,7,8,11,12,13-octahydro-cyclopentacyclododecen-1-one