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(3R,5R)-1-benzyloxycarbonyl-3,5-bis(tert-butyldimethylsiloxy)-4-(1-imidazolylcarbothioyloxy)-piperidine

(3R,5R)-1-benzyloxycarbonyl-3,5-bis(tert-butyldimethylsiloxy)-4-(1-imidazolylcarbothioyloxy)-piperidine

CAS号：664978-86-3

英文名：(3R,5R)-1-benzyloxycarbonyl-3,5-bis(tert-butyldimethylsiloxy)-4-(1-imidazolylcarbothioyloxy)-piperidine

分子式：C29H47N3O5SSi2

分子量：605.937

合成路线

1-O-benzoyl-2,3-O-isopropylidene-α-D-mannofuranoside

1-O-benzoyl-2,3-O-isopropylidene-α-D-mannofuranoside

(3R,5R)-1-benzyloxycarbonyl-3,5-bis(tert-butyldimethylsiloxy)-4-(1-imidazolylcarbothioyloxy)-piperidine

(3R,5R)-1-benzyloxycarbonyl-3,5-bis(tert-butyldimethylsiloxy)-4-(1-imidazolylcarbothioyloxy)-piperidine

(+)-2,3:5,6-di-O-isopropylidene-α-D-mannofuranos-3-yl benzoate

(+)-2,3:5,6-di-O-isopropylidene-α-D-mannofuranos-3-yl benzoate

(3R,5R)-1-benzyloxycarbonyl-3,5-bis(tert-butyldimethylsiloxy)-4-(1-imidazolylcarbothioyloxy)-piperidine

(3R,5R)-1-benzyloxycarbonyl-3,5-bis(tert-butyldimethylsiloxy)-4-(1-imidazolylcarbothioyloxy)-piperidine

5-azido-1-O-benzoyl-5-deoxy-2,3-O-isopropylidene-α-D-lyxofuranose

5-azido-1-O-benzoyl-5-deoxy-2,3-O-isopropylidene-α-D-lyxofuranose

(3R,5R)-1-benzyloxycarbonyl-3,5-bis(tert-butyldimethylsiloxy)-4-(1-imidazolylcarbothioyloxy)-piperidine

(3R,5R)-1-benzyloxycarbonyl-3,5-bis(tert-butyldimethylsiloxy)-4-(1-imidazolylcarbothioyloxy)-piperidine

(3R,4S,5R)-5-hydroxy-3,4-O-(1-methylethylidene)piperidine

(3R,4S,5R)-5-hydroxy-3,4-O-(1-methylethylidene)piperidine

(3R,5R)-1-benzyloxycarbonyl-3,5-bis(tert-butyldimethylsiloxy)-4-(1-imidazolylcarbothioyloxy)-piperidine

(3R,5R)-1-benzyloxycarbonyl-3,5-bis(tert-butyldimethylsiloxy)-4-(1-imidazolylcarbothioyloxy)-piperidine

(3R,5R)-3,4,5-Trihydroxy-piperidine-1-carboxylic acid benzyl ester

(3R,5R)-3,4,5-Trihydroxy-piperidine-1-carboxylic acid benzyl ester

(3R,5R)-1-benzyloxycarbonyl-3,5-bis(tert-butyldimethylsiloxy)-4-(1-imidazolylcarbothioyloxy)-piperidine

(3R,5R)-1-benzyloxycarbonyl-3,5-bis(tert-butyldimethylsiloxy)-4-(1-imidazolylcarbothioyloxy)-piperidine

(3R,4S,5R)-1-benzyloxycarbonyl-4,5-isopropylidenedioxypiperidin-3-ol

(3R,4S,5R)-1-benzyloxycarbonyl-4,5-isopropylidenedioxypiperidin-3-ol

(3R,5R)-1-benzyloxycarbonyl-3,5-bis(tert-butyldimethylsiloxy)-4-(1-imidazolylcarbothioyloxy)-piperidine

(3R,5R)-1-benzyloxycarbonyl-3,5-bis(tert-butyldimethylsiloxy)-4-(1-imidazolylcarbothioyloxy)-piperidine

上游原料

5-azido-1-O-benzoyl-5-deoxy-2,3-O-isopropylidene-α-D-lyxofuranose (3R,4S,5R)-5-hydroxy-3,4-O-(1-methylethylidene)piperidine (+)-2,3:5,6-di-O-isopropylidene-α-D-mannofuranos-3-yl benzoate (3R,4S,5R)-1-benzyloxycarbonyl-4,5-isopropylidenedioxypiperidin-3-ol 1-O-benzoyl-2,3-O-isopropylidene-α-D-mannofuranoside (3R,5R)-3,4,5-Trihydroxy-piperidine-1-carboxylic acid benzyl ester

下游产品

1-[(3S,5S)-3,5-Bis-(tert-butyl-dimethyl-silanyloxy)-piperidin-1-yl]-2-[(1R,3aS,7aR)-1-((R)-5-methoxymethoxy-1,5-dimethyl-hexyl)-7a-methyl-octahydro-inden-(4E)-ylidene]-ethanone (3R,5R)-3,5-bis(tert-butyldimethylsilyloxy)piperidine (3S,5S)-1-benzyloxycarbonyl-3,5-bis(tert-butyldimethylsilyloxy)piperidine