百科

2-benzenesulfonyl-1,4-bis-[5-(1,5-dimethyl-1-trimethylsilanyloxy-hex-4-enyl)-2-methyl-tetrahydro-furan-2-yl]-4-(4-methoxy-benzyloxy)-butan-1-one

2-benzenesulfonyl-1,4-bis-[5-(1,5-dimethyl-1-trimethylsilanyloxy-hex-4-enyl)-2-methyl-tetrahydro-furan-2-yl]-4-(4-methoxy-benzyloxy)-butan-1-one

CAS号：678999-19-4

英文名：2-benzenesulfonyl-1,4-bis-[5-(1,5-dimethyl-1-trimethylsilanyloxy-hex-4-enyl)-2-methyl-tetrahydro-furan-2-yl]-4-(4-methoxy-benzyloxy)-butan-1-one

分子式：C50H80O9SSi2

分子量：913.401

合成路线

(2R,5R)-5-((S)-1,5-Dimethyl-1-trimethylsilanyloxy-hex-4-enyl)-2-methyl-tetrahydro-furan-2-carboxylic acid methyl ester

(2R,5R)-5-((S)-1,5-Dimethyl-1-trimethylsilanyloxy-hex-4-enyl)-2-methyl-tetrahydro-furan-2-carboxylic acid methyl ester

((S)-1-{(2R,5S)-5-[(R)-3-Benzenesulfonyl-1-(4-methoxy-benzyloxy)-propyl]-5-methyl-tetrahydro-furan-2-yl}-1,5-dimethyl-hex-4-enyloxy)-trimethyl-silane

((S)-1-{(2R,5S)-5-[(R)-3-Benzenesulfonyl-1-(4-methoxy-benzyloxy)-propyl]-5-methyl-tetrahydro-furan-2-yl}-1,5-dimethyl-hex-4-enyloxy)-trimethyl-silane

2-benzenesulfonyl-1,4-bis-[5-(1,5-dimethyl-1-trimethylsilanyloxy-hex-4-enyl)-2-methyl-tetrahydro-furan-2-yl]-4-(4-methoxy-benzyloxy)-butan-1-one

2-benzenesulfonyl-1,4-bis-[5-(1,5-dimethyl-1-trimethylsilanyloxy-hex-4-enyl)-2-methyl-tetrahydro-furan-2-yl]-4-(4-methoxy-benzyloxy)-butan-1-one

(R)-2,2-Dimethyl-4-[(2S,5R)-2-methyl-5-((S)-2-methyl-oxiranyl)-tetrahydro-furan-2-yl]-[1,3]dioxolane

(R)-2,2-Dimethyl-4-[(2S,5R)-2-methyl-5-((S)-2-methyl-oxiranyl)-tetrahydro-furan-2-yl]-[1,3]dioxolane

2-benzenesulfonyl-1,4-bis-[5-(1,5-dimethyl-1-trimethylsilanyloxy-hex-4-enyl)-2-methyl-tetrahydro-furan-2-yl]-4-(4-methoxy-benzyloxy)-butan-1-one

2-benzenesulfonyl-1,4-bis-[5-(1,5-dimethyl-1-trimethylsilanyloxy-hex-4-enyl)-2-methyl-tetrahydro-furan-2-yl]-4-(4-methoxy-benzyloxy)-butan-1-one

(S)-2-{(2R,5S)-5-[(R)-3-Benzenesulfonyl-1-(4-methoxy-benzyloxy)-propyl]-5-methyl-tetrahydro-furan-2-yl}-6-methyl-hept-5-en-2-ol

(S)-2-{(2R,5S)-5-[(R)-3-Benzenesulfonyl-1-(4-methoxy-benzyloxy)-propyl]-5-methyl-tetrahydro-furan-2-yl}-6-methyl-hept-5-en-2-ol

2-benzenesulfonyl-1,4-bis-[5-(1,5-dimethyl-1-trimethylsilanyloxy-hex-4-enyl)-2-methyl-tetrahydro-furan-2-yl]-4-(4-methoxy-benzyloxy)-butan-1-one

2-benzenesulfonyl-1,4-bis-[5-(1,5-dimethyl-1-trimethylsilanyloxy-hex-4-enyl)-2-methyl-tetrahydro-furan-2-yl]-4-(4-methoxy-benzyloxy)-butan-1-one

(S)-2-[(2R,5S)-5-((R)-3-Benzenesulfonyl-1-hydroxy-propyl)-5-methyl-tetrahydro-furan-2-yl]-6-methyl-hept-5-en-2-ol

(S)-2-[(2R,5S)-5-((R)-3-Benzenesulfonyl-1-hydroxy-propyl)-5-methyl-tetrahydro-furan-2-yl]-6-methyl-hept-5-en-2-ol

2-benzenesulfonyl-1,4-bis-[5-(1,5-dimethyl-1-trimethylsilanyloxy-hex-4-enyl)-2-methyl-tetrahydro-furan-2-yl]-4-(4-methoxy-benzyloxy)-butan-1-one

2-benzenesulfonyl-1,4-bis-[5-(1,5-dimethyl-1-trimethylsilanyloxy-hex-4-enyl)-2-methyl-tetrahydro-furan-2-yl]-4-(4-methoxy-benzyloxy)-butan-1-one

(2R,5R)-5-((S)-1-Hydroxy-1,5-dimethyl-hex-4-enyl)-2-methyl-tetrahydro-furan-2-carboxylic acid

(2R,5R)-5-((S)-1-Hydroxy-1,5-dimethyl-hex-4-enyl)-2-methyl-tetrahydro-furan-2-carboxylic acid

2-benzenesulfonyl-1,4-bis-[5-(1,5-dimethyl-1-trimethylsilanyloxy-hex-4-enyl)-2-methyl-tetrahydro-furan-2-yl]-4-(4-methoxy-benzyloxy)-butan-1-one

2-benzenesulfonyl-1,4-bis-[5-(1,5-dimethyl-1-trimethylsilanyloxy-hex-4-enyl)-2-methyl-tetrahydro-furan-2-yl]-4-(4-methoxy-benzyloxy)-butan-1-one

(2R,5R)-5-((S)-1-Hydroxy-1,5-dimethyl-hex-4-enyl)-2-methyl-tetrahydro-furan-2-carboxylic acid methyl ester

(2R,5R)-5-((S)-1-Hydroxy-1,5-dimethyl-hex-4-enyl)-2-methyl-tetrahydro-furan-2-carboxylic acid methyl ester

2-benzenesulfonyl-1,4-bis-[5-(1,5-dimethyl-1-trimethylsilanyloxy-hex-4-enyl)-2-methyl-tetrahydro-furan-2-yl]-4-(4-methoxy-benzyloxy)-butan-1-one

2-benzenesulfonyl-1,4-bis-[5-(1,5-dimethyl-1-trimethylsilanyloxy-hex-4-enyl)-2-methyl-tetrahydro-furan-2-yl]-4-(4-methoxy-benzyloxy)-butan-1-one

上游原料

(S)-2-{(2R,5S)-5-[(R)-3-Benzenesulfonyl-1-(4-methoxy-benzyloxy)-propyl]-5-methyl-tetrahydro-furan-2-yl}-6-methyl-hept-5-en-2-ol (2R,5R)-5-((S)-1-Hydroxy-1,5-dimethyl-hex-4-enyl)-2-methyl-tetrahydro-furan-2-carboxylic acid methyl ester ((S)-1-{(2R,5S)-5-[(R)-3-Benzenesulfonyl-1-(4-methoxy-benzyloxy)-propyl]-5-methyl-tetrahydro-furan-2-yl}-1,5-dimethyl-hex-4-enyloxy)-trimethyl-silane (2R,5R)-5-((S)-1,5-Dimethyl-1-trimethylsilanyloxy-hex-4-enyl)-2-methyl-tetrahydro-furan-2-carboxylic acid methyl ester (S)-2-[(2R,5S)-5-((R)-3-Benzenesulfonyl-1-hydroxy-propyl)-5-methyl-tetrahydro-furan-2-yl]-6-methyl-hept-5-en-2-ol (2R,5R)-5-((S)-1-Hydroxy-1,5-dimethyl-hex-4-enyl)-2-methyl-tetrahydro-furan-2-carboxylic acid (R)-2,2-Dimethyl-4-[(2S,5R)-2-methyl-5-((S)-2-methyl-oxiranyl)-tetrahydro-furan-2-yl]-[1,3]dioxolane

下游产品

14-deacetyl eurylene