百科

6-O-acetyl-4-O-(2-azido-4-O-benzyl-2-deoxy-3,6-di-O-benzoyl-α-D-glucopyranosyl)-2-O-benzoyl-3-O-benzyl-L-idopyranosyl acetate

6-O-acetyl-4-O-(2-azido-4-O-benzyl-2-deoxy-3,6-di-O-benzoyl-α-D-glucopyranosyl)-2-O-benzoyl-3-O-benzyl-L-idopyranosyl acetate

CAS号：676342-76-0

英文名：6-O-acetyl-4-O-(2-azido-4-O-benzyl-2-deoxy-3,6-di-O-benzoyl-α-D-glucopyranosyl)-2-O-benzoyl-3-O-benzyl-L-idopyranosyl acetate

分子式：C51H49N3O15

分子量：943.946

合成路线

6-deoxy-1,2:3,5-di-O-isopropylidene-α-D-xylo-hex-5-enofuranose

6-deoxy-1,2:3,5-di-O-isopropylidene-α-D-xylo-hex-5-enofuranose

6-O-acetyl-4-O-(2-azido-4-O-benzyl-2-deoxy-3,6-di-O-benzoyl-α-D-glucopyranosyl)-2-O-benzoyl-3-O-benzyl-L-idopyranosyl acetate

6-O-acetyl-4-O-(2-azido-4-O-benzyl-2-deoxy-3,6-di-O-benzoyl-α-D-glucopyranosyl)-2-O-benzoyl-3-O-benzyl-L-idopyranosyl acetate

1,2:3,5-di-O-isopropylidene-β-L-idofuranoside

1,2:3,5-di-O-isopropylidene-β-L-idofuranoside

6-O-acetyl-4-O-(2-azido-4-O-benzyl-2-deoxy-3,6-di-O-benzoyl-α-D-glucopyranosyl)-2-O-benzoyl-3-O-benzyl-L-idopyranosyl acetate

6-O-acetyl-4-O-(2-azido-4-O-benzyl-2-deoxy-3,6-di-O-benzoyl-α-D-glucopyranosyl)-2-O-benzoyl-3-O-benzyl-L-idopyranosyl acetate

1,6-anhydro-2,3,4-triO-trimethylsilyl-β-L-idopyranose

1,6-anhydro-2,3,4-triO-trimethylsilyl-β-L-idopyranose

6-O-acetyl-4-O-(2-azido-4-O-benzyl-2-deoxy-3,6-di-O-benzoyl-α-D-glucopyranosyl)-2-O-benzoyl-3-O-benzyl-L-idopyranosyl acetate

6-O-acetyl-4-O-(2-azido-4-O-benzyl-2-deoxy-3,6-di-O-benzoyl-α-D-glucopyranosyl)-2-O-benzoyl-3-O-benzyl-L-idopyranosyl acetate

上游原料

1,6-anhydro-2,3,4-triO-trimethylsilyl-β-L-idopyranose 6-deoxy-1,2:3,5-di-O-isopropylidene-α-D-xylo-hex-5-enofuranose 1,2:3,5-di-O-isopropylidene-β-L-idofuranoside

下游产品

methyl 4-O-(2-azido-4-O-benzyl-2-deoxy-3,6-di-O-benzoyl-α-D-glucopyranosyl)-2-O-benzoyl-3-O-benzyl-α-L-idopyranoside (2R,3S,4S,5R,6R)-3-((2R,3R,4R,5S,6R)-3-Azido-4-benzoyloxy-6-benzoyloxymethyl-5-benzyloxy-tetrahydro-pyran-2-yloxy)-5-benzoyloxy-4-benzyloxy-6-methoxy-tetrahydro-pyran-2-carboxylic acid