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(4R,5S,8S,9S,10S)-11-(tert-Butyl-dimethyl-silanyloxy)-5,9-bis-methoxymethoxy-4,8,10-trimethyl-1-trimethylsilanyl-undec-1-yn-3-one

(4R,5S,8S,9S,10S)-11-(tert-Butyl-dimethyl-silanyloxy)-5,9-bis-methoxymethoxy-4,8,10-trimethyl-1-trimethylsilanyl-undec-1-yn-3-one

CAS号：676254-78-7

英文名：(4R,5S,8S,9S,10S)-11-(tert-Butyl-dimethyl-silanyloxy)-5,9-bis-methoxymethoxy-4,8,10-trimethyl-1-trimethylsilanyl-undec-1-yn-3-one

分子式：C27H54O6Si2

分子量：530.885

合成路线

(4R,5S)-3-[(2R,3S,4S)-3-(methoxymethoxy)-2,4-dimethylhept-6-enoyl]-4-methyl-5-phenyl-1,3-oxazolidin-2-one

(4R,5S)-3-[(2R,3S,4S)-3-(methoxymethoxy)-2,4-dimethylhept-6-enoyl]-4-methyl-5-phenyl-1,3-oxazolidin-2-one

(4R,5S,8S,9S,10S)-11-(tert-Butyl-dimethyl-silanyloxy)-5,9-bis-methoxymethoxy-4,8,10-trimethyl-1-trimethylsilanyl-undec-1-yn-3-one

(4R,5S,8S,9S,10S)-11-(tert-Butyl-dimethyl-silanyloxy)-5,9-bis-methoxymethoxy-4,8,10-trimethyl-1-trimethylsilanyl-undec-1-yn-3-one

((2S,3S,4S,7S,8S)-9-Benzyloxy-3,7-bis-methoxymethoxy-2,4,8-trimethyl-nonyloxy)-tert-butyl-dimethyl-silane

((2S,3S,4S,7S,8S)-9-Benzyloxy-3,7-bis-methoxymethoxy-2,4,8-trimethyl-nonyloxy)-tert-butyl-dimethyl-silane

(4R,5S,8S,9S,10S)-11-(tert-Butyl-dimethyl-silanyloxy)-5,9-bis-methoxymethoxy-4,8,10-trimethyl-1-trimethylsilanyl-undec-1-yn-3-one

(4R,5S,8S,9S,10S)-11-(tert-Butyl-dimethyl-silanyloxy)-5,9-bis-methoxymethoxy-4,8,10-trimethyl-1-trimethylsilanyl-undec-1-yn-3-one

(2S,3S,6S,7S,8S)-1-Benzyloxy-9-(tert-butyl-dimethyl-silanyloxy)-7-methoxymethoxy-2,6,8-trimethyl-nonan-3-ol

(2S,3S,6S,7S,8S)-1-Benzyloxy-9-(tert-butyl-dimethyl-silanyloxy)-7-methoxymethoxy-2,6,8-trimethyl-nonan-3-ol

(4R,5S,8S,9S,10S)-11-(tert-Butyl-dimethyl-silanyloxy)-5,9-bis-methoxymethoxy-4,8,10-trimethyl-1-trimethylsilanyl-undec-1-yn-3-one

(4R,5S,8S,9S,10S)-11-(tert-Butyl-dimethyl-silanyloxy)-5,9-bis-methoxymethoxy-4,8,10-trimethyl-1-trimethylsilanyl-undec-1-yn-3-one

2,3,5-trihydroxy-24,34,53,71-heptaoxid-2-ene

2,3,5-trihydroxy-24,34,53,71-heptaoxid-2-ene

(4R,5S,8S,9S,10S)-11-(tert-Butyl-dimethyl-silanyloxy)-5,9-bis-methoxymethoxy-4,8,10-trimethyl-1-trimethylsilanyl-undec-1-yn-3-one

(4R,5S,8S,9S,10S)-11-(tert-Butyl-dimethyl-silanyloxy)-5,9-bis-methoxymethoxy-4,8,10-trimethyl-1-trimethylsilanyl-undec-1-yn-3-one

上游原料

(2S,3S,6S,7S,8S)-1-Benzyloxy-9-(tert-butyl-dimethyl-silanyloxy)-7-methoxymethoxy-2,6,8-trimethyl-nonan-3-ol (4R,5S)-3-[(2R,3S,4S)-3-(methoxymethoxy)-2,4-dimethylhept-6-enoyl]-4-methyl-5-phenyl-1,3-oxazolidin-2-one ((2S,3S,4S,7S,8S)-9-Benzyloxy-3,7-bis-methoxymethoxy-2,4,8-trimethyl-nonyloxy)-tert-butyl-dimethyl-silane

下游产品

(5S,6S)-6-[(1S,4S,5R,6R)-6-(tert-butyldiphenylsilyloxy)-4-hydroxy-1,5-dimethyl-oct-7-ynyl]-5-methyl-5,6-dihydro-pyran-2-one