百科

[2-((2R,3S,6S,8S,9R)-8-Benzyloxymethyl-3,9-dimethyl-1,7-dioxa-spiro[5.5]undec-2-yl)-ethoxy]-tert-butyl-dimethyl-silane

[2-((2R,3S,6S,8S,9R)-8-Benzyloxymethyl-3,9-dimethyl-1,7-dioxa-spiro[5.5]undec-2-yl)-ethoxy]-tert-butyl-dimethyl-silane

CAS号：677752-47-5

英文名：[2-((2R,3S,6S,8S,9R)-8-Benzyloxymethyl-3,9-dimethyl-1,7-dioxa-spiro[5.5]undec-2-yl)-ethoxy]-tert-butyl-dimethyl-silane

分子式：C27H46O4Si

分子量：462.737

合成路线

(4S,5R)-7-(tert-Butyl-dimethyl-silanyloxy)-4-methyl-5-triethylsilanyloxy-heptanoic acid methoxy-methyl-amide

(4S,5R)-7-(tert-Butyl-dimethyl-silanyloxy)-4-methyl-5-triethylsilanyloxy-heptanoic acid methoxy-methyl-amide

[2-((2R,3S,6S,8S,9R)-8-Benzyloxymethyl-3,9-dimethyl-1,7-dioxa-spiro[5.5]undec-2-yl)-ethoxy]-tert-butyl-dimethyl-silane

[2-((2R,3S,6S,8S,9R)-8-Benzyloxymethyl-3,9-dimethyl-1,7-dioxa-spiro[5.5]undec-2-yl)-ethoxy]-tert-butyl-dimethyl-silane

(3R,4S)-1-[(tert-butyldimethylsilyl)oxy]-4-methylhex-5-en-3-ol

(3R,4S)-1-[(tert-butyldimethylsilyl)oxy]-4-methylhex-5-en-3-ol

[2-((2R,3S,6S,8S,9R)-8-Benzyloxymethyl-3,9-dimethyl-1,7-dioxa-spiro[5.5]undec-2-yl)-ethoxy]-tert-butyl-dimethyl-silane

[2-((2R,3S,6S,8S,9R)-8-Benzyloxymethyl-3,9-dimethyl-1,7-dioxa-spiro[5.5]undec-2-yl)-ethoxy]-tert-butyl-dimethyl-silane

上游原料

(4S,5R)-7-(tert-Butyl-dimethyl-silanyloxy)-4-methyl-5-triethylsilanyloxy-heptanoic acid methoxy-methyl-amide (3R,4S)-1-[(tert-butyldimethylsilyl)oxy]-4-methylhex-5-en-3-ol

下游产品

(2E,4E)-6-((2R,3S,6S,8S,9R)-8-Ethynyl-3,9-dimethyl-1,7-dioxa-spiro[5.5]undec-2-yl)-4-methyl-hexa-2,4-dienal (4E,6E)-(2R,3S)-8-((2R,3S,6S,8S,9R)-8-Ethynyl-3,9-dimethyl-1,7-dioxa-spiro[5.5]undec-2-yl)-3-hydroxy-1-((S)-4-isopropyl-2-thioxo-oxazolidin-3-yl)-2,6-dimethyl-octa-4,6-dien-1-one tert-Butyl-[2-((2R,3S,6S,8S,9R)-8-ethynyl-3,9-dimethyl-1,7-dioxa-spiro[5.5]undec-2-yl)-ethoxy]-dimethyl-silane