百科

tert-Butyl-[2-((2R,3S,6S,8S,9R)-8-ethynyl-3,9-dimethyl-1,7-dioxa-spiro[5.5]undec-2-yl)-ethoxy]-dimethyl-silane

tert-Butyl-[2-((2R,3S,6S,8S,9R)-8-ethynyl-3,9-dimethyl-1,7-dioxa-spiro[5.5]undec-2-yl)-ethoxy]-dimethyl-silane

CAS号：677752-54-4

英文名：tert-Butyl-[2-((2R,3S,6S,8S,9R)-8-ethynyl-3,9-dimethyl-1,7-dioxa-spiro[5.5]undec-2-yl)-ethoxy]-dimethyl-silane

分子式：C21H38O3Si

分子量：366.61

合成路线

(3R,4S)-1-[(tert-butyldimethylsilyl)oxy]-4-methylhex-5-en-3-ol

(3R,4S)-1-[(tert-butyldimethylsilyl)oxy]-4-methylhex-5-en-3-ol

tert-Butyl-[2-((2R,3S,6S,8S,9R)-8-ethynyl-3,9-dimethyl-1,7-dioxa-spiro[5.5]undec-2-yl)-ethoxy]-dimethyl-silane

tert-Butyl-[2-((2R,3S,6S,8S,9R)-8-ethynyl-3,9-dimethyl-1,7-dioxa-spiro[5.5]undec-2-yl)-ethoxy]-dimethyl-silane

((1S,2R)-1-Benzyloxymethyl-2-methyl-but-3-ynyloxy)-triethyl-silane

((1S,2R)-1-Benzyloxymethyl-2-methyl-but-3-ynyloxy)-triethyl-silane

tert-Butyl-[2-((2R,3S,6S,8S,9R)-8-ethynyl-3,9-dimethyl-1,7-dioxa-spiro[5.5]undec-2-yl)-ethoxy]-dimethyl-silane

tert-Butyl-[2-((2R,3S,6S,8S,9R)-8-ethynyl-3,9-dimethyl-1,7-dioxa-spiro[5.5]undec-2-yl)-ethoxy]-dimethyl-silane

(2R,3R)-5-(tert-Butyl-dimethyl-silanyloxy)-2-methyl-3-triethylsilanyloxy-pentanal

(2R,3R)-5-(tert-Butyl-dimethyl-silanyloxy)-2-methyl-3-triethylsilanyloxy-pentanal

tert-Butyl-[2-((2R,3S,6S,8S,9R)-8-ethynyl-3,9-dimethyl-1,7-dioxa-spiro[5.5]undec-2-yl)-ethoxy]-dimethyl-silane

tert-Butyl-[2-((2R,3S,6S,8S,9R)-8-ethynyl-3,9-dimethyl-1,7-dioxa-spiro[5.5]undec-2-yl)-ethoxy]-dimethyl-silane

(4S,5R)-7-(tert-Butyl-dimethyl-silanyloxy)-4-methyl-5-triethylsilanyloxy-heptanoic acid methoxy-methyl-amide

(4S,5R)-7-(tert-Butyl-dimethyl-silanyloxy)-4-methyl-5-triethylsilanyloxy-heptanoic acid methoxy-methyl-amide

tert-Butyl-[2-((2R,3S,6S,8S,9R)-8-ethynyl-3,9-dimethyl-1,7-dioxa-spiro[5.5]undec-2-yl)-ethoxy]-dimethyl-silane

tert-Butyl-[2-((2R,3S,6S,8S,9R)-8-ethynyl-3,9-dimethyl-1,7-dioxa-spiro[5.5]undec-2-yl)-ethoxy]-dimethyl-silane

[2-((2R,3S,6S,8S,9R)-8-Benzyloxymethyl-3,9-dimethyl-1,7-dioxa-spiro[5.5]undec-2-yl)-ethoxy]-tert-butyl-dimethyl-silane

[2-((2R,3S,6S,8S,9R)-8-Benzyloxymethyl-3,9-dimethyl-1,7-dioxa-spiro[5.5]undec-2-yl)-ethoxy]-tert-butyl-dimethyl-silane

tert-Butyl-[2-((2R,3S,6S,8S,9R)-8-ethynyl-3,9-dimethyl-1,7-dioxa-spiro[5.5]undec-2-yl)-ethoxy]-dimethyl-silane

tert-Butyl-[2-((2R,3S,6S,8S,9R)-8-ethynyl-3,9-dimethyl-1,7-dioxa-spiro[5.5]undec-2-yl)-ethoxy]-dimethyl-silane

(2S,3R,9S,10R)-1-Benzyloxy-12-(tert-butyl-dimethyl-silanyloxy)-3,9-dimethyl-2,10-bis-triethylsilanyloxy-dodecan-6-one

(2S,3R,9S,10R)-1-Benzyloxy-12-(tert-butyl-dimethyl-silanyloxy)-3,9-dimethyl-2,10-bis-triethylsilanyloxy-dodecan-6-one

tert-Butyl-[2-((2R,3S,6S,8S,9R)-8-ethynyl-3,9-dimethyl-1,7-dioxa-spiro[5.5]undec-2-yl)-ethoxy]-dimethyl-silane

tert-Butyl-[2-((2R,3S,6S,8S,9R)-8-ethynyl-3,9-dimethyl-1,7-dioxa-spiro[5.5]undec-2-yl)-ethoxy]-dimethyl-silane

上游原料

[2-((2R,3S,6S,8S,9R)-8-Benzyloxymethyl-3,9-dimethyl-1,7-dioxa-spiro[5.5]undec-2-yl)-ethoxy]-tert-butyl-dimethyl-silane ((1S,2R)-1-Benzyloxymethyl-2-methyl-but-3-ynyloxy)-triethyl-silane (4S,5R)-7-(tert-Butyl-dimethyl-silanyloxy)-4-methyl-5-triethylsilanyloxy-heptanoic acid methoxy-methyl-amide (2S,3R,9S,10R)-1-Benzyloxy-12-(tert-butyl-dimethyl-silanyloxy)-3,9-dimethyl-2,10-bis-triethylsilanyloxy-dodecan-6-one (2R,3R)-5-(tert-Butyl-dimethyl-silanyloxy)-2-methyl-3-triethylsilanyloxy-pentanal (3R,4S)-1-[(tert-butyldimethylsilyl)oxy]-4-methylhex-5-en-3-ol

下游产品

(2E,4E)-6-((2R,3S,6S,8S,9R)-8-Ethynyl-3,9-dimethyl-1,7-dioxa-spiro[5.5]undec-2-yl)-4-methyl-hexa-2,4-dienal (4E,6E)-(2R,3S)-8-((2R,3S,6S,8S,9R)-8-Ethynyl-3,9-dimethyl-1,7-dioxa-spiro[5.5]undec-2-yl)-3-hydroxy-1-((S)-4-isopropyl-2-thioxo-oxazolidin-3-yl)-2,6-dimethyl-octa-4,6-dien-1-one