百科

4R-{2S-[2-(3S-hydroxy-7-tritylsulfanylhept-4E-enoylamino)propionylamino]-3-tritylsulfanylpropionylamino}-5R-methyl-3S-triisopropylsilanyloxyhexanoic acid 2,2,2-trichloroethyl ester

4R-{2S-[2-(3S-hydroxy-7-tritylsulfanylhept-4E-enoylamino)propionylamino]-3-tritylsulfanylpropionylamino}-5R-methyl-3S-triisopropylsilanyloxyhexanoic acid 2,2,2-trichloroethyl ester

CAS号：663919-03-7

英文名：4R-{2S-[2-(3S-hydroxy-7-tritylsulfanylhept-4E-enoylamino)propionylamino]-3-tritylsulfanylpropionylamino}-5R-methyl-3S-triisopropylsilanyloxyhexanoic acid 2,2,2-trichloroethyl ester

分子式：C69H84Cl3N3O7S2Si

分子量：1266.0

合成路线

(2E)-5-[(triphenylmethyl)thio]-2-pentenal

(2E)-5-[(triphenylmethyl)thio]-2-pentenal

4R-{2S-[2-(3S-hydroxy-7-tritylsulfanylhept-4E-enoylamino)propionylamino]-3-tritylsulfanylpropionylamino}-5R-methyl-3S-triisopropylsilanyloxyhexanoic acid 2,2,2-trichloroethyl ester

4R-{2S-[2-(3S-hydroxy-7-tritylsulfanylhept-4E-enoylamino)propionylamino]-3-tritylsulfanylpropionylamino}-5R-methyl-3S-triisopropylsilanyloxyhexanoic acid 2,2,2-trichloroethyl ester

(3S,4R)-4-(tert-butoxycarbonylamino)-3-hydroxy-5-methylhexanoic acid methyl ester

(3S,4R)-4-(tert-butoxycarbonylamino)-3-hydroxy-5-methylhexanoic acid methyl ester

4R-{2S-[2-(3S-hydroxy-7-tritylsulfanylhept-4E-enoylamino)propionylamino]-3-tritylsulfanylpropionylamino}-5R-methyl-3S-triisopropylsilanyloxyhexanoic acid 2,2,2-trichloroethyl ester

4R-{2S-[2-(3S-hydroxy-7-tritylsulfanylhept-4E-enoylamino)propionylamino]-3-tritylsulfanylpropionylamino}-5R-methyl-3S-triisopropylsilanyloxyhexanoic acid 2,2,2-trichloroethyl ester

4R-[2-(9H-fluoren-9-ylmethoxycarbonylamino)-3S-tritylsulfanylpropionylamino]-3S-hydroxy-5-methylhexanoic acid 2,2,2-trichloroethyl ester

4R-[2-(9H-fluoren-9-ylmethoxycarbonylamino)-3S-tritylsulfanylpropionylamino]-3S-hydroxy-5-methylhexanoic acid 2,2,2-trichloroethyl ester

4R-{2S-[2-(3S-hydroxy-7-tritylsulfanylhept-4E-enoylamino)propionylamino]-3-tritylsulfanylpropionylamino}-5R-methyl-3S-triisopropylsilanyloxyhexanoic acid 2,2,2-trichloroethyl ester

4R-{2S-[2-(3S-hydroxy-7-tritylsulfanylhept-4E-enoylamino)propionylamino]-3-tritylsulfanylpropionylamino}-5R-methyl-3S-triisopropylsilanyloxyhexanoic acid 2,2,2-trichloroethyl ester

上游原料

4R-[2-(9H-fluoren-9-ylmethoxycarbonylamino)-3S-tritylsulfanylpropionylamino]-3S-hydroxy-5-methylhexanoic acid 2,2,2-trichloroethyl ester (2E)-5-[(triphenylmethyl)thio]-2-pentenal (3S,4R)-4-(tert-butoxycarbonylamino)-3-hydroxy-5-methylhexanoic acid methyl ester

下游产品

2R-isopropyl-6R-methyl-13S-triisopropylsilanyloxy-2S-[4-(triphenyl-λ-sulfanyl)but-1E-enyl]-9S-tritylsulfanylmethyl-1-oxa-5,8,11-triazacyclopentadecane-4,7,10,15-tetraone 4R-{2S-[2-(3S-hydroxy-7-tritylsulfanylhept-4E-enoylamino)propionylamino]-3-tritylsulfanylpropionylamino}-5R-methyl-3S-triisopropylsilanyloxyhexanoic acid (9S,17S)-6R-isopropyl-20R-methyl-5S-triisopropylsilanyloxy-2-oxa-11,12-dithia-7,19,22-triazabicyclo[7.7.6]docos-15E-ene-3,8,18,21-tetraone