百科

(1S,11S,13S,15R)-7,15-Bis-(tert-butyl-dimethyl-silanyloxy)-11-(3-hydroxy-propyl)-10,17-dioxa-tricyclo[11.3.1.03,8]heptadeca-3,5,7-trien-9-one

(1S,11S,13S,15R)-7,15-Bis-(tert-butyl-dimethyl-silanyloxy)-11-(3-hydroxy-propyl)-10,17-dioxa-tricyclo[11.3.1.03,8]heptadeca-3,5,7-trien-9-one

CAS号：659738-85-9

英文名：(1S,11S,13S,15R)-7,15-Bis-(tert-butyl-dimethyl-silanyloxy)-11-(3-hydroxy-propyl)-10,17-dioxa-tricyclo[11.3.1.03,8]heptadeca-3,5,7-trien-9-one

分子式：C30H52O6Si2

分子量：564.901

合成路线

(1S,11S,13S,15R)-7,15-Bis-(tert-butyl-dimethyl-silanyloxy)-11-[3-(tert-butyl-dimethyl-silanyloxy)-propyl]-10,17-dioxa-tricyclo[11.3.1.03,8]heptadeca-3(8),4,6-trien-9-one

(1S,11S,13S,15R)-7,15-Bis-(tert-butyl-dimethyl-silanyloxy)-11-[3-(tert-butyl-dimethyl-silanyloxy)-propyl]-10,17-dioxa-tricyclo[11.3.1.03,8]heptadeca-3(8),4,6-trien-9-one

(1S,11S,13S,15R)-7,15-Bis-(tert-butyl-dimethyl-silanyloxy)-11-(3-hydroxy-propyl)-10,17-dioxa-tricyclo[11.3.1.03,8]heptadeca-3,5,7-trien-9-one

(1S,11S,13S,15R)-7,15-Bis-(tert-butyl-dimethyl-silanyloxy)-11-(3-hydroxy-propyl)-10,17-dioxa-tricyclo[11.3.1.03,8]heptadeca-3,5,7-trien-9-one

(1S,11S,13R,15R)-15-Benzyloxy-11-(3-benzyloxy-propyl)-7-methoxy-10,17-dioxa-tricyclo[11.3.1.03,8]heptadeca-3(8),4,6-trien-9-one

(1S,11S,13R,15R)-15-Benzyloxy-11-(3-benzyloxy-propyl)-7-methoxy-10,17-dioxa-tricyclo[11.3.1.03,8]heptadeca-3(8),4,6-trien-9-one

(1S,11S,13S,15R)-7,15-Bis-(tert-butyl-dimethyl-silanyloxy)-11-(3-hydroxy-propyl)-10,17-dioxa-tricyclo[11.3.1.03,8]heptadeca-3,5,7-trien-9-one

(1S,11S,13S,15R)-7,15-Bis-(tert-butyl-dimethyl-silanyloxy)-11-(3-hydroxy-propyl)-10,17-dioxa-tricyclo[11.3.1.03,8]heptadeca-3,5,7-trien-9-one

上游原料

(1S,11S,13R,15R)-15-Benzyloxy-11-(3-benzyloxy-propyl)-7-methoxy-10,17-dioxa-tricyclo[11.3.1.03,8]heptadeca-3(8),4,6-trien-9-one (1S,11S,13S,15R)-7,15-Bis-(tert-butyl-dimethyl-silanyloxy)-11-[3-(tert-butyl-dimethyl-silanyloxy)-propyl]-10,17-dioxa-tricyclo[11.3.1.03,8]heptadeca-3(8),4,6-trien-9-one

下游产品

(2Z,4Z)-Hepta-2,4-dienoic acid {3-[(1S,11S,13S,15R)-7,15-bis-(tert-butyl-dimethyl-silanyloxy)-9-oxo-10,17-dioxa-tricyclo[11.3.1.03,8]heptadeca-3(8),4,6-trien-11-yl]-1-hydroxy-propyl}-amide 3,11-di-O-tert-butyldimethylsilylapicularen A